Transforming Dyes into Fluorophores:Exciton-Induced Emission with Chain-like Oligo-BODIPY Superstructures

Herein we present a systematic study demonstrating to which extent exciton formation can amplify fluorescence based on a series of ethylene-bridged oligo-BODIPYs. A set of non- and weakly fluorescent BODIPY motifs was selected and transformed into discrete, chain-like oligomers by linkage via a flexible ethylene tether. The prepared superstructures constitute excitonically active entities with non-conjugated, Coulomb-coupled oscillators. The non-radiative deactivation channels of Internal Conversion (IC), also combined with an upstream reductive Photoelectron Transfer (rPET) and Intersystem Crossing (ISC) were addressed at the monomeric state and the evolution of fluorescence and (non-)radiative decay rates studied along the oligomeric series. We demonstrate that a “masked” fluorescence can be fully reactivated irrespective of the imposed conformational rigidity. This work challenges the paradigm that a collective fluorescence enhancement is limited to sterically induced motional restrictions

Monte Carlo studies of the jet activity in Higgs + 2 jet events

Tree-level studies have shown in the past that kinematical correlations between the two jets in Higgs+2-jet events are direct probes of the Higgs couplings, e.g. of their CP nature. In this paper we explore the impact of higher-order corrections on the azimuthal angle correlation of the two leading jets and on the rapidity distribution of extra jets. Our study includes matrix-element and shower MC effects, for the two leading sources of Higgs plus two jet events at the CERN LHC, namely vector-boson and gluon fusion. We show that the discriminating features present in the previous leading-order matrix element studies survive.Comment: 12 pages, 10 figures. Version to appear on JHEP. Figs. 5-8 replaced with colour version

Matching matrix elements and shower evolution for top-quark production in hadronic collisions

We study the matching of multijet matrix elements and shower evolution in the case of top production in hadronic collisions at the Tevatron and at the LHC. We present the results of the matching algorithm implemented in the ALPGEN Monte Carlo generator, and compare them with results obtained at the parton level, and with the predictions of the MC@NLO approach. We highlight the consistency of the matching algorithm when applied to these final states, and the excellent agreement obtained with MC@NLO for most inclusive quantities. We nevertheless identify also a remarkable difference in the rapidity spectrum of the leading jet accompanying the top quark pair, and comment on the likely origin of this discrepancy.Comment: 22 pages, 13 figures, 5 tables. JHEP styl

Top Quark Physics at the LHC: A Review of the First Two Years

This review summarizes the highlights in the area of top quark physics obtained with the two general purpose detectors ATLAS and CMS during the first two years of operation of the Large Hadron Collider LHC. It covers the 2010 and 2011 data taking periods, where the LHC provided pp collisions at a center-of-mass energy of sqrt(s)=7 TeV. Measurements are presented of the total and differential top quark pair production cross section in many different channels, the top quark mass and various other properties of the top quark and its interactions, for instance the charge asymmetry. Measurements of single top quark production and various searches for new physics involving top quarks are also discussed. The already very precise experimental data are in good agreement with the standard model.Comment: 107 pages, invited review for Int. J. Mod. Phys. A, v2 is identical to v1 except for the addition of the table of content

Dynamic orifice area variations in functional mitral regurgitation: In vivoreproduction and mechanistic insights

Aims: The spinocerebellar ataxia type 2 (SCA2), type 3 (SCA3) and type 7 (SCA7) are clinically characterized by progressive and severe ataxic symptoms, dysarthria, dysphagia, oculomotor impairments, pyramidal and extrapyramidal manifestations and sensory deficits. Although recent clinical studies reported additional disease signs suggesting involvement of the brainstem auditory system, this has never been studied in detail in SCA2, SCA3 or SCA7. Methods: We performed a detailed pathoanatomical investigation of unconventionally thick tissue sections through the auditory brainstem nuclei (that is, nucleus of the inferior colliculus, nuclei of the lateral lemniscus, superior olive, cochlear nuclei) and auditory brainstem fibre tracts (that is, lateral lemniscus, trapezoid body, dorsal acoustic stria, cochlear portion of the vestibulocochlear nerve) of clinically diagnosed and genetically confirmed SCA2, SCA3 and SCA7 patients. Results: Examination of unconventionally thick serial brainstem sections stained for lipofuscin pigment and Nissl material revealed a consistent and widespread involvement of the auditory brainstem nuclei in the SCA2, SCA3 and SCA7 patients studied. Serial brainstem tissue sections stained for myelin showed loss of myelinated fibres in two of the auditory brainstem fibre tracts (that is, lateral lemniscus, trapezoid body) in a subset of patients. Conclusions: The involvement of the auditory brainstem system offers plausible explanations for the auditory impairments detected in some of our and other SCA2, SCA3 and SCA7 patients upon bedside examination or neurophysiological investigation. However, further clinical studies are required to resolve the striking discrepancy between the consistent involvement of the brainstem auditory system observed in this study and the comparatively low frequency of reported auditory impairments in SCA2, SCA3 and SCA7 patients

