112 research outputs found
Stress-Transfer in Anisotropic and Environmentally Adaptive Cellulose Whisker Nanocomposites
Development of a stimuli-responsive polymer nanocomposite toward biologically optimized, MEMS-based neural probes
Investigating the Interaction of Cellulose Nanofibers Derived from Cotton with a Sophisticated 3D Human Lung Cell Coculture
Mechanical, thermal, and barrier properties of methylcellulose/cellulose nanocrystals nanocomposites
Effective functionalization of carbon nanotubes for bisphenol F epoxy matrix composites
Morphing in nature and beyond: a review of natural and synthetic shape-changing materials and mechanisms
Shape-changing materials open an entirely new solution space for a wide range of disciplines: from architecture that responds to the environment and medical devices that unpack inside the body, to passive sensors and novel robotic actuators. While synthetic shape-changing materials are still in their infancy, studies of biological morphing materials have revealed key paradigms and features which underlie efficient natural shape-change. Here, we review some of these insights and how they have been, or may be, translated to artificial solutions. We focus on soft matter due to its prevalence in nature, compatibility with users and potential for novel design. Initially, we review examples of natural shape-changing materials—skeletal muscle, tendons and plant tissues—and compare with synthetic examples with similar methods of operation. Stimuli to motion are outlined in general principle, with examples of their use and potential in manufactured systems. Anisotropy is identified as a crucial element in directing shape-change to fulfil designed tasks, and some manufacturing routes to its achievement are highlighted. We conclude with potential directions for future work, including the simultaneous development of materials and manufacturing techniques and the hierarchical combination of effects at multiple length scales.</p
Water-responsive mechanically adaptive nanocomposites based on styrene-butadiene rubber and cellulose nanocrystals - processing matters
Biomimetic, stimuli-responsive polymer nanocomposites based on a hydrophobic styrene-butadiene rubber (SBR) matrix and rigid, rod-like cellulose nanocrystals (CNCs) isolated from cotton were prepared by three different approaches, and their properties were studied and related to the composition, processing history, and exposure to water as a stimulus. The first processing approach involved mixing an aqueous SBR latex with aqueous CNC dispersions, and films were subsequently formed by solution-casting. The second method utilized the first protocol, but films were additionally compression-molded. The third method involved the formation of a CNC organogel via a solvent exchange with acetone, followed by infusing this gel, in which the CNCs form a percolating network with solutions of SBR in tetrahydrofuran. The thermomechanical properties of the materials were established by dynamic mechanical thermal analysis (DMTA). In the dry state, all nanocomposites show much higher tensile storage moduli, E′, than the neat SBR or the SBR latex. E′ increases with the CNC content and depends strongly on the processing method, which appears to influence the morphology of the SBR nanocomposites produced. The highest E′ values were observed for the solution cast samples involving an SBR latex, where E′ increased from 3 MPa for the neat SBR to ca. 740 MPa for the nanocomposite containing 20% v/v CNCs. Upon submersion in deionized water, a dramatic reduction of E′ was observed, for example from 740 to 5 MPa for the solution-cast nanocomposite containing 20% v/v CNCs. This change is interpreted as a disengagement of the percolating CNC network, on account of modest aqueous swelling and competitive hydrogen bonding of water molecules with the CNCs. It is shown that the method of preparation also influenced the swelling behavior and kinetics of modulus switching, consistent with different arrangements of the CNCs, which serve as channels for water absorption and transport within the hydrophobic SBR matrix
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