Sc, Cr, Co, Ni, Th and rare earth elements systematics in black shales of Murav’inskaya and Velsovskaya formations (Lyapin-Kutim anticlinorium, the Northern Urals): to the provenance reconstructions

The features of the Sc, Cr, Co, Ni, Th and rare earth elements distribution in the black shales of the Riphean Murav’inskaya and Velsovskaya formations in southern part of the Lyapin-Kutim anticlinorium (Northern Ural) are analyzed. The contents of the listed elements in 20 samples of black shales are determined by the ICP-MS method at the IGG UB RAS (Ekaterinburg). Samples of the shales of the Murav’insky formation are selected from the outcrops along the river Vels, below the mouth of Pos’mak River, as well as along Pravaya Rassokha River. The selection was made from outcrops more or less evenly distributed over the studied area. The shales of the Velsovskaya formation were studied from the drilling holes in the basin of Sur’ya Vagranskaya River, as well as in outcrops along the Sibiryakovskaya Martayka and Pravaya Rassokha rivers. In the Sc-Th/Sc diagram, the data points of the black shales of the Murav’inskaya and Velsovskaya formations are fairly compact located between the points of the average composition of the Archean and Proterozoic granites, on the one hand, and tonalite-trondhjemite-granite (TTG) associations of the same age. Approximately the same distribution of the data points of the black shales of these formations can be seen in the La/Sc-Th/Co and La/Sm-Sc/Th diagrams. The average value of ΣРЗЭ in black shales of the Murav’inskaya formation is 316 ± 90 ppm, in the shales of the Velsovskaya Formation it is noticeably lower - 200 ± 47 ppm. The black shales of the Murav’inskaya Formation are substantially enriched with light lanthanides (La/Yb)Nmean = 40, and noticeably depleted by heavy lanthanides, (Gd/Yb)Nmean = 5.4. For the black shales of the Velsovsky formation (La/Yb)Nmean = 22, (Gd/Yb)Nmean = 3.1. This ones and a number of the other data make it possible to conclude that the complexes of rock-sources of fine aluminosiliciclastics for black shales of Murav’inskaya and Velsovskaya formations had a rather specific composition. On the basis of a comparison of the geochemical features of the black shales of the southern part of the Lyapin-Kutim anticlinorium and potential sources of fine aluminosiliciclastics, the conclusion is based that such rock complexes could be, from one side, the Archean and/or Proterozoic TTG associations and granites of the same age of the Eastern European platform, and, from another side, certain local rocks with high Cr contents and significant differentiation of REE, similar in composition to the products of kimberlite magmatism

The results of U-Pb SHRIMP-II dating of zircon from granitoids of Talitsky molybdenum-bearing massif (eastern slope of the Middle Urals)

Age position and geodynamic conditions of molybdenum metallization and productive granitoids of the Urals formation are very little studied now. This publication contains the results of isotopic dating of granites from Talitsa Cu-Mo-porphyry deposit which should help solve this problem. The timing of formation of the molybdenum-bearing granitoids of Talitsa deposit was determined by applying the U-Pb SHRIMP-II method through zircons (the Center for Isotopic Research of All Russian Geological Research Institute, St.Petersburg). The U-Pb-age has been calculated on 7 (from a total of 11 conduc­ted) measurements with probability of concordanсе 0.996 and MSWD = 0.105 and it is 297.4 ± 2.3 Ma. The results of U-Pb dating are similar to before published Re-Os ages of Talitsa molybdenite deposit: 299.9 ± ± 2.9 Ma and 298.3 ± 1.3 Ma. These data establishes the new unknown before age level of molybdenum metallization. Until recently there has been only data on the Yuzhno-Shameiskoe molybdenum deposit connected with the subalkaline granites of Malyshevo massif which is younger: 277.1 ± 1.1 Ma. According to the received data, the intrusion of investigated granitoids happened practically at the same time as the formation of the wide-spread in the western slope of the Middle Urals intrusive bodies which are accompanied by gold metallization (Verkhisetsky, Shartashsky and others). With such close (practically the same) time of formation the rocks of molybdenum-bearing and gold-bearing massifs significantly differ in petrochemical peculiarities, which probably determines their metallogenetic specialization. Granitoids forming gold-bearing quartz veins on chemical composition are rocks of calc-alkaline series (typical exemple - Shartashskyi massif with Beriozovsk gold deposite). The granitoids productive on of Cu-Mo-porphyry type metallization together with large number of normal alkalinity rocks includes subalkaline rocks such as monzodiorites and quartz monzodiorites