Time Delay Induced Death in Coupled Limit Cycle Oscillators

We investigate the dynamical behaviour of two limit cycle oscillators that interact with each other via time delayed coupling and find that time delay can lead to amplitude death of the oscillators even if they have the same frequency. We demonstrate that this novel regime of amplitude "death" also exists for large collections of coupled identical oscillators and provide quantitative measures of this death region in the parameter space of coupling strength and time delay. Its implication for certain biological and physical applications is also pointed out.Comment: 4 aps formatted revtex pages; 3 figures; to be published in Phys. Rev. Let

Synthesis, Crystal Structure and Photophysical Properties of Lanthanide Coordination Polymers of 4- 4-(9H-Carbazol-9-Yl)Butoxy Benzoate: The Effect of Bidentate Nitrogen Donors on Luminescence

A new aromatic carboxylate ligand, 4-[4-(9H-carbazol-9-yl)butoxy]benzoic acid (HL), has been synthesized by the replacement of the hydroxyl hydrogen of 4-hydroxy benzoic acid with a 9-butyl-9H-carbazole moiety. The anion derived from HL has been used for the support of a series of lanthanide coordination compounds [Ln = Eu (1), Gd (2) and Tb (3)]. The new lanthanide complexes have been characterized by a variety of spectroscopic techniques. Complex 3 was structurally authenticated by single-crystal X-ray diffraction and found to exist as a solvent-free 1D coordination polymer with the formula [Tb(L)(3)](n). The structural data reveal that the terbium atoms in compound 3 reside in an octahedral ligand environment that is somewhat unusual for a lanthanide. It is interesting to note that each carboxylate group exhibits only a bridging-bidentate mode, with a complete lack of more complex connectivities that are commonly observed for extended lanthanide-containing solid-state structures. Examination of the packing diagram for 3 revealed the existence of two-dimensional molecular arrays held together by means of CH-pi interactions. Aromatic carboxylates of the lanthanides are known to exhibit highly efficient luminescence, thus offering the promise of applicability as optical devices. However, due to difficulties that arise on account of their polymeric nature, their practical application is somewhat limited. Accordingly, synthetic routes to discrete molecular species are highly desirable. For this purpose, a series of ternary lanthanide complexes was designed, synthesized and characterized, namely [Eu(L)(3)(phen)] (4), [Eu(L)(3)(tmphen)] (5), [Tb(L)(3)(phen)] (6) and [Tb(L)(3)(tmphen)] (7) (phen = 1,10-phenanthroline and tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline). The photophysical properties of the foregoing complexes in the solid state at room temperature have been investigated. The quantum yields of the ternary complexes 4 (9.65%), 5 (21.00%), 6 (14.07%) and 7 (32.42%), were found to be significantly enhanced in the presence of bidentate nitrogen donors when compared with those of the corresponding binary compounds 1 (0.11%) and 3 (1.45%). Presumably this is due to effective energy transfer from the ancillary ligands.Council of Scientific and Industrial Research (CSIR-TAPSUN Project) SSL, NWP-55CSIR, New DelhiRobert A. Welch Foundation F-0003Chemistr

Transport and magnetic anomalies due to A-site ionic size mismatch in La0.5_{0.5}Ca0.5−x_{0.5-x}Ba_{x}MnO3_3

We present results of electrical resistivity, magnetoresistance and ac and dc magnetic susceptibility on polycrystalline samples of the type La(0.5)Ca(0.5-x)Ba(x)MnO(3) synthesized under identical heat treatment conditions. The substitution of larger Ba ions for Ca results in a non- monotonic variation of the curie temperature as the system evolves from a charge ordered insulating state for x=0 to a ferromagnetic metallic state for x=0.5. An intermediate compositino, x=0.1, interestingly exhibits ferromagnetic. insulating behaviour with thermal hysteresis in ac chi around the curie tem- perature (120K). The x=0.2 and 0.3 compounds exhibit semiconducting like behavior as the temperature is lowered below 300K, with a broad peak in rho around 80-100K: These compositions exhibit a weak increase in rho as the temperature lowered below 30K, indicative of electron localization effects. These compositions also undergo ferromagnetic transitions below about 200 and 235K respectively, though these are non-hysteretic; above all, for these compositions, MR is large and conveniently measurable over the entire tempera- ture range of measurement below Tc. This experimental finding may be of interest from the application point of view. We infer that the A-site ionic-size mismatch plays a crucial role in the deciding these properties.Comment: 5 pages, 6 Figures, Resubmitted with extended abstract on 26 Nov, 199

Towards Benchmarking Scene Background Initialization

Given a set of images of a scene taken at different times, the availability of an initial background model that describes the scene without foreground objects is the prerequisite for a wide range of applications, ranging from video surveillance to computational photography. Even though several methods have been proposed for scene background initialization, the lack of a common groundtruthed dataset and of a common set of metrics makes it difficult to compare their performance. To move first steps towards an easy and fair comparison of these methods, we assembled a dataset of sequences frequently adopted for background initialization, selected or created ground truths for quantitative evaluation through a selected suite of metrics, and compared results obtained by some existing methods, making all the material publicly available.Comment: 6 pages, SBI dataset, SBMI2015 Worksho

Shaping social literacy through HIV in Higher Education curricula

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Three Li-rich K giants: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952

We report on spectroscopic analyses of three K giants previously suggested to be Li-rich: IRAS 12327-6523, IRAS 13539-4153, and IRAS 17596-3952. High-resolution optical spectra and the LTE model atmospheres are used to derive the stellar parameters: ($T_{\rm eff}$, log $g$, [Fe/H]), elemental abundances, and the isotopic ratio $^{12}$C/$^{13}$C. IRAS 13539-4153 shows an extremely high Li abundance of $\log\epsilon$(Li) $\approx$ 4.2, a value ten times more than the present Li abundance in the local interstellar medium. This is the third highest Li abundance yet reported for a K giant. IRAS 12327-6523 shows a Li abundances of $\log\epsilon$(Li)$\approx$ 1.4. IRAS 17596-3952 is a rapidly rotating ($V{\sin i}$ $\approx$ 35 km s$^{-1}$) K giant with $\log\epsilon$(Li) $\approx$ 2.2. Infrared photometry which shows the presence of an IR excess suggesting mass-loss. A comparison is made between these three stars and previously recognized Li-rich giants.Comment: 17 pages, 6 figures, accepted for A