3 research outputs found
Evidence for Supercurrent Connectivity in Conglomerate Particles in NdFeAsO1-d
Here we use global and local magnetometry and Hall probe imaging to
investigate the electromagnetic connectivity of the superconducting current
path in the oxygen-deficient fluorine-free Nd-based oxypnictides. High
resolution transmission electron microscopy and scanning electron microscopy
show strongly-layered crystallites, evidence for a ~ 5nm amorphous oxide around
individual particles, and second phase neodymium oxide which may be responsible
for the large paramagnetic background at high field and at high temperatures.
From global magnetometry and electrical transport measurements it is clear
that there is a small supercurrent flowing on macroscopic sample dimensions
(mm), with a lower bound for the average (over this length scale) critical
current density of the order of 103 A/cm2. From magnetometry of powder samples
and local Hall probe imaging of a single large conglomerate particle ~120
microns it is clear that on smaller scales, there is better current
connectivity with a critical current density of the order of 5 x 104 A/cm2. We
find enhanced flux creep around the second peak anomaly in the magnetisation
curve and an irreversibility line significantly below Hc2(T) as determined by
ac calorimetry.Comment: 11 pages, 4 figure
Coulomb repulsion and correlation strength in LaFeAsO from Density Functional and Dynamical Mean-Field Theories
LDA+DMFT (Local Density Approximation combined with Dynamical Mean-Field
Theory) computation scheme has been used to calculate spectral properties of
LaFeAsO -- the parent compound for new high-T iron oxypnictides. Coulomb
repulsion and Hund's exchange parameters for iron 3d electrons were
calculated using \textit {first principles} constrained density functional
theory scheme in Wannier functions formalism. Resulting values strongly depend
on the number of states taken into account in calculations: when full set of
O-, As-, and Fe-3d orbitals with corresponding bands are included,
computation results in 4 eV and J=0.8 eV. In contrast to that when the
basis set is restricted to Fe-3d orbitals and bands only, computation gives
much smaller parameter values =0.8 eV, =0.5 eV. However, DMFT
calculations with both parameter sets and corresponding to them choice of basis
functions result in weakly correlated electronic structure that is in agreement
with experimental X-ray and photoemission spectra.Comment: 13 pages, 9 figure