Microstructure and Optical Properties of Tantalum Modified TiO2 Thin Films Prepared by the Sol-Gel Process

Tantalum doped TiO2 thin films ((TiO2)(1-x) (Ta2O5)(x), x = 0, 0.1%, 0.3%, 0.5%, 0.8%) were prepared on ITO-coated substrates by means of the sol gel method and spin coating technology followed by rapid thermal annealing treatment (RTA). The effects of various processing parameters, including Ta content (x = 0-0.8%) and annealing temperature, on the growth and properties of thin films were investigated. Structural characteristics by X-ray diffraction analysis indicated that the doping of Ta2O5 in the TiO2 without change the anatase structure of TiO2 thin films. The optical transmittance of (TiO2)(1-x) (Ta2O5) thin films decrease from 50% down to 20% with increasing the Ta2O5 concentrations from x = 0.00 to x = 0.8%. The absorption coefficient shows energy gap were decreased with increasing Ta2O5 content from 2.932 eV for x = 0.00 to 2.717 eV for x = 0.8%. Doping TiO2 with Ta2O5 can lower its band gap and shift its optical response to the visible region

Photoluminescence Properties of the Zn1-x Y (x) O Tubes Prepared by Polycarbonate Templates

We have prepared Zn1-x Y (x) O (x=0 and 0.01) tubes to study its structural and photoluminescent properties. A pore wetting process of porous polycarbonate templates with the liquid precursor and following thermal treatment were utilized for preparing the Zn1-x Y (x) O tube structure. Using the polycarbonate template with pore size of about 2 mu m diameter, the Zn1-x Y (x) O tubes were obtained. Photoluminescence (PL) spectroscopy was used to measure optical emissions from 350 to 650 nm with a He-Cd laser. The results of the PL spectra show that the Zn1-x Y (x) O tubes have evident emission peaks at the UV (about 380 nm) and visible (around 500 to 650 nm) region. The emission peak at the UV region was slightly shifted to higher wavelengths with increasing Y content. Meanwhile, the green and yellow emission peaks intