2 research outputs found
Observation of thermodynamics originating from a mixed-spin ferromagnetic chain
We present a model compound that forms a mixed-spin ferromagnetic chain. Our
material design, based on the organic radicals, affords a verdazyl-based
complex (p-Py-V)2[Mn(hfac)2]. The molecular orbital calculations of the
compound indicate the formation of a mixed spin-(1/2, 1/2, 5/2) ferromagnetic
chain. The temperature dependence of magnetic susceptibility reveals its
ferromagnetic behavior. The magnetic specific heat exhibits a double-peak
structure and indicates a phase transition at the low-temperature peak. The
observed characteristics are explained using the quantum Monte Carlo
calculations. Furthermore, the modified spin-wave theory verifies that the
double-peak structure of the specific heat significantly reflects the relative
ration of the acoustic excitation band and the optical excitation gap