530 research outputs found

    Synthesis and Characteristics of Carbon Nanofibers/Silicon Composites and Application to Anode Materials of Li Secondary Batteries

    Get PDF
    Among the various synthesizing technologies of carbon nanofibers (CNFs), chemical vapor deposition (CVD) technology, which uses hydrocarbon gas or carbon monoxide as a carbon source gas and pyrolyzes it to grow CNFs on transition metal catalysts, such as Ni, Fe, and Co, has been regarded as the most inexpensive and convenient method to produce CNFs for industrial use. Experimental variables for CVD are source gas, catalyst layers, temperature, and reaction time. Since the particle size of metal catalysts has an influence on the diameter of CNFs, it is possible to control the diameter of CNFs by varying particle sizes of the metal. As such, it is possible to synthesize CNFs selectively through the selective deposition of catalyst metals. In this study, CNFs were grown by CVD on C-fiber textiles, which had catalysts deposited via electrophoretic deposition. The CNFs were coated with a silica layer via hydrolysis of TEOS (tetraethyl orthosilicate), and the CNFs were oxidized by nitric acid. Due to oxidation, a hydroxyl group was created on the CNFs, which was then able to be used as an activation site for the SiO2. CNFs and the CNFs/SiO2 composite can be used in various applications, such as a composite material, electromagnetic wave shielding material, ultrathin display devices, carbon semiconductors, and anode materials of Li secondary batteries. In particular, there is an increasing demand for lightweight, small-scale, and high-capacity batteries for portable electronic devices, such as laptop computers or smart phones, along with the escalating concern of fossil energy depletion. Accordingly, CNFs and CNFs/SiO2 composites are receiving attention for their use as anode materials of Li secondary batteries, which are eco-friendly, lightweight, and high capacity. Therefore, the physicochemical properties and electrochemical performance data of synthesized CNFs and CNFs/SiO2 composite are described in this chapter

    Preparation and Characterization of Carbon Nanofibers and its Composites by Chemical Vapor Deposition

    Get PDF
    Hydrocarbon gas or carbon monoxide was pyrolyzed by chemical vapor deposition (CVD), and carbon nanofiber (CNF) synthesis was performed using transition metals such as Ni, Fe, and Co as catalysts. When synthesizing carbon nanofibers using the CVD method, experimental variables are temperature, catalysts, source gas, etc. Especially, the particle size of the catalyst is the most important factor in determining the diameter of carbon nanofibers. Hydrocarbon gases, such as CH4, C2H4, benzene, and toluene are used as the carbon source, and in addition to these reaction gases, nonreactive gases such as H2, Ar, and N2 gases are used for transportation. Synthesis occurs at a synthesis temperature of 600–900°C, and catalyst metals such as Ni, Co, and Fe are definitely required when synthesizing CNFs. Therefore, it is possible to synthesize CNFs in selective areas through selective deposition of such catalyst metals. In this study, CNFs were synthesized by CVD. Ethylene gas was employed as the carbon source for synthesis of CNFs with H2 as the promoting gas and N2 as the balancing gas. Synthesized CNFs can be used in various applications, such as composite materials, electromagnetic wave shielding materials, ultrathin display devices, carbon semiconductors, and anode materials of Li secondary batteries. In particular, there is an increasing demand for light-weight, small-scale, and high-capacity batteries for portable electronic devices, such as notebook computers or smartphones along with the recent issue of fossil energy depletion. Accordingly, CNFs and their silicon-series composites are receiving attention for use as anode materials for lithium secondary batteries that are eco-friendly, light weight, and high capacity

    Requirement analysis framework of naval military system for expeditionary warfare

    Get PDF
    Military systems are getting more complex due to the demands of various types of missions, rapidly evolving technologies, and budgetary constraints. In order to support complex military systems, there is a need to develop a new naval logistic asset that can respond to global missions effectively. This development is based on the requirement which must be satisfice-able within the budgetary constraints, address pressing real world needs, and allow designers to innovate. This research is conducted to produce feasible and viable requirements for naval logistic assets in complex military systems. The process to find these requirements has diverse uncertainties about logistics, environment and missions. To understand and address these uncertainties, this research includes instability analysis, operational analysis, sea state analysis and disembarkation analysis. By the adaptive Monte-Carlo simulation with maximum entropy, uncertainties are considered with corresponding probabilistic distribution. From Monte-Carlo simulation, the concept of Probabilistic Logistic Utility (PLU) was created as a measure of logistic ability. To demonstrate the usability of this research, this procedure is applied to a Medium Exploratory Connector (MEC) which is an Office of Naval Research (ONR) innovative naval prototype. Finally, the preliminary design and multi-criteria decision-making method become capable of including requirements considering uncertainties.Ph.D

    Finite Element Simulation of Powder Compaction via Shock Consolidation Using Gas-gun System

    Get PDF
    AbstractShock consolidation is a promising method for consolidation of nanocrystalline metallic powders since it can prevent grain growth of nanopowders during the process due to very short processing time. However, internal cracks often occurs in powder compacts during the shock consolidation process. In this paper, finite element simulations showed that reflected tensile wave causes spall phenomena resulting internal crack of powder compaction during shock compaction process. To reduce spall phenomena, FEM simulation with changing compaction die's geometry was performed to find out relationship between shape and tensile wave intensity. Based on FEM results, new compaction die was designed and bulk nanocrystalline Cu are obtained using new compaction die

    Guillain-Barre syndrome after lumbar epidural block

    Get PDF
    • …
    corecore