Structural studies of mesoporous ZrO2_{2}-CeO2_{2} and ZrO2_{2}-CeO2_{2}/SiO2_{2} mixed oxides for catalytical applications

In this work the synthesis of ZrO$_{2}$-CeO$_{2}$ and ZrO$_{2}$-CeO$_{2}$/SiO$_{2}$ were developed, based on the process to form ordered mesoporous materials such as SBA-15 silica. The triblock copolymer Pluronic P-123 was used as template, aiming to obtain crystalline single phase walls and larger specific surface area, for future applications in catalysis. SAXS and XRD results showed a relationship between ordered pores and the material crystallization. 90% of CeO$_{2}$ leaded to single phase homogeneous ceria-zirconia solid solution of cubic fluorite structure (Fm$\bar{3}$m). The SiO$_{2}$ addition improved structural and textural properties as well as the reduction behavior at lower temperatures, investigated by XANES measurements under H$_{2}$ atmosphere

Experimental violation of a spin-1 Bell inequality using maximally-entangled four-photon states

We demonstrate the first experimental violation of a spin-1 Bell inequality. The spin-1 inequality is a calculation based on the Clauser, Horne, Shimony and Holt formalism. For entangled spin-1 particles the maximum quantum mechanical prediction is 2.552 as opposed to a maximum of 2, predicted using local hidden variables. We obtained an experimental value of 2.27 $\pm 0.02$ using the four-photon state generated by pulsed, type-II, stimulated parametric down-conversion. This is a violation of the spin-1 Bell inequality by more than 13 standard deviations.Comment: 5 pages, 3 figures, Revtex4. Problem with figures resolve

Animal husbandry across the Western Roman Empire: Changes and continuities

This special issue of the European Journal of Archaeology discusses aspects of animal husbandry in a number of provinces of the Western Roman Empire. In this introduction, we describe the general characteristics of animal husbandry in pre-Roman and Roman times to assess any changes that may have occurred after the Roman conquest. The results suggest that the territoriality typifying the first millennium BC had a significant impact on production, resulting in a decrease in cattle size and frequencies across Europe. Nevertheless, not all the regions reacted in the same way, and regional communities that focused their animal production on pigs implemented more sustainable husbandry practices over time. By bringing together studies carried out across Europe, this paper highlights the existence of cases of both change and continuity across the Empire, and the (uneven) impact of the market economy on animal husbandry and dietary practices in climatically different regions

REUSE OF WASTEWATER FROM POLYESTER FIBRES DYEING PROCESS BY THERMAL FIXATION WITH DYE ACID BASE: CASE STUDY IN A BRAZILIAN AUTO PARTS FACILITY

This work aims to test biodegradable chemicals into treatment of textile waste water from an auto parts facility with goal of reuse of water treated in dyeing process of lace used in safety belts. It presents a method that suits the treatment of waste water with local environmental regulations and allows the reuse of water through the adoption of actions that replace the conventional physical-chemical treatment by biodegradable products, which naturally extend the possibility of reuse beyond the process and increase the quality of water for reuse in that one, allowing satisfy the requirements of product quality demanded by the market. This work proposes substitution of some chemicals by biodegradable products and comparison to previous results obtained with current treatment for the same conditions preestablished. Also the ultra-filtration method had evaluated and its results were compared to traditional process and to new proposal. According to results obtained, replacement of traditional chemicals by biodegradable products is technical and economical viable and attends to the waste water reuse policy proposed

Social disruption: Sublethal pesticides in pollen lead to Apis mellifera queen events and brood loss

