New data on the exploitation of obsidian in the mediterranean basin: The harbour of pyrgi and the trade in neolithic age

The contribution shows the first results of ongoing research on the origins and prehistoric assumptions of the well-known Etruscan and Roman harbour of Pyrgi, an ancient Ceretan harbour in southern Etruria. In the light of recent land and submarine investigations, traces of ancient frequentations and contacts dating back to the Neolithic era are emerging when the coastal morphology and environmental characteristics of the site were very different from the current ones. The Etruscan port of Pyrgi, which continues its historical history in Roman and Medieval times, appears as the heir of one or more landing points frequented perhaps already in the Middle Neolithic. As part of this contribution, around 60 obsidian finds (waste resulting from the manufacture of arrowheads) were analyzed using the LA-ICP-MS technique (Laser Ablation Inductively Coupled Plasma Mass Spectrometry). The comparison between the data obtained on the archaeological finds and the bibliographic data relating to the geological obsidians of the peri-Tyrrhenian area allowed the identification of the provenance of the finds. In particular, most of the finds can be attributed to the Aeolian area, highlighting the leading role played by the Aeolian archipelago in the development of trade of this material. Other sources of supply have been identified on the island of Palmarola and in Sardinia (Monte Arci) although with a lower incidence. The discovery of numerous findings in obsidian from overseas, which took place in the area immediately surrounding Pyrgi, offers different suggestions about the origin of the docking place, with traces of centuries-old frequentation, extended from the Neolithic to the modern era

Studio di processi di degrado su manufatti archeologici in ambiente narino sommerso e sperimentazione di procedure innovative per la conservazione in situ

Dottorato "Archimede" in Scienze ,Comunicazione e Tecnologie, Ciclo XXVII, a.a. 2014Università della Calabri

Indagini archeometriche di reperti archeologici di provenienza marina e ipotesi di conservazione con formulati a base di nanoparticelle

Scuola di Dottorato "Archimede" in Scienze ,Comunicazione e Tecnologie, Ciclo XXVII a.a. 2014Università della Calabri

Indagini archeometriche finalizzate allo studio delle forme di alterazione e degrado dei materiali lapidei naturali e artificiali in ambiente subacque

Dottorato di Ricerca Scienze della Terra, XXI Ciclo, a.a. 2008-2009Università della Calabri

THE BAROQUE MONUMENTS OF MODICA (EASTERN SICILY): ASSESSMENT OF CAUSES OF CHROMATIC ALTERATION OF STONE BUILDING MATERIALS

Published on line 08 april 201

An Integrated Analytical Approach to Define the Compositional and Textural Features of Mortars Used in the Underwater Archaeological Site of Castrum Novum (Santa Marinella, Rome, Italy)

This paper aims to carry out an archaeometric characterization of mortar samples taken from an underwater environment. The fishpond of the archaeological site of Castrum Novum (Santa Marinella, Rome, Italy) was chosen as a pilot site for experimentation. The masonry structures reached the maximum thickness at the apex of the fishpond (4.70 m) and consisted of a concrete conglomerate composed of slightly rough stones of medium size bound with non-hydraulic mortar. After sampling, for a complete characterization of selected mortar fragments, different and complementary techniques (stereomicroscopy, polarizing optical microscopy, and X-ray powder diffraction analysis) were carried out in order to: a) define the minero-petrographic features; and b) investigate their state of conservation. The obtained data allowed the determination of the main constituents of mortars from a compositional point of view. The raw materials, in fact, were quite homogeneous, as well as the ratio in which they were mixed, confirming the typical "recipe" used in Roman times to manufacture hydraulic-type mortars by adding pozzolana. At the same time, it was possible to identify the various degradation processes we were interested in, namely, biological colonization (bio-fouling) that develops differently according to environmental conditions. Based on characterization phase results, the research will help to develop adequate techniques for intervention (innovative tools and methods for the protection of underwater cultural heritage) with particular regard to cleaning and consolidating procedures to be carried out directly in situ

