918 research outputs found

    Evaluation of Half-metallic Antiferromagnetism in A2{\cal A}_2CrFeO6_6 ({A\cal A}=La, Sr

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    The nearly well-ordered double perovskite La2_2CrFeO6_6 has been synthesized recently. Contrary to previous theoretical predictions, but in agreement with experimental observations, our first principle calculations indicate an insulating ferrimagnet La2_2CrFeO6_6 with antialigned S=3/2 Cr3+^{3+} and S=5/2 Fe3+^{3+} ions,using the local spin density approximation (LSDA), a correlated band theory LDA+U, and a semilocal functional modified Becke-Johnson method. Additionally, we investigated the double perovskite Sr2_2CrFeO6_6, which is as yet unsynthesized. In LSDA calculations, this system shows formally tetravalent Cr and Fe ions both having antialigned SS=1 moments, but is a simple metal. Once applying on-site Coulomb repulsion U on both Cr and Fe ions, this system becomes half-metallic and the moment of Fe is substantially reduced, resulting in zero net moment. These results are consistent with our fixed spin moment studies. Our results suggest a precisely compensated half-metallic Sr2_2CrFeO6_6.Comment: 7 page

    Electron and phonon band-structure calculations for the antipolar SrPt3_{3}P antiperovskite superconductor: Evidence of low-energy two-dimensional phonons

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    SrPt3P has recently been reported to exhibit superconductivity with Tc = 8.4 K. To explore its superconducting mechanism, we have performed electron and phonon band calculations based on the density functional theory, and found that the superconductivity in SrPt3P is well described by the strong coupling phonon-mediated mechanism. We have demonstrated that superconducting charge carriers come from pd\pi-hybridized bands between Pt and P ions, which couple to low energy (~ 5 meV) phonon modes confined on the ab in-plane. These in-plane phonon modes, which do not break antipolar nature of SrPt3P, enhance both the electron-phonon coupling constant \lambda and the critical temperature Tc. There is no hint of a specific phonon softening feature in the phonon dispersion, and the effect of the spin-orbit coupling on the superconductivity is found to be negligible.Comment: 5 pages, 5 figures, 1 tabl

    On the trace theorem to Volterra-type equations with local or non-local derivatives

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    This paper considers traces at the initial time for solutions of evolution equations with local or non-local derivatives in vector-valued ApA_p weighted LpL_p spaces. To achieve this, we begin by introducing a generalized real interpolation method. Within the framework of generalized interpolation theory, we make use of stochastic process theory and two-weight Hardy's inequality to derive our trace and extension theorems. Our results encompass findings applicable to time-fractional equations with broad temporal weight functions

    Characterizations of weighted Besov and Triebel-Lizorkin spaces with variable smoothness

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    In this paper, we study different types of weighted Besov and Triebel-Lizorkin spaces with variable smoothness. The function spaces can be defined by means of the Littlewood-Paley theory in the field of Fourier analysis, while there are other norms arising in the theory of partial differential equations such as Sobolev-Slobodeckij spaces. It is known that two norms are equivalent when one considers constant regularity function spaces without weights. We show that the equivalence still holds for variable smoothness and weights, which is accomplished by making use of shifted maximal functions, Peetre's maximal functions, and the reverse H\"older inequality. Moreover, we obtain a weighted regularity estimate for time-fractional evolution equations and a generalized Sobolev embedding theorem without weights.Comment: 36 page

    Quality of Care for Older Patients with Non-Cancer Diagnoses under the End-of-Life Care Program

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    Background: End-of-life (EOL) care is an important part of geriatric medicine in view of rapidly ageing populations in the world. Aim: We aimed to evaluate the quality of care for older patients with non-cancer terminal illnesses, who died in 2010, under the EOL care program of an academic medical unit in Hong Kong. This unit consisted of an acute hospital, Prince of Wales Hospital (PWH) and a convalescence hospital (Shatin Hospital, SH). Methods: This was a retrospective hospital-based audit of clinical effectiveness of the EOL service. We reviewed the quality of patient care during the final seven days of life. The quality of care was evaluated based on the compliance rates of five selected goals and the adoption of futile life-sustaining procedures and treatments. Results: Case records of 129 patients in the EOL care program were analyzed. Two goals, including minimization of regular monitoring of vital signs and no blood taking, achieved over 70% compliance at SH and 0% at PWH. The compliance rates of discontinuation of non-essential medications were 46.4% in SH and 47.1% in PWH; and the compliance rates of switching essential medications to non-oral routes were 63.4% in SH and 70.6% in PWH (not statistically significant). The compliance rates of using as-required intravenous or subcutaneous medications were extremely low (<2%) at both hospitals. All futile life-sustaining procedures and treatments were initiated at the PWH. Conclusions: We demonstrated significant differences in the quality of EOL care between the acute hospital and convalescence hospital. Greater emphasis on specialist training and education with allocation of resources may improve the EOL care in both settings.published_or_final_versio
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