A novel approach to non-segmented flow analysis. Part 2. A prototype high-performance analyser

A high-performance continuous flow analyser is described, based on gas pressure driven carrier and reagents controlled by computer switched solenoid valves. The principal characteristics of the analyser are discussed and examples of its performance are provided in the form of results obtained using a standard procedure for the determination of Cr(VI). The system was also tested in use with real samples using an ammonium ion analysis on potable and effluent water samples, and the results compared with those obtained using a segmented continuous flow method operated at the Laboratory of the Government Chemist

A novel approach to non-segmented flow analysis: Part 4. Aluminium in river waters

A rapid and precise method is developed for the determination of aluminium in water. The results demonstrate that the calibration range of the assay can be extended by a simple manipulation of the control program of the flow analyser. An RSD of 1.8% is achieved for injection of standards and the theoretical limit of detection is estimated at 0.33 ppm alum (equivalent to 18 ppb Al3+). The method is applied to monitoring of environmental samples

Bio-economic evaluation of pasture-cropping, a novel system of integrating perennial pastures and crops on crop-livestock farms

Pasture-cropping is a novel approach to increase the area of perennial crops in mixed sheep and cropping systems. It involves planting annual cereals directly into a living perennial pasture. There is interest in subtropical grasses as they are winter dormant and their growth profile is potentially well suited to pasture-cropping. However, a wide range of factors can affect the uptake of such systems. This paper assesses the relative importance of factors that can influence decisions to introduce pasture-cropping. In this paper the research question is: what factors predispose a farm to take up a new technology such as (1) subtropical grass and (2) subtropical grass that is pasture-cropped. The analysis uses the MIDAS model of a central wheatbelt farm in Western Australia. The results suggest the adoption of subtropical grasses is likely to be strongly influenced by soil mix; feed quality; and whether the farm is predominantly grazing or cropping and by the presence of meat versus wool producing animals. The same factors are relevant for subtropical grass that is pasture-cropped but in addition yield penalties due to competition between the host perennial and the companion cereal become important. The results suggest the level of forage production by subtropical grass is less important but this factor is likely to become more important if feed quality can be improved.Environmental Economics and Policy,

A Hadamard transform UV absorption detection for high performance liquid chromatography. Part I. Preliminary experiments

The principles and design of a Hadamard transform UV absorbance detector for liquid chromatography are outlined, and some spectra of aromatic compounds passing through its flow cell are presented. This approach could be valuable in providing a low-cost multi-wavelength detection method for liquid chromatography

Reforestation success can be enhanced by improving tree planting methods

Successful cost-effective reforestation plantings depend substantially on maximising sapling survival from the time of planting, yet in reforestation programs remarkably little attention is given to management of saplings at the planting stage and to planting methods used. Critical determinants of sapling survival include their vigour and condition when planted, the wetness of the soil into which saplings are planted, the trauma of transplant shock from nursery to natural field soils, and the method and care taken during planting. While some determinants are outside planters' control, careful management of specific elements associated with outplanting can significantly lessen transplanting shock and improve survival rates. Results from three reforestation experiments designed to examine cost-effective planting methods in the Australian wet tropics provided the opportunity to examine the effects of specific planting treatments, including (1) watering regime prior to planting, (2) method of planting and planter technique, and (3) site preparation and maintenance, on sapling survival and establishment. Focusing on sapling root moisture and physical protection during planting improved sapling survival by at least 10% (>91% versus 81%) at 4 months. Survival rates of saplings under different planting treatments were reflected in longer-term survival of trees at 18–20 months, differing from a low of 52% up to 76–88%. This survival effect was evident more than 6 years after planting. Watering saplings immediately prior to planting, careful planting using a forester's planting spade in moist soil and suppressing grass competition using appropriate herbicides were critical to improved plant survival

Pollinators, “mustard oil” volatiles, and fruit production in flowers of the dioecious tree Drypetes natalensis (Putranjivaceae)

The Putranjivaceae is an enigmatic family, notable for being the only lineage outside the Capparales to possess the glucosinolate biochemical pathway, which forms the basis of an induced chemical defense system against herbivores (the “ mustard oil bomb ” ). We investigated the pollination biology and fl oral scent chemistry of Drypetes natalensis (Putranjivaceae), a dioecious subcanopy tree with fl owers borne on the stem (caulifl ory). Flowering male trees were more abundant than female ones and produced about 10-fold more fl owers. Flowers of both sexes produce copious amounts of nectar on disc-like nectaries accessible to short-tongued insects. The main fl ower visitors observed were cetoniid beetles, bees, and vespid wasps. Pollen load analysis indicated that these insects exhibit a high degree of fi delity to D. natalensis fl owers. Insects effectively transfer pollen from male to female plants resulting in about 31% of female fl owers developing fruits with viable seeds. Cetoniid beetles showed signifi cant orientation toward the scent of D. natalensis fl owers in a Y-maze olfactometer. The scents of male and female fl owers are similar in chemical composition and dominated by fatty acid derivatives and isothiocyanates from the glucosinolate pathway. The apparent constitutive emission of isothiocyanates raises interesting new questions about their functional role in flowers

Magnetodielectric coupling in Mn3O4

We have investigated the dielectric anomalies associated with spin ordering transitions in the tetragonal spinel Mn$_3$O$_4$, using thermodynamic, magnetic, and dielectric measurements. We find that two of the three magnetic ordering transitions in Mn$_3$O$_4$ lead to decreases in the temperature dependent dielectric constant at zero applied field. Applying a magnetic field to the polycrystalline sample leaves these two dielectric anomalies practically unchanged, but leads to an increase in the dielectric constant at the intermediate spin-ordering transition. We discuss possible origins for this magnetodielectric behavior in terms of spin-phonon coupling. Band structure calculations suggest that in its ferrimagnetic state, Mn$_3$O$_4$ corresponds to a semiconductor with no orbital degeneracy due to strong Jahn-Teller distortion.Comment: 6 pages, 7 figure