12,617 research outputs found
Electron transfer in the nonadiabatic regime: Crossover from quantum-mechanical to classical behaviour
We study nonadiabatic electron transfer within the biased spin-boson model.
We calculate the incoherent transfer rate in analytic form at all temperatures
for a power law form of the spectral density of the solvent coupling. In the
Ohmic case, we present the exact low temperature corrections to the zero
temperature rate for arbitrarily large bias energies between the two redox
sites. Both for Ohmic and non-Ohmic coupling, we give the rate in the entire
regime extending from zero temperature, where the rate depends significantly on
the detailed spectral behaviour, via the crossover region, up to the classical
regime. For low temperatures, the rate shows characteristic quantum features,
in particular the shift of the rate maximum to a bias value below the
reorganization energy, and the asymmetry of the rate around the maximum. We
study in detail the gradual extinction of the quantum features as temperature
is increased.Comment: 17 pages, 4 figures, to be published in Chem. Phy
Operators for scattering of particles with spin
Operators for simulating the scattering of two particles with spin are
constructed. Three methods are shown to give the consistent lattice operators
for PN, PV, VN and NN scattering, where P, V and N denote pseudoscalar meson,
vector meson and nucleon. The projection method leads to one or several
operators that transform according to a given irreducible
representation and row r. However, it gives little guidance on which
continuum quantum numbers of total J, spin S, orbital momentum L or
single-particle helicities will be related with a given
operator. This is remedied with the helicity and partial-wave methods. There
first the operators with good continuum quantum numbers
or are constructed and then subduced to the irreps of the
discrete lattice group. The results indicate which linear combinations
of various n have to be employed in the simulations in order
to enhance couplings to the states with desired continuum quantum numbers. The
total momentum of two hadrons is restricted to zero since parity P is a good
quantum number in this case.Comment: 7 pages, talk presented at the 34th International Symposium on
Lattice Field Theory, 24-30 July 2016, Southampton, U
Decay of correlations in the dissipative two-state system
We study the equilibrium correlation function of the polaron-dressed
tunnelling operator in the dissipative two-state system and compare the
asymptoptic dynamics with that of the position correlations. For an Ohmic
spectral density with the damping strength , the correlation functions
are obtained in analytic form for all times at any and any bias. For ,
the asymptotic dynamics is found by using a diagrammatic approach within a
Coulomb gas representation. At T=0, the tunnelling or coherence correlations
drop as , whereas the position correlations show universal decay
. The former decay law is a signature of unscreened attractive
charge-charge interactions, while the latter is due to unscreened dipole-dipole
interactions.Comment: 5 pages, 5 figures, to be published in Europhys. Let
Formation of a carcinogenic aromatic amine from an azo dye by human skin bacteria in vitro
Dieser Beitrag ist mit Zustimmung des Rechteinhabers aufgrund einer (DFG geförderten) Allianz- bzw. Nationallizenz frei zugänglich.This publication is with permission of the rights owner freely accessible due to an Alliance licence and a national licence (funded by the DFG, German Research Foundation) respectively.Azo dyes represent the major class of dyestuffs. They are metabolised to the corresponding amines by liver enzymes and the intestinal microflora following incorporation by both experimental animals and humans. For safety evaluation of the dermal exposure of consumers to azo dyes from wearing coloured textiles, a possible cleavage of azo dyes by the skin microflora should be considered since, in contrast to many dyes, aromatic amines are easily absorbed by the skin. A method for measuring the ability of human skin flora to reduce azo dyes was established. In a standard experiment, 361011 cells of a culture of Staphylococcus aureus wereincubatedinsyntheticsweat (pH 6.8, final volume 20 mL) at 288C for 24 h with Direct Blue 14 (C.I. 23850, DB 14). The reaction products were extracted and analysed using HPLC. The reduction product o-tolidine (3,3'-dimethylbenzidine, OT) could indeed be detected showing that the strain used was able to metabolise DB 14 to the corresponding aromatic amine. In addition to OT, two further metabolites of DB 14 were detected. Using mass spectrometry they were identified as 3,3'-dimethyl-4-amino-4'-hydroxybiphenyl and 3,3'-di methyl-4-aminobiphenyl. The ability to cleave azo dyes seems to be widely distributed among human skin bacteria, as, under these in vitro conditions, bacteria isolated from healthy human skin and human skin bacteria from strain collections also exhibited azo reductase activity. Further studies are in progress in order to include additional azo dyes and coloured textiles. At the moment, the meaning of the results with regard to consumer health cannot be finally assessed
Bose Hubbard model in the presence of Ohmic dissipation
We study the zero temperature mean-field phase diagram of the Bose-Hubbard
model in the presence of local coupling between the bosons and an external
bath. We consider a coupling that conserves the on-site occupation number,
preserving the robustness of the Mott and superfluid phases. We show that the
coupling to the bath renormalizes the chemical potential and the interaction
between the bosons and reduces the size of the superfluid regions between the
insulating lobes. For strong enough coupling, a finite value of hopping is
required to obtain superfluidity around the degeneracy points where Mott phases
with different occupation numbers coexist. We discuss the role that such a bath
coupling may play in experiments that probe the formation of the
insulator-superfluid shell structure in systems of trapped atoms.Comment: 5 pages, 2 figures. Error found in v1, now corrected, leads to
qualitative changes in result
Rising extreme sea levels in the German Bight under enhanced CO2 levels: a regionalized large ensemble approach for the North Sea
We quantify the change in extreme high sea level (ESL) statistics in the German Bight under rising CO2 concentrations by downscaling a large ensemble of global climate model simulations using the regionally coupled climate system model REMO-MPIOM. While the model setup combines a regionally high resolution with the benefits of a global ocean model, the large ensemble size of 32 members allows the estimation of high return levels with much lower uncertainty. We find that ESLs increase with atmospheric CO2 levels, even without considering a rise in the background sea level (BSL). Local increases of up to 0.5 m are found along the western shorelines of Germany and Denmark for ESLs of 20–50 years return periods, while higher return levels remain subject to sampling uncertainty. This ESL response is related to a cascade of an enhanced large-scale activity along the North Atlantic storm belt to a subsequent local increase in predominantly westerly wind speed extremes, while storms of the major West-Northwest track type gain importance. The response is seasonally opposite: summer ESLs and the strength of its drivers decrease in magnitude, contrasting the response of the higher winter ESLs, which governs the annual response. These results have important implications for coastal protection. ESLs do not only scale with the expected BSL rise, but become even more frequent, as preindustrial 50-year return levels could be expected to occur almost every year by the end of the century. The magnitude of the relative change in ESL statistics is hereby up to half of the expected rise in BSL, depending on the location. Changes in the highest extremes are subject to large multidecadal variations and remain uncertain, thus potentially demanding even further safety measures
Determining ethylene group disorder levels in -(BEDT-TTF)Cu[N(CN)]Br
We present a detailed structural investigation of the organic superconductor
-(BEDT-TTF)Cu[N(CN)]Br at temperatures from 9 to 300 K.
Anomalies in the dependence of the lattice parameters are associated with a
glass-like transition previously reported at = 77 K. From structure
refinements at 9, 100 and 300 K, the orthorhombic crystalline symmetry, space
group {\it Pnma}, is established at all temperatures. Further, we extract the
dependence of the occupation factor of the eclipsed conformation of the
terminal ethylene groups of the BEDT-TTF molecule. At 300 K, we find 67(2) %,
with an increase to 97(3) % at 9 K. We conclude that the glass-like transition
is not primarily caused by configurational freezing-out of the ethylene groups
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