191 research outputs found
Large-scale Graphitic Thin Films Synthesized on Ni and Transferred to Insulators: Structural and Electronic Properties
We present a comprehensive study of the structural and electronic properties
of ultrathin films containing graphene layers synthesized by chemical vapor
deposition (CVD) based surface segregation on polycrystalline Ni foils then
transferred onto insulating SiO2/Si substrates. Films of size up to several
mm's have been synthesized. Structural characterizations by atomic force
microscopy (AFM), scanning tunneling microscopy (STM), cross-sectional
transmission electron microscopy (XTEM) and Raman spectroscopy confirm that
such large scale graphitic thin films (GTF) contain both thick graphite regions
and thin regions of few layer graphene. The films also contain many wrinkles,
with sharply-bent tips and dislocations revealed by XTEM, yielding insights on
the growth and buckling processes of the GTF. Measurements on mm-scale
back-gated transistor devices fabricated from the transferred GTF show
ambipolar field effect with resistance modulation ~50% and carrier mobilities
reaching ~2000 cm^2/Vs. We also demonstrate quantum transport of carriers with
phase coherence length over 0.2 m from the observation of 2D weak
localization in low temperature magneto-transport measurements. Our results
show that despite the non-uniformity and surface roughness, such large-scale,
flexible thin films can have electronic properties promising for device
applications.Comment: This version (as published) contains additional data, such as cross
sectional TEM image
UV continuum emission and diagnostics of hydrogen-containing non-equilibrium plasmas
For the first time the emission of the radiative dissociation continuum of
the hydrogen molecule ( electronic
transition) is proposed to be used as a source of information for the
spectroscopic diagnostics of non-equilibrium plasmas. The detailed analysis of
excitation-deactivation kinetics, rate constants of various collisional and
radiative transitions and fitting procedures made it possible to develop two
new methods of diagnostics of: (1) the ground state
vibrational temperature from the relative intensity
distribution, and (2) the rate of electron impact dissociation
(d[\mbox{H_{2}}]/dt)_{\text{diss}} from the absolute intensity of the
continuum. A known method of determination of from relative
intensities of Fulcher- bands was seriously corrected and simplified
due to the revision of transition probabilities and cross sections of
electron impact excitation. General considerations are illustrated
with examples of experiments in pure hydrogen capillary-arc and H+Ar
microwave discharges.Comment: REVTeX, 25 pages + 12 figures + 9 tables. Phys. Rev. E, eprint
replaced because of resubmission to journal after referee's 2nd repor
Optimal values of rovibronic energy levels for triplet electronic states of molecular deuterium
Optimal set of 1050 rovibronic energy levels for 35 triplet electronic states
of has been obtained by means of a statistical analysis of all available
wavenumbers of triplet-triplet rovibronic transitions studied in emission,
absorption, laser and anticrossing spectroscopic experiments of various
authors. We used a new method of the analysis (Lavrov, Ryazanov, JETP Letters,
2005), which does not need any \it a priory \rm assumptions concerning the
molecular structure being based on only two fundamental principles:
Rydberg-Ritz and maximum likelihood. The method provides the opportunity to
obtain the RMS estimates for uncertainties of the experimental wavenumbers
independent from those presented in original papers. 234 from 3822 published
wavenumber values were found to be spurious, while the remaining set of the
data may be divided into 20 subsets (samples) of uniformly precise data having
close to normal distributions of random errors within the samples. New
experimental wavenumber values of 125 questionable lines were obtained in the
present work. Optimal values of the rovibronic levels were obtained from the
experimental data set consisting of 3713 wavenumber values (3588 old and 125
new). The unknown shift between levels of ortho- and para- deuterium was found
by least squares analysis of the , ,
rovibronic levels with odd and even values of . All the energy levels were
obtained relative to the lowest vibro-rotational level (, ) of
the electronic state, and presented in tabular form together
with the standard deviations of the empirical determination. New energy level
values differ significantly from those available in literature.Comment: 46 pages, 9 picture
Extreme stiffness hyperbolic elastic metamaterial for total transmission subwavelength imaging
Subwavelength imaging by metamaterials and extended work to pursue total transmission has been successfully demonstrated with electromagnetic and acoustic waves very recently. However, no elastic counterpart has been reported because earlier attempts suffer from considerable loss. Here, for the first time, we realize an elastic hyperbolic metamaterial lens and experimentally show total transmission subwavelength imaging with measured wave field inside the metamaterial lens. The main idea is to compensate for the decreased impedance in the perforated elastic metamaterial by utilizing extreme stiffness, which has not been independently actualized in a continuum elastic medium so far. The fabricated elastic lens is capable of directly transferring subwavelength information from the input to the output boundary. In the experiment, this intriguing phenomenon is confirmed by scanning the elastic structures inside the lens with laser scanning vibrometer. The proposed elastic metamaterial lens will bring forth significant guidelines for ultrasonic imaging techniquesope
On determination of electronic-vibro-rotational term values of diatomic molecules from measured wavenumbers
A method is proposed for determining rovibronic term values of diatomics from
experimental data on the wavenumbers of electronic-vibro-rotational spectral
lines. In contrast to existing techniques, the new one is based on the
Rydberg-Ritz principle only. It is shown that a link between a set of
rovibronic term values and a set of wavenumbers of observed rovibronic spectral
lines appears when three and more different electronic-vibrational states are
pairwise-connected by radiative transitions. The method differs from known
techniques in several aspects, namely, it: 1) doesn't need any assumptions
concerning an internal structure of a molecule; 2) doesn't involve any
intermediate parameters (as molecular constants in traditional techniques); 3)
gives an opportunity to use in one-stage optimization procedure all available
experimental data obtained for various band systems, by various authors, and in
various works; 4) provides in an interactive mode the opportunity to select the
experimental values, eliminating rough errors, to revise wrong identifications
of spectral lines and to compare various sets of experimental data for mutual
consistency; 5) allows to obtain not only an optimal set of rovibronic term
values, but also the error bars depending on quantity and quality of existing
experimental data. Necessary precondition for use of this method is a
preliminary identification of electronic-vibro-rotational lines to certain
electronic-vibro-rotational radiative transitions. For this purpose one has to
use traditional methods of the analysis of molecular spectra.Comment: 10 pages, 2 figures, in Russia
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