Economic and Market Analysis of CO2 Utilization Technologies – Focus on CO2 derived from North Dakota lignite

AbstractBased on information obtained about the technical aspects of the technologies, several challenges are expected to be faced by any potential CO2 utilization technologies intended for North Dakota lignite plants. The weather, alkaline content of lignite fly ash, and space limitations in the immediate vicinity of existing power plants are challenging hurdles to overcome. Currently, no CO2 utilization option is ready for implementation or integration with North Dakota power plants. Mineralization technologies suffer from the lack of a well-defined product and insufficient alkalinity in lignite fly ash. Algae and microalgae technologies are not economically feasible and will have weather- related challenges

Chemical mechanisms in mercury emission control technologies

The emission of elemental mercury in the flue gas from coal-burning power plants is a major environmental concern. Control technologies utilizing activated carbon show promise and are currently under intense review. Oxidation and capture of elemental mercury on activated carbon was extensively investigated in a variety of flue gas atmospheres. Extensive parametric testing with individual and a variety of combinations and concentrations of reactive flue gas components and spectroscopic examination of the sulfur and chlorine forms present before and after breakthrough have led to an improved model to explain the kinetic and capacity results. The improved model delineates the independent Lewis acid oxidation site as well as a zig-zag carbene site on the carbon edge that performs as a Lewis base in reacting with both the oxidized mercury formed at the oxidation site and with the acidic flue gas components in competing reactions to form organochlorine, sulfinate, and sulfate ester moieties on the carbon edge