18 research outputs found

    MODELISATION DE L'INFLUENCE DU TRAITEMENT THERMIQUE SUR LES PROPRIETES MECANIQUES DES ALLIAGES ALUMINIUM-CUIVRE (Al-Cu)

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    In order to master and improve the quality and properties of the final products, the major industrial challenge lies in the possibility of controlling the morphology, size of microstructures that reside within the molded pieces, as well as their defects; this is the fundamental reason according to which we are more and more interested in mastering the growth and germination of such alloys, as well as the developing structures, at the time of solidification process. The modeling reveals as a valuable aid in the mastery of the formation of such heterogeneousness: segregation cells that are incompatible with industrial requirements. The whole work focuses upon the modeling of the segregation phenomenon of the four hypoeutectic alloys, Al1%Cu, Al2%Cu, Al3%Cu et Al4%Cu, as well as the copper effect upon certain mechanical properties of aluminum. Usually, the microstructure and mechanical behavior of such alloys as Al-Cu are directly influenced by some parameters such as composition, cooling velocity and homogenization process

    Thermodynamic modelling of the La-Pb Binary system

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    The thermodynamic modelling of the La-Pb binary system was carried out with the help of CALPHAD (CALculation of PHAse Diagram) method. La5Pb3, La4Pb3, La5Pb4, αLa3Pb4, βLa3Pb4, LaPb2, LaPb3 have been treated as stoichiometric compounds while a solution model has been used for the description of the liquid, BCC and FCC phases. The calculations based on the thermodynamic modeling are in good agreement with the phase diagram data and experimental thermodynamic values

    Airflow and microclimate patterns in a one-hectare Canary type greenhouse: an experimental and CFD assisted study

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    This study presents an analysis of air circulation and microclimate distribution during daytime in a 1-hectare Canary type tomato greenhouse in the coastal area of southern Morocco. The investigation of the climate inside the greenhouse is based on a numerical simulation using a finite volumes method to solve the mass, momentum and energy conservation equations. The main novelty of this simulation lies in the realism of the 3D modelling of this very large agricultural structure with (i) a coupling of convective and radiative exchanges at the surface of the plastic roof cover, (ii) simulation of the dynamic influence of the insect screens and tomato crop on airflow movement, using the concept of porous medium, (iii) simulation, in each grid cell of the crop canopy, of the sensible and latent heat exchanges between the greenhouse air and the tomato crop, and (iv) detailed simulation of climate parameters in a 1-hectare real-scale commercial greenhouse. The model simulations were first validated with respect to temperature and relative humidity fields measured inside the experimental greenhouse for fairly steady-state outside conditions marked by a prevailing sea breeze around the solar noon. A good agreement was observed between the measured and simulated values for inside air temperatures and specific humidity. It was next used for exploring the details of the inside air temperature and humidity fields and plant microclimates and transpiration fluxes throughout the greenhouse space. Simulation for a wind direction perpendicular to the side and roof openings shows that the insect screen significantly reduced inside air velocity and increased inside temperature and humidity, especially in the vicinity of the crop canopy. It revealed the details of the flow field within the greenhouse. At the windward end of the greenhouse, the flow field was marked by a strong windwise air current above the tomato canopy which was fed by the wind ward side vent, and a slow air stream flowing within the tomato canopy space. Then, from the first third of the greenhouse to the leeward end, the flow field was marked by the combination of wind and buoyancy forces, with warmer and more humid inside air which was evacuated through the upper roof vents, while colder and dryer air was penetrated through the upper roof vent openings. Based on these simulations, design studies of the greenhouse crop system were performed to improve inside air temperature and humidity conditions by simple modifications of orientation of the crop row

    Thermodynamic assessment of the Pd–Y binary system

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    The Pd–Y system was critically assessed using the CALPHAD technique. The solution phases (liquid, b.c.c., f.c.c. and h.c.p.) were modeled using the Redlich–Kister equation. The intermetallic compounds Pd3Y and PdY, which have homogeneity ranges, were treated as the formula (Pd,Y)0.75(Pd,Y)0.25 and (Pd,Y)0.5(Pd,Y)0.5 by a two-sublattice model with a mutual substitution of Pd and Y on both sublattices. The optimization was carried out in two steps. In the first treatment, Pd3Y and PdY are assumed to be stoichiometric compounds; in the second treatment they are treated by a sublattice model. The parameters obtained from the first treatment were used as starting values for the second treatment. The calculated phase diagram and the thermodynamic properties of the system are in satisfactory agreement with the experimental data

    Semi-experimental mixing enthalpy of ternary liquid phases as a support of phase-diagrams calculation

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    There exist about 1250 interesting binary systems but more than 22000 ternary ones. For this reason a good experimental investigation of all ternary phase diagrams cannot be expected in the near future. An approach to many ternary systems can be achieved by a phase diagram optimisation, taking into account various experimental incomplete data. In such an objective the mixing enthalpy of the ternary liquid phase can be selected as a general primary thermodynamic information able to scale the different Gibbs functions of all the phases present in the system. In 1991. we have engaged a program to optimise a general procedure with the goal of rapidly obtaining the mixing enthalpy of any ternary metallic liquid phase with the following restrictive conditions :

    Thermodynamic assessment of the Pd–Y binary system

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    The Pd–Y system was critically assessed using the CALPHAD technique. The solution phases (liquid, b.c.c., f.c.c. and h.c.p.) were modeled using the Redlich–Kister equation. The intermetallic compounds Pd3Y and PdY, which have homogeneity ranges, were treated as the formula (Pd,Y)0.75(Pd,Y)0.25 and (Pd,Y)0.5(Pd,Y)0.5 by a two-sublattice model with a mutual substitution of Pd and Y on both sublattices. The optimization was carried out in two steps. In the first treatment, Pd3Y and PdY are assumed to be stoichiometric compounds; in the second treatment they are treated by a sublattice model. The parameters obtained from the first treatment were used as starting values for the second treatment. The calculated phase diagram and the thermodynamic properties of the system are in satisfactory agreement with the experimental data
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