1 research outputs found
Mn local moments prevent superconductivity in iron-pnictides Ba(Fe 1-x Mn x)2As2
75As nuclear magnetic resonance (NMR) experiments were performed on
Ba(Fe1-xMnx)2As2 (xMn = 2.5%, 5% and 12%) single crystals. The Fe layer
magnetic susceptibility far from Mn atoms is probed by the75As NMR line shift
and is found similar to that of BaFe2As2, implying that Mn does not induce
charge doping. A satellite line associated with the Mn nearest neighbours
(n.n.) of 75As displays a Curie-Weiss shift which demonstrates that Mn carries
a local magnetic moment. This is confirmed by the main line broadening typical
of a RKKY-like Mn-induced staggered spin polarization. The Mn moment is due to
the localization of the additional Mn hole. These findings explain why Mn does
not induce superconductivity in the pnictides contrary to other dopants such as
Co, Ni, Ru or K.Comment: 6 pages, 7 figure