Le spectromètre de masse à temps de vol DEPIL et son utilisation pour la mesure de masses de protéines élevées dépassant 5 000 u : insuline et lyzozyme

Un spectromètre de masse à temps de vol a été construit à l'Institut de Physique Nucléaire d'Orsay pour mesurer des masses de molécules diverses. La gamme de masses accessibles est comprise entre 1 et 20 000 u. Nous présentons ici une description succincte de l'appareillage avec des exemples de mesures de hautes masses

Analyse de spectres d'énergie β+ Méthode et applications à la détermination d'énergie totale de transition β pour des noyaux identifiés par la technique de temps de vol dans la région N ≃ Z ≃ 40

Une méthode par analyse de forme de spectres de positon a été développée à Orsay pour déterminer l'énergie totale des transitions β+. Une précision inférieure à 100 keV peut être atteinte par cette méthode qui est applicable à des spectres de faibles activités. Les spectres de référence et les spectres de Qβ inconnus sont mesurés simultanément dans les mêmes conditions. Nous avons appliqué cette méthode de détermination de Qβ à quelques isotopes produits au cours des réactions 32S + 27Al et 32S + 54Fe

Range of orbital angular momenta available for complete fusion between heavy ions

The same compound nucleus, 158Er, has been formed through three different entrance channels, with projectiles 16O, 40Ar and 84Kr. Excitation functions for reactions (HI, 5n) and (HI, 6n) are well fitted by statistical model calculations, provided that a certain window in orbital angular momentum should be taken in order to produce complete fusion in the case of Ar ions and Kr ions. Curiously enough, low l-waves should be avoided. It implies that, during the interaction leading to complete fusion, the energy dissipation by tangential friction should be rather large

Simulation of MeV/atom cluster correlations in matter

We present an efficient algorithm able to predict the trajectories of individual cluster constituents as they penetrate relatively thick amorphous targets. Our algorithm properly treats both the intracluster Coulomb repulsion and the collisions between cluster constituents and target atoms. We have compared our simulation predictions to experimental measurements of the distribution of lateral exit velocities, and demonstrated that the in-target Coulomb explosion of 2MeV/atom carbon clusters in carbon foils must be shielded with a screening length of less than 2.5 Å. We also present a simple phenomenological model for the suppression of the exit-side charge of ions in clusters which depends on the enhanced ionization potential that an electron near an ion feels due to the ion’s charged comoving neighbors. By using our simulation algorithm we have predicted the exit correlations of the cluster constituents and verified that the charge suppression model fits the observed charge suppression of ions in clusters to within the experimental uncertainties

Measurement of energy and angular distributions of secondary ions in the sputtering of gold by swift Au-n clusters: Study of emission mechanisms

Energy and angular distributions of negative ions (Au–, Au2-, Au3-, and Au5-) emitted from gold target bombarded by Au, Au4, and Au9 projectiles at 200 keV/atom were measured with a multipixel position sensitive detector. The angular distributions are symmetrical with respect to the normal to the target surface and forward peaked. They depend on the type of emitted ions, on the emission energy, and on the projectile size. More forward directed emission is observed with Au9 projectiles. The secondary ion energy distributions obtained with Au and Au4 projectiles are well reproduced by a sum of linear collision cascades and thermal spike processes. However, in the case of Au9 projectiles the energy distributions are better described by using a simple spike model with two different average temperature regimes: the first one corresponds to high emission energy occurring in the early stage of the whole process, and the second to the low energy component

DESORPTION YIELDS USING keV POLYATOMIC PROJECTILES

We have studied the negative secondary ion emission from solid organic targets bombarded by molecular ions and cluster ions. As an example we present here the results obtained with the compound phenylalanine. We have used organic projectiles of mass 73 [Si (CH3)+], 147[Si(CH3)3 OSi(CH3)2+], 300 [molecular ion of coronene C24H12]+, 598 [coronene dimer 2(M-H)]+, and atomic and polyatomic ions of mass 133 [Cs]+, 393 [Cs2I]+, 653 [Cs3I2]+. These primary ions have been produced in the bombardment of targets of coronene and CsI by fission fragment from a 252Cf source. They were accelerated and focussed on the sample target. Sophisticated time of flight measurements of the primary and secondary ions have been performed with a special data acquisition system. All the time of flight mass spectra were recorded at one. The secondary molecular ion yield of the phenilalanine (M-H)- = 164 has been studied as a function of the energy of impact and of the mass of the projectile. A large enhancement of the yield with the mass and the energy is observed

Ion-beam mixing induced by atomic and cluster bombardment in the electronic stopping-power regime

Single crystals of magnesium oxide containing nanoprecipitates of sodium were bombarded with swift ions (∼GeV-Pb, U) or cluster beams (∼20 MeV-C60) to study the phase change induced by electronic processes at high stopping power (≳10 keV/nm). The sodium precipitates and the defect creation were characterized by optical absorption and transmission electron microscopy. The ion or cluster bombardment leads to an evolution of the Na precipitate concentration but the size distribution remains unchanged. The decrease in Na metallic concentration is attributed to mixing effects at the interfaces between Na clusters and MgO. In addition, optical-absorption measurements show a broadening of the absorption band associated with electron plasma oscillations in Na clusters. This effect is due to a decrease of the electron mean free path, which could be induced by defect creation in the metal. All these results show an influence of high electronic stopping power in materials known to be very resistant to irradiation with weak ionizing projectiles. The dependence of these effects on electronic stopping power and on various solid-state parameters is discussed

CLUSTER FORMATION BY FAST HEAVY ION IMPACT ON METAL ACETATES

No abstract availabl

Heavy gold cluster beams production and identification

NIM ACCIt is shown that beams of very heavy gold clusters can be produced by a liquid metal ion source (LMIS). An experimental method is described for defining the LMIS source and the Wien filter parameters that must be set to extract and select large Aun clusters. This method is based on the acceleration of the clusters to high energy (MeV) and on the measurement, after their passage through a thin foil, of their number of constituents and velocity. Only an average mass over charge value is obtained for a given set of source and Wien filter parameters. These parameters can then be used to select heavy Aun cluster beams for applications at low energy (keV) in mass spectrometry