Dynamical mean-field theory for bosons

We discuss the recently developed bosonic dynamical mean-field (B-DMFT) framework, which maps a bosonic lattice model onto the selfconsistent solution of a bosonic impurity model with coupling to a reservoir of normal and condensed bosons. The effective impurity action is derived in several ways: (i) as an approximation to the kinetic energy functional of the lattice problem, (ii) using a cavity approach, and (iii) by using an effective medium approach based on adding a one-loop correction to the selfconsistently defined condensate. To solve the impurity problem, we use a continuous-time Monte Carlo algorithm based on a sampling of a perturbation expansion in the hybridization functions and the condensate wave function. As applications of the formalism we present finite temperature B-DMFT phase diagrams for the bosonic Hubbard model on a 3d cubic and 2d square lattice, the condensate order parameter as a function of chemical potential, critical exponents for the condensate, the approach to the weakly interacting Bose gas regime for weak repulsions, and the kinetic energy as a function of temperature.Comment: 26 pages, 19 figure

Theory of Bose-Einstein condensation for trapped atoms

We outline the general features of the conventional mean-field theory for the description of Bose-Einstein condensates at near zero temperatures. This approach, based on a phenomenological model, appears to give excellent agreement with experimental data. We argue, however, that such an approach is not rigorous and cannot contain the full effect of collisional dynamics due to the presence of the mean-field. We thus discuss an alternative microscopic approach and explain, within our new formalism, the physical origin of these effects. Furthermore, we discuss the potential formulation of a consistent finite-temperature mean-field theory, which we claim necessiates an analysis beyond the conventional treatment.Comment: 12 pages. To appear in Phil. Trans. R. Soc. Lond. A 355 (1997

Phase separation of Bose-Einstein condensates

The zero-temperature system of two dilute overlapping Bose-Einstein condensates is unstable against long wavelength excitations if the interaction strength between the distinguishable bosons exceeds the geometric mean of the like-boson interaction strengths. If the condensates attract each other, the instability is similar to the instability of the negative scattering length condensates. If the condensates repel, they separate spatially into condensates of equal pressure. We estimate the boundary size, surface tension and energy of the phase separated condensate system and we discuss the implications for double condensates in atomic traps.Comment: 11 pages, 1 figur

Infrared behavior of interacting bosons at zero temperature

We review the infrared behavior of interacting bosons at zero temperature. After a brief discussion of the Bogoliubov approximation and the breakdown of perturbation theory due to infrared divergences, we present two approaches that are free of infrared divergences -- Popov's hydrodynamic theory and the non-perturbative renormalization group -- and allow us to obtain the exact infrared behavior of the correlation functions. We also point out the connection between the infrared behavior in the superfluid phase and the critical behavior at the superfluid--Mott-insulator transition in the Bose-Hubbard model.Comment: 8 pages, 4 figures. Proceedings of the 19th International Laser Physics Workshop, LPHYS'10 (Foz do Iguacu, Brazil, July 5-9, 2010

Ground state at high density

Weak limits as the density tends to infinity of classical ground states of integrable pair potentials are shown to minimize the mean-field energy functional. By studying the latter we derive global properties of high-density ground state configurations in bounded domains and in infinite space. Our main result is a theorem stating that for interactions having a strictly positive Fourier transform the distribution of particles tends to be uniform as the density increases, while high-density ground states show some pattern if the Fourier transform is partially negative. The latter confirms the conclusion of earlier studies by Vlasov (1945), Kirzhnits and Nepomnyashchii (1971), and Likos et al. (2007). Other results include the proof that there is no Bravais lattice among high-density ground states of interactions whose Fourier transform has a negative part and the potential diverges or has a cusp at zero. We also show that in the ground state configurations of the penetrable sphere model particles are superposed on the sites of a close-packed lattice.Comment: Note adde

Oligothiophene Nanoparticies: Photophysical and Electrogenerated Chemiluminescence Studies

Thiophene oligomer nanoparticles (NPs) were studied by fluorescence spectroscopy and electrogenerated chemiluminescence (ECL). Distinct spectroscopic differences between aggregates or NPs of thiophene hexamers having differing substitution patterns of solubilizing alkyl groups were observed. The alpha,omega-unsubstituted thiophene hexamer, Hexamer-2, exhibited fluorescence properties that were similar in solution and as colloidal NPs; there was only a small red shift compared with what was observed for the discrete system dissolved in tetrahydrofuran (THF). In contrast, the oligomer substituted in the alpha,omega-positions with branched alkyl substituents (Hexamer-1) displayed a gradual bathochromic shift of the fluorescence maximum in proportion to the amount of a poor solvent (water) added to the THF solution. Moreover, the fluorescence characteristics for the oligomer(s) dissolved in a mixture of THF and water were similar to those seen by annihilation ECL in a mixture of benzene/acetonitrile. On this basis, we conclude that annihilation ECL may be a useful technique for monitoring the formation of organic nanoparticles