MadGraph/MadEvent v4: The New Web Generation

We present the latest developments of the MadGraph/MadEvent Monte Carlo event generator and several applications to hadron collider physics. In the current version events at the parton, hadron and detector level can be generated directly from a web interface, for arbitrary processes in the Standard Model and in several physics scenarios beyond it (HEFT, MSSM, 2HDM). The most important additions are: a new framework for implementing user-defined new physics models; a standalone running mode for creating and testing matrix elements; generation of events corresponding to different processes, such as signal(s) and backgrounds, in the same run; two platforms for data analysis, where events are accessible at the parton, hadron and detector level; and the generation of inclusive multi-jet samples by combining parton-level events with parton showers. To illustrate the new capabilities of the package some applications to hadron collider physics are presented: 1) Higgs search in pp \to H \to W^+W^-: signal and backgrounds. 2) Higgs CP properties: pp \to H jj$in the HEFT. 3) Spin of a new resonance from lepton angular distributions. 4) Single-top and Higgs associated production in a generic 2HDM. 5) Comparison of strong SUSY pair production at the SPS points. 6) Inclusive W+jets matched samples: comparison with the Tevatron data.Comment: 38 pages, 15 figure

W+W-, WZ and ZZ production in the POWHEG BOX

We present an implementation of the vector boson pair production processes ZZ, W+W- and W Z within the POWHEG framework, which is a method that allows the interfacing of NLO calculations to shower Monte Carlo programs. The implementation is built within the POWHEG BOX package. The Z/\gamma^* interference, as well as singly resonant contributions, are properly included. We also considered interference terms arising from identical leptons in the final state. As a result, all contributions leading to the desired four-lepton system have been included in the calculation, with the sole exception of the interference between ZZ and W+W- in the production of a pair of same-flavour, oppositely charged fermions and a pair of neutrinos, which we show to be fully negligible. Anomalous trilinear couplings can be also set in the program, and we give some examples of their effect at the LHC. We have made the relevant code available at the POWHEG BOX web site.Comment: 20 pages, 9 figures, 2 tables. Minor corrections and updated references in revised versio

Scaling Patterns for QCD Jets

Jet emission at hadron colliders follows simple scaling patterns. Based on perturbative QCD we derive Poisson and staircase scaling for final state as well as initial state radiation. Parton density effects enhance staircase scaling at low multiplicities. We propose experimental tests of our theoretical findings in Z+jets and QCD gap jets production based on minor additions to current LHC analyses.Comment: 36 pages, 16 figure

Distortion in a 7xxx aluminum alloy during liquid phase sintering

The distortion in a sintered 7xxx aluminum alloy, Al-7Zn-2.5Mg-1Cu (wt. pct), has been investigated by sintering three rectangular bars in each batch at 893 K (620 °C) for 0 to 40 minutes in nitrogen, followed by air or furnace cooling. They were placed parallel to each other, equally spaced apart at 2 mm, with their long axes being perpendicular to the incoming nitrogen flow. Pore evolution in each sample during isothermal sintering was examined metallographically. The compositional changes across sample mid-cross section and surface layers were analyzed using energy dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy depth profiling, respectively. The two outer samples bent toward the middle one, while the middle sample was essentially distortion free after sintering. The distortion in the outer samples was a result of differential shrinkage between their outer and inner surfaces during isothermal sintering. The porous outer surface showed an enrichment of oxygen around the large pores as well as lower magnesium and zinc contents than the interior and inner surface of the same sample, while the inner surface was distinguished by the presence of AlN. The differential shrinkage was caused by different oxygen contents in local sintering atmosphere and unbalanced loss of magnesium and zinc between the outer and inner surfaces

W b bbar production in POWHEG

We present an implementation of the next-to-leading order hadronic production of a W boson in association with a pair of massive bottom quarks in the framework of POWHEG, a method to consistently interface NLO QCD calculations with shower Monte Carlo generators. The process has been implemented using the POWHEG BOX, an automated computer code that sistematically applies the POWHEG method to NLO QCD calculations. Spin correlations in the decay of the W boson into leptons have been taken into account using standard approximated techniques. We present phenomenological results for W b bbar-> l nu b bbar production, at both the Tevatron and the LHC, obtained by showering the POWHEG results with PYTHIA and HERWIG, and we discuss the outputs of the two different shower Monte Carlo programs.Comment: Corrected a conclusion that turned out to be wron