THE APPLICATION OF NOVEL ORGANIC DEEMULSIFIERS FOR THE SEPARATION OF OIL-IN-WATER EMULSIONS

The paper summarizes the results of tests of separation of oil-in-water emulsions with the application of novel organic deemulsifiers. Fresh and used emulsions of different concentrations were tested. The manipulated variables were: the concentration of oil in the emulsion; the concentration and amount of deemulsifier solution; the temperature. The results of these tests are presented graphically

Modeling of adsorption in a mixing tank

Computational models for adsorption in a tank are presented. The approximate model provides the same results as the exact model. The diffusion coefficient of a dye in an adsorbent pellet and the mass transfer coefficient in a fluid phase were determined on the basis of the measurements of dye adsorption on the activated carbon. It was determined how the fraction of the resistance to mass transfer in the fluid to the overall mass transfer resistance changes during adsorption. It was found that, for the examined system, the main resistance to mass transfer is located in the liquid phase

Application of monte Carlo method for determination of multiple reactions kinetic curves

Kinetic curves for multiple reactions have been determined by the means of the Monte Carlo method. Both reversible and nonreversible parallel, series, series-parallel and autocatalytic reactions have been taken under consideration. The complete consistency between results of stochastic calculations and results obtained with the use of deterministic models has been shown

BATCH ADSORPTION IN A FINITE VOLUME RESERVOIR – APPLICATION OF AN APPROXIMATE KINETIC MODEL

The paper refers to the kinetics of batch adsorption in a perfect mixing reservoir. Systems with a linear adsorption equilibrium, spherical adsorbent pellets and mass transfer resistance in both phases are considered. An approximate kinetic model, based on approximation with the use of continued fractions, was used in calculations. It was found that the model gives results consistent with the exact solution

TEMPERATURE PROFILES IN GROUND HEAT EXCHANGERS

A mathematical model of a ground heat exchanger cooperating with a heat pump was presented. The model is based on a one-dimensional heat conduction equation with an internal heat source. On the basis of the solutions to the model equations, both the temperature distribution of different types of ground at different times of year as well as the time courses of temperature at different depths are shown. Calculations based on the presented model can be useful for the simulation and design of this apparatus

Heat conduction in the ground under natural conditions and with heat exchanger installed

The results of calculations of the heat transfer in a horizontal ground heat exchanger are presented. The applied model is based on a one-dimensional equation of the transient heat conduction with an internal heat source. The model was correctly verified by comparison of computational results and experimental measurements presented in literature. Thermal calculations concerning heat transfer in the ground under natural conditions are also presented

On adsorption of water vapor on silica gel

The aim of this work is to present the results of studies on heat and mass transfer in an adsorber, which is the main part of an adsorption chiller. The paper refers to adsorption of water vapor on silica gel grains. Adsorbent grains were coated on the outer surface of a copper pipe. The influence of grains diameter and flow rate of the gas phase on process intensity was considered

Development of comprehensive river typology based on macrophytes in the mountain-lowland gradient of different Central European ecoregions

The aim of the study was to identify the vegetation pattern in the different types of watercourses basing on survey in reference conditions in a wide geographical gradient, including mountain, upland and lowland rivers. We tested relationship between composition of macrophytes to environmental variables including: altitude, slope, catchment area, geology of valley, land use, hydromorphological sfeatures, water physical and chemical measurements. Analysis based on 109 pristine river sites located throughout major types of rivers in Central Europe. Qualitative and quantitative plant surveys were carried out between 2005 and 2013. Based on TWINSPAN classification and DCA analysis, six macrophyte types were distinguished. The lowland sites were divided into the following three types: humic rivers and two types of siliceous rivers depending on the catchment area, including medium-large and small rivers. The mountain and upland rivers were divided into three geological types: siliceous, calcareous and gravel. We found that the variation of macrophyte communities was determined by several habitat factors (mainly altitude, flow type, riverbed granulometry, conductivity and alkalinity), whereas the spatial factor was rather limited; further, the plant diversity was not reflected accurately by the European ecoregion approach

Macrophyte and macroinvertebrate patterns in unimpacted mountain rivers of two European ecoregions

The aim of the study was to compare the patterns of development of macrophytes and macroinvertebrates in different types of reference mountain rivers. The study is based on reference river sites surveyed throughout the mountains in Poland and Slovakia in two European ecoregions (9—Central Highlands, 10—The Carpathians). A wide range of environmental variables were estimated, including water chemistry, hydromorphology, geology, and the spatial factor. Based on the Jaccard index, macrophyte and macroinvertebrate variation was confirmed between four mountain and upland river types. It was found that the biological diversification is mainly influenced by geological and associated chemical factors. In the case of macroinvertebrates, additionally, the importance of the spatial factor was revealed (difference between ecoregions). Finally, the habitat preferences of various taxa were identified. It was found that extreme mountain conditions can sometimes distort bioindicative response, as was detected in the case of macroinvertebrates in the highest mountain sites. We concluded that consideration of two groups of organisms enables more comprehensive and reliable monitoring than assessment based on a single group, especially when standard bioindicative methods can be distorted by extreme local conditions

Modelling of Heat Transfer in Ground Heat Exchangers

The results of the numerical simulation of heat conduction in ground with a horizontal, tubular (parallel pipes) heat exchanger installed are presented in this paper. On the basis of analysis of courses of temperature isolines in the ground, a simplified mathematical heat transfer model in a horizontal ground exchanger was developed. The ground thermal diffusivity was assumed to be a variable of location. On the basis of the model, the temperature profiles in the ground with a heat exchanger installed were determined