Evaluation of Refractory Metal Concentrations in Nano-Particulate Pressed-Powder Pellets Using LA-ICP-MS

Whole-rock geochemical analysis is a standard method to measure the chemical composition of ores. Analysis of refractory ore metals such as Ta and W typically requires fused bead and acid digestion followed by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled mass spectrometry (ICP-MS). Since these techniques are time-consuming and expensive, there is a demand for methods that can quantitatively measure low elemental concentration of refractory ore metals using a less expensive and simple approach. This paper evaluates preparation and analytical procedures developed to obtain whole-rock element concentrations of ore samples and mineral concentrates. It shows that the production of nano-particulate pressed-powder pellets followed by LA-ICP-MS analysis of W and Ta ores can be used to determine, within the error margin, the concentrations of the refractory metals W, Ta, Nb, and Sn compared to a reference values obtained by solution analysis. The results have implications for developing a commercially viable method for analysis of refractory elements to benefit mineral processing given the simplicity and resource-efficiency of the combined pressed pellet production and laser ablation analytical methodology