1,608 research outputs found
A growth walk model for estimating the canonical partition function of Interacting Self Avoiding Walk
We have explained in detail why the canonical partition function of
Interacting Self Avoiding Walk (ISAW), is exactly equivalent to the
configurational average of the weights associated with growth walks, such as
the Interacting Growth Walk (IGW), if the average is taken over the entire
genealogical tree of the walk. In this context, we have shown that it is not
always possible to factor the the density of states out of the canonical
partition function if the local growth rule is temperature-dependent. We have
presented Monte Carlo results for IGWs on a diamond lattice in order to
demonstrate that the actual set of IGW configurations available for study is
temperature-dependent even though the weighted averages lead to the expected
thermodynamic behavior of Interacting Self Avoiding Walk (ISAW).Comment: Revised version consisting of 12 pages (RevTeX manuscript, plus three
.eps figure files); A few sentences in the second paragraph on Page 4 are
rewritten so as to make the definition of the genealogical tree, , clearer. Also, the second equality of Eq.(1) on Page 4, and its
corresponding statement below have been remove
Chern-Simons Reduction and non-Abelian Fluid Mechanics
We propose a non-Abelian generalization of the Clebsch parameterization for a
vector in three dimensions. The construction is based on a group-theoretical
reduction of the Chern-Simons form on a symmetric space. The formalism is then
used to give a canonical (symplectic) discussion of non-Abelian fluid
mechanics, analogous to the way the Abelian Clebsch parameterization allows a
canonical description of conventional fluid mechanics.Comment: 12 pages, REVTeX; revised for publication in Phys Rev D; email to
[email protected]
Interacting Growth Walk - a model for hyperquenched homopolymer glass?
We show that the compact self avoiding walk configurations, kinetically
generated by the recently introduced Interacting Growth Walk (IGW) model, can
be considered as members of a canonical ensemble if they are assigned random
values of energy. Such a mapping is necessary for studying the thermodynamic
behaviour of this system. We have presented the specific heat data for the IGW,
obtained from extensive simulations on a square lattice; we observe a broad
hump in the specific heat above the -point, contrary to expectation.Comment: 4 figures; Submitted to PR
Recovery of Ammonium Nitrate and Reusable Acetic Acid from Effluent Generated during HMX Production
Production of HMX on commercial scale is mainly carried out by modified Bachmann process, and acetic acid constitutes major portion of effluenttspent liquor produced during this process. The recovery of glacial acetic acid from this spent liquor is essential to make the process commercially viable besides making it eco-friendly by minimising the quantity of disposable effluent. The recovery of glacial acetic acid from spent liquor is not advisable by simple distillation since it contains, in addition to acetic acid, a small fraction of nitric acid, traces of RDX, HMX, and undesired nitro compounds. The process normally involves neutralising the spent mother liquor with liquor ammonia and then distillating the ueutralised mother liquor under vacuum to recover dilute acetic acid (strength approx. 30 %). The dilute acetic acid, in turn, is concentrated to glacial acetic acid by counter current solvent extraction, followed by distillation. The process is very lengthy and the energy requirement is also veryhigh, rendering the process economically unviable. Hence, a novel method has been developed on bench-scale to obtain glacial acetic acid directly from the mother liquor after the second ageing process
Two-Dimensional Magnetic Resonance Tomographic Microscopy using Ferromagnetic Probes
We introduce the concept of computerized tomographic microscopy in magnetic
resonance imaging using the magnetic fields and field gradients from a
ferromagnetic probe. We investigate a configuration where a two-dimensional
sample is under the influence of a large static polarizing field, a small
perpendicular radio-frequency field, and a magnetic field from a ferromagnetic
sphere. We demonstrate that, despite the non-uniform and non-linear nature of
the fields from a microscopic magnetic sphere, the concepts of computerized
tomography can be applied to obtain proper image reconstruction from the
original spectral data by sequentially varying the relative sample-sphere
angular orientation. The analysis shows that the recent proposal for atomic
resolution magnetic resonance imaging of discrete periodic crystal lattice
planes using ferromagnetic probes can also be extended to two-dimensional
imaging of non-crystalline samples with resolution ranging from micrometer to
Angstrom scales.Comment: 9 pages, 11 figure
- …