A scientific approach to the characterization of the painting technique of an author: the case of Raffaele Rinaldi

During the last restoration of the six paintings by Raffaele Rinaldi (1851-1916), located in the church of Maria SS. Annunziata (Marano Principato, Cosenza, Italy), made between 1890 and 1903, several scientific investigations were carried out on them. The present work aims at differentiating the painting in terms of its materials and technical particularities. The goal of this study was to characterize the painting technique of the author, its evolution and possible additions made during previous restorations. Pigments, binder media and raw materials used for the application of the ground and the paint layers were studied using electronic microscopy equipped with energy dispersive spectroscopy qualitative microanalysis (SEM-EDS), infrared spectroscopy (FTIR) and gas chromatography coupled with mass spectrometry (GC/MS). Furthermore, a complete analysis of the state of preservation of these paintings represents a scientific aid and guide for its restoration, taking into account the, severe damage not exclusively due to natural decay processes. Our data can provide information about historical and stylistic background as well as advises for correct planning of the cleaning procedures. The identification of materials allowed a correct restoration

Multidisciplinary study of Holocene archaeological soils in an upland Mediterranean site: Natural versus anthropogenic environmental changes at Cecita Lake, Calabria, Italy

This paper highlights results of a multidisciplinary and multi-analytical study of Holocene archaeological soils around Cecita Lake (Sila massif, Calabria, southern Italy), which represents a typical upland Mediterranean environment. It is focused on assessment of climatic and environmental changes that took place since late Neolithic to Roman times, trying to discriminate natural from anthropogenic signals. Based on an integration of archaeological, geomorphological, stratigraphic, pedological, volcanological and soil charcoal (pedoanthracological) data, the following paleoclimatic/environmental reconstruction is proposed: a warm and humid, seasonally contrasted climate, with an overall geomorphological stability suited for soil development, characterized the late prehistoric environment (Holocene climatic optimum), dominated by a widespread oak forest. The main pedogenetic processes consisted in organic matter accumulation, clay illuviation, phyllosilicate and short-range order mineral neogenesis from weathering of granite and volcanic ash, sourced from late Pleistocene-Holocene eruptions of the Aeolian Islands. One or more mid-Holocene episodes of climate deterioration towards drier conditions (indicated by a decrease of clay translocation processes and possible irreversible dehydration of poorly-crystalline aluminosilicates into phyllosilicate clay minerals) promoted intense land degradation. This was in turn enhanced by increasing human activities for settlement and resource exploitation (among which deforestation and ploughing for agriculture), which led to a shift of the vegetation cover towards a dominant pine forest between 3kaBP and the Roman epoch. Humid and possibly cooler climatic conditions during the late Holocene are indicated by the decrease of clay illuviation, coupled with short-range order components prevailing over phyllosilicate clays during Roman soil formation

Marine Antifouling for Underwater Archaeological Sites: TiO2 and Ag-Doped TiO2

Marine fouling plays a crucial role in the degradation of underwater archaeological sites. Limitation of fouling activity and its damages are one of the most critical issues for archaeologists and conservators. The common cleaning procedure, consisting in the manual removal of fouling, requires a continuous maintenance, while a proper inhibition of biological colonisation would provide a long-time protection against biofouling. On the other hand, the most used antifouling paints, especially for ship hulls, show considerable toxicity level. Since submerged archaeological sites are often included in environmental protected areas, more eco-friendly products must be used. We have explored the possibility to use titanium dioxide and Ag-doped titanium dioxide as antifouling agents. For this purpose, they have been synthetized by sol-gel method, and then XRD, XPS, and reflectance spectroscopy measurements have been carried out to gain structural information. The powders have been dispersed in a polymer and then applied to marble surface to evaluate the chromatic alteration induced by the treatments. By means of biological tests, it was possible to assess their behaviour as biofouling agents. Results show a decreasing of biofouling activity on treated stony surfaces