Creation of dense polymer brush layers by the controlled deposition of an amphiphilic responsive comb polymer

We introduce a copolymer with a comb topology that has been engineered to assemble in a brush configuration at an air-water interface. The molecule comprises a 6.1 kDa poly(methyl methacrylate) backbone with a statistical amount of poly[2-(dimethyl amino)ethyl methacrylate] polybase side chains averaging 2.43 per backbone.. Brush layers deposited with the hydrophobic PMMA backbone adsorbed to hydrophobized silicon are stable in water even when stored at pH values less than 2.0 for over 24 h. The use of a Langmuir trough allows a simple controlled deposition of the layers at a variety of grafting densities. Depth profiling of brush layers was performed using neutron reflectometry and reveals a significant shifting of the responsiveness of the layer upon changing the grafting density. The degree of swelling of the layers at a pH value of 4 (below the pK(b)) decreases as grafting density increases. Lowering the pH of the subphase during deposition causes the side chains to become charged and more hydrophilic extending to a brush-like configuration while at neutral pH the side chains lie in a "pancake" conformation at the interface. (C) 2009 Elsevier Ltd. All rights reserved

The Relationship Between Plasma Flow Doppler Velocities and Magnetic Field Parameters During the Emergence of Active Regions at the Solar Photospheric Level

A statistical study has been carried out of the relationship between plasma flow Doppler velocities and magnetic field parameters during the emergence of active regions at the solar photospheric level with data acquired by the Michelson Doppler Imager (MDI) onboard the Solar and Heliospheric Observatory (SOHO). We have investigated 224 emerging active regions with different spatial scales and positions on the solar disc. The following relationships for the first hours of the emergence of active regions have been analysed: i) of peak negative Doppler velocities with the position of the emerging active regions on the solar disc; ii) of peak plasma upflow and downflow Doppler velocities with the magnetic flux growth rate and magnetic field strength for the active regions emerging near the solar disc centre (the vertical component of plasma flows); iii) of peak positive and negative Doppler velocities with the magnetic flux growth rate and magnetic field strength for the active regions emerging near the limb (the horizontal component of plasma flows); iv) of the magnetic flux growth rate with the density of emerging magnetic flux; v) of the Doppler velocities and magnetic field parameters for the first hours of the appearance of active regions with the total unsigned magnetic flux at the maximum of their development.Comment: 14 pages, 8 figures. The results of article were presented at the ESPM-13 (12-16 September 2011, Rhodes, Greece, Abstract Book p. 102-103, P.4.13, http://astro.academyofathens.gr/espm13/documents/ESPM13_abstract_programme_book.pdf

Commodity risk assessment of Momordica charantia fruits from Honduras

The European Commission requested the EFSA Panel on Plant Health to prepare and deliver risk assessments for commodities listed in Commission Implementing Regulation (EU) 2018/2019 as ‘High risk plants, plant products and other objects’. Momordica fruits originating from countries where Thrips palmi is known to occur qualify as high risk plants. This Scientific Opinion covers the introduction risk for T. palmi posed by fruits of Momordica charantia L. imported from Honduras, taking into account the available scientific information, including the technical information provided by the National Service of Agrifood Health and Safety (SENASA) of Honduras. The risk mitigation measures proposed in the technical dossier from Honduras were evaluated taking into account the possible limiting factors. An expert judgement is given on the likelihood of pest freedom taking into consideration the potential pest pressure in the field, the risk mitigation measures acting on the pest in the field and in the packinghouse, including uncertainties associated with the assessment. For T. palmi on M. charantia fruits from Honduras, an expert judgement is given on the likelihood of pest freedom following the evaluation of the risk mitigation measures acting on T. palmi, including any uncertainties. The Expert Knowledge Elicitation indicated, with 95% certainty that between 9,406 and 10,000 M. charantia fruits per 10,000 will be free from T. palmi

Commodity risk assessment of Momordica charantia fruits from Mexico

The European Commission requested the EFSA Panel on Plant Health to prepare and deliver risk assessments for commodities listed in Commission Implementing Regulation (EU) 2018/2019 as ‘High risk plants, plant products and other objects’. Momordica fruits originating from countries where Thrips palmi is known to occur qualify as high risk plants. This Scientific Opinion covers the introduction risk for T. palmi posed by fruits of Momordica charantia L. imported from Mexico, taking into account the available scientific information, including the technical information provided by the National Service of Health, Safety and Agrifood Quality (Senasica) of Mexico. The risk mitigation measures proposed in the technical dossier from Mexico were evaluated taking into account the possible limiting factors. An expert judgement is given on the likelihood of pest freedom taking into consideration the potential pest pressure in the field, the risk mitigation measures acting on the pest in the field and in the packinghouse, including uncertainties associated with the assessment. For T. palmi on M. charantia fruits from Mexico, an expert judgement is given on the likelihood of pest freedom following the evaluation of the risk mitigation measures acting on T. palmi, including any uncertainties. The Expert Knowledge Elicitation indicated, with 95% certainty that between 9,492 and 10,000 M. charantia fruits per 10,000 will be free from T. palmi