Eusocial Apis mellifera colonies depend on queen longevity and brood viability to survive, as the queen is the sole reproductive individual and the maturing brood replenishes the shorter-lived worker bees. Production of many crops rely on both pesticides and bee pollination to improve crop quantity and quality, yet sublethal impacts of this pesticide exposure is often poorly understood. We investigated the resiliency of queens and their brood after one month of sublethal exposure to field relevant doses of pesticides that mimic exposure during commercial pollination contracts. We exposed full size colonies to pollen contaminated with field-relevant doses of the fungicides (chlorothalonil and propicanizole), insecticides (chlorypyrifos and fenpropathrin) or both, noting a significant reduction in pollen consumption in colonies exposed to fungicides compared to control. While we found no difference in the total amount of pollen collected per colony, a higher proportion of pollen to nonpollen foragers was detected in all pesticide exposed colonies. After ceasing treatments, we measured brood development, discovering a significant increase in brood loss and/or cannibalism across all pesticide exposed groups. Sublethal pesticide exposure in general was linked to reduced production of replacement workers and a change in protein acquisition (pollen vs. non-pollen foraging). Fungicide exposure also resulted in increased loss of the reproductive queen

Phase diagram study of a two-dimensional frustrated antiferromagnet via unsupervised machine learning

We apply unsupervised learning techniques to classify the different phases of the $J_1-J_2$ antiferromagnetic Ising model on the honeycomb lattice. We construct the phase diagram of the system using convolutional autoencoders. These neural networks can detect phase transitions in the system via `anomaly detection', without the need for any label or a priori knowledge of the phases. We present different ways of training these autoencoders and we evaluate them to discriminate between distinct magnetic phases. In this process, we highlight the case of high temperature or even random training data. Finally, we analyze the capability of the autoencoder to detect the ground state degeneracy through the reconstruction error.Comment: 11 pages, 15 figure

Combined analytical and numerical approach to study magnetization plateaux in doped quasi-one-dimensional antiferromagnets

We investigate the magnetic properties of quasi-one-dimensional quantum spin-S antiferromagnets. We use a combination of analytical and numerical techniques to study the presence of plateaux in the magnetization curve. The analytical technique consists in a path integral formulation in terms of coherent states. This technique can be extended to the presence of doping and has the advantage of a much better control for large spins than the usual bosonization technique. We discuss the appearance of doping-dependent plateaux in the magnetization curves for spin-S chains and ladders. The analytical results are complemented by a density matrix renormalization group (DMRG) study for a trimerized spin-1/2 and anisotropic spin-3/2 doped chains.Instituto de Física La Plat

Ultrasonographic evaluation of the supraspinous ligament in a series of ridden and unridden horses and horses with unrelated back pathology

Abstract Background Injury to the supraspinous ligament (SSL) is reported to cause back pain in the horse. The diagnosis is based on clinical examination and confirmed by ultrasonographic examination. The ultrasonographic appearance of the supraspinous ligament has been well described, but there are few studies that correlate ultrasonographic findings with clinical pain and/or pathology. This preliminary study aims to test the hypothesis that unridden horses (n = 13) have a significantly reduced frequency of occurrence of ultrasonographic changes of the SSL consistent with a diagnosis of desmitis when compared to ridden horses (n = 13) and those with clinical signs of back pain (n = 13). Results The supraspinous ligament of all horses was imaged between T(thoracic)6-T18 and ultrasonographic appearance. There was an average of 2.08 abnormal images per horse from the whole group. The average number of abnormalities in unridden horses was 4.92, in ridden horses 2.92 and in horses with clinical back pain 4.69. No lesions were found between T6 and T10 and 68% of lesions were found between T14 and T17. No significant difference (p < 0.05) was found between the three groups in the number or location of abnormal images. Conclusion The main conclusion was that every horse in this study (n = 39) had at least one site of SSL desmitis (range 2 to 11). It was clear that ultrasonographically diagnosed SSL desmitis cannot be considered as prima facie evidence of clinically significant disease and further evidence is required for a definitive diagnosis.RIGHTS : This article is licensed under the BioMed Central licence at http://www.biomedcentral.com/about/license which is similar to the 'Creative Commons Attribution Licence'. In brief you may : copy, distribute, and display the work; make derivative works; or make commercial use of the work - under the following conditions: the original author must be given credit; for any reuse or distribution, it must be made clear to others what the license terms of this work are