Asteroseismology of the δ\delta Scuti star HD 50844

Aims. We aim to probe the internal structure and investigate more detailed information of the $\delta$ Scuti star HD 50844 with asteroseismology. Methods. We analyse the observed frequencies of the $\delta$ Scuti star HD 50844 obtained by Balona (2014), and search for possible multiplets based on the rotational splitting law of g-mode. We tried to disentangle the frequency spectra of HD 50844 by means of the rotational splitting only. We then compare them with theoretical pulsation modes, which correspond to stellar evolutionary models with various sets of initial metallicity and stellar mass, to find the best-fitting model. Results. There are three multiplets including two complete triplets and one incomplete quintuplet, in which mode identifications for spherical harmonic degree $l$ and azimuthal number $m$ are unique. The corresponding rotational period of HD 50844 is found to be 2.44$^{+0.13}_{-0.08}$ days. The physical parameters of HD 50844 are well limited in a small region by three modes identified as nonradial ones ($f_{11}$, $f_{22}$, and $f_{29}$) and by the fundamental radial mode ($f_{4}$). Our results show that the three nonradial modes ($f_{11}$, $f_{22}$, and $f_{29}$) are all mixed modes, which mainly represent the property of the helium core. The fundamental radial mode ($f_{4}$) mainly represents the property of the stellar envelope. In order to fit these four pulsation modes, both the helium core and the stellar envelope must be matched to the actual structure of HD 50844. Finally, the mass of the helium core of HD 50844 is estimated to be 0.173 $\pm$ 0.004 $M_{\odot}$ for the first time. The physical parameters of HD 50844 are determined to be $M=$ 1.81 $\pm$ 0.01 $M_{\odot}$, $Z=$ 0.008 $\pm$ 0.001. $T_{\rm eff}=$ 7508 $\pm$ 125 K, log$g=$ 3.658 $\pm$ 0.004, $R=$ 3.300 $\pm$ 0.023 $R_{\odot}$, $L=$ 30.98 $\pm$ 2.39 $L_{\odot}$.Comment: 11 pages, 7 figures, 6 tables, accepted for publication in A&

Predicted Optimal Bifunctional Electrocatalysts for the Hydrogen Evolution Reaction and the Oxygen Evolution Reaction Using Chalcogenide Heterostructures Based on Machine Learning Analysis of in Silico Quantum Mechanics Based High Throughput Screening

Two-dimensional van der Waals heterostructure materials, particularly transition metal dichalcogenides (TMDC), have proved to be excellent photoabsorbers for solar radiation, but performance for such electrocatalysis processes as water splitting to form H₂ and O₂ is not adequate. We propose that dramatically improved performance may be achieved by combining two independent TMDC while optimizing such descriptors as rotational angle, bond length, distance between layers, and the ratio of the bandgaps of two component materials. In this paper we apply the least absolute shrinkage and selection operator (LASSO) process of artificial intelligence incorporating these descriptors together with quantum mechanics (density functional theory) to predict novel structures with predicted superior performance. Our predicted best system is MoTe₂/WTe₂ with a rotation of 300°, which is predicted to have an overpotential of 0.03 V for HER and 0.17 V for OER, dramatically improved over current electrocatalysts for water splitting

Design of a Graphene Nitrene Two-Dimensional Catalyst Heterostructure Providing a Well-Defined Site Accommodating 1 to 3 Metals, with Application to CO₂ Reduction Electrocatalysis for the 2 Metal Case

Recently, the reduction of CO₂ to fuels has been the subject of numerous studies, but the selectivity and activity remain inadequate. Progress has been made on single-site two-dimensional catalysts based on graphene coupled to a metal and nitrogen for the CO₂ reduction reaction (CO₂RR); however, the product is usually CO, and the metal–N environment remains ambiguous. We report a novel two-dimensional graphene nitrene heterostructure (grafiN₆) providing well-defined active sites (N₆) that can bind one to three metals for the CO₂RR. We find that homobimetallic FeFe–grafiN₆ could reduce CO₂ to CH₄ at −0.61 V and to CH₃CH₂OH at −0.68 V versus reversible hydrogen electrode, with high product selectivity. Moreover, the heteronuclear FeCu–grafiN₆ system may be significantly less affected by hydrogen evolution reaction, while maintaining a low limiting potential (−0.68 V) for C1 and C2 mechanisms. Binding metals to one N₆ site but not the other could promote efficient electron transport facilitating some reaction steps. This framework for single or multiple metal sites might also provide unique catalytic sites for other catalytic processes

The Functions Of Cultural Schemata In The Chinese Reading Comprehension And Reading Time Of College Students In Taiwan

The study examined the effects of cultural familiarity with a text on Chinese students’ reading comprehension performance and reading time. In the first phase of the study, participants were required to read a culturally familiar text, write down the time they spent reading the passage, and immediately complete a cloze test without referring back to the culturally-embedded text. In the second phase, they went through the same procedure for a culturally unfamiliar text. Upon completion of the reading tasks, a topic familiarity questionnaire was distributed to them to complete in order to screen out those who were culturally familiar with both reading texts. A survey about their attitudes toward the role that background knowledge played in their reading process was administered to them following the topic familiarity questionnaire. The results showed that the students’ reading comprehension performance and reading time were both significantly affected by their familiarity with the target culture. They spent less time on and comprehended better the culturally-embedded text they were familiar with. Analysis of the survey also substantiated the claim that they relied on the facilitative role of background knowledge in reading so as to read in a faster and more efficient way. The findings suggest that a reader’s cultural schemata impacts memory, reading comprehension, interpretation and reading time. Pedagogical implications of the study and suggestions for future research are also discussed in the article