Spin susceptibility in small Fermi energy systems: effects of nonmagnetic impurities

In small Fermi energy metals, disorder can deeply modify superconducting state properties leading to a strong suppression of the critical temperature $T_c$. In this paper, we show that also normal state properties can be seriously influenced by disorder when the Fermi energy $E_{\rm F}$ is sufficiently small. We calculate the normal state spin susceptibility $\chi$ for a narrow band electron-phonon coupled metal as a function of the non-magnetic impurity scattering rate $\gamma_{\rm imp}$. We find that as soon as $\gamma_{\rm imp}$ is comparable to $E_{\rm F}$, $\chi$ is strongly reduced with respect to its value in the clean limit. The effects of the electron-phonon interaction including the nonadiabatic corrections are discussed. Our results strongly suggest that the recent finding on irradiated MgB$_2$ samples can be naturally explained in terms of small $E_{\rm F}$ values associated with the $\sigma$-bands of the boron plane, sustaining therefore the hypothesis that MgB$_2$ is a nonadiabatic metal.Comment: 7 pages, 6 eps figures, to appear on Eur. Phys. J.

The physical origin of the electron-phonon vertex correction

The electron-phonon vertex correction has a complex structure both in momentum and frequency. We explain this structure on the basis of physical considerations and we show how the vertex correction can be decomposed into two terms with different physical origins. In particular, the first term describes the lattice polarization induced by the electrons and it is essentially a single-electron process whereas the second term is governed by the particle-hole excitations due to the exchange part of the phonon-mediated electron-electron interaction. We show that by weakening the influence of the exchange interaction the vertex takes mostly positive values giving rise to an enhanced effective coupling in the scattering with phonons. This weakening of the exchange interaction can be obtained by lowering the density of the electrons, or by considering only long-ranged (small q) electron-phonon couplings. These findings permit to understand why in the High-Tc materials the small carrier density and the long ranged electron-phonon interaction may play a positive role in enhancing Tc.Comment: 11 pages, 5 postscript figure

s- and d-wave Symmetries in Nonadiabatic Theory of Superconductivity

High-$T_c$ superconductors have Fermi energies $E_F$ much smaller than conventional metals comparable to phonon frequencies. In such a situation nonadiabatic effects are important. A generalization of Eliashberg theory in the nonadiabatic regime has previously been shown to reproduce some anomalous features of the high-$T_c$ superconductors as for istance the enhancement of $T_c$ or the isotopic effects on $T_c$ and $m^*$. In this contribution we address the issue of the symmetry of the gap in the context of nonadiabatic superconductivity. We show that vertex corrections have a momentum structure which favours d-wave superconductivity when forward scattering is predominant. An additional increase of $T_c$ is also found.Comment: 6 pages, 3 eps figure, ijmpb-macros, proceeding of SATT10, to appear on Int. Journ. Mod. Phys.

A survey of nonadiabatic superconductivity in cuprates and fullerides

High-$T_c$ superconductors are characterized by very low carrier densities. This feature leads to two fundamental consequences: on one hand the Fermi energies are correspondingly small and they can be of the same order of phonon frequencies. In such a situation nonadiabatic corrections arising from the breakdown of Migdal's theorem can not be longer neglected. In addition, small carrier densities imply poor screening and correlation effects have to be taken into account. We present a comprehensive overview of the theory of superconductivity generalized into the nonadiabatic regime which is qualitatively different from the conventional one. In this framework some of the observed properties of the cuprates and the fullerene compounds can be naturally accounted for, and a number of theoretical predictions are proposed that can be experimentally tested.Comment: 1 eps figure, ijmpb-macros, proceeding of SATT10, to appear on Int. Journ. Mod. Phys.

High TcT_c superconductivity in MgB2_2 by nonadiabatic pairing

The evidence for the key role of the $\sigma$ bands in the electronic properties of MgB$_2$ points to the possibility of nonadiabatic effects in the superconductivity of these materials. These are governed by the small value of the Fermi energy due to the vicinity of the hole doping level to the top of the $\sigma$ bands. We show that the nonadiabatic theory leads to a coherent interpretation of $T_c = 39$ K and the boron isotope coefficient $\alpha_{\rm B} = 0.30$ without invoking very large couplings and it naturally explains the role of the disorder on $T_c$. It also leads to various specific predictions for the properties of MgB$_2$ and for the material optimization of these type of compounds.Comment: 4 revtex pages, 3 eps figures, to appear on Phys. Rev. Let

Relevance of multiband Jahn-Teller effects on the electron-phonon interaction in A3A_3C60_{60}

Assessing the effective relevance of multiband effects in the fullerides is of fundamental importance to understand the complex superconducting and transport properties of these compounds. In this paper we investigate in particular the role of the multiband effects on the electron-phonon (el-ph) properties of the $t_{1u}$ bands coupled with the Jahn-Teller intra-molecular $H_g$ vibrational modes in the C$_{60}$ compounds. We show that, assuming perfect degeneracy of the electronic bands, vertex diagrams arising from the breakdown of the adiabatic hypothesis, are one order of magnitude smaller than the non-crossing terms usually retained in the Migdal-Eliashberg (ME) theory. These results permit to understand the robustness on ME theory found by numerical calculations. The effects of the non degeneracy of the $t_{1u}$ in realistic systems are also analyzed. Using a tight-binding model we show that the el-ph interaction is mainly dominated by interband scattering within a single electronic band. Our results question the reliability of a degenerate band modeling and show the importance of these combined effects in the $A_3$C$_{60}$ family.Comment: 5 pages, 3 eps figure

Anomalous impurity effects in nonadiabatic superconductors

We show that, in contrast with the usual electron-phonon Migdal-Eliashberg theory, the critical temperature Tc of an isotropic s-wave nonadiabatic superconductor is strongly reduced by the presence of diluted non-magnetic impurities. Our results suggest that the recently observed Tc-suppression driven by disorder in K3C60 [Phys. Rev. B vol.55, 3866 (1997)] and in Nd(2-x)CexCuO(4-delta) [Phys. Rev. B vol.58, 8800 (1998)] could be explained in terms of a nonadiabatic electron-phonon coupling. Moreover, we predict that the isotope effect on Tc has an impurity dependence qualitatively different from the one expected for anisotropic superconductors.Comment: 10 pages, euromacr.tex, europhys.sty, 6 figures. Replaced with accepted version (Europhysics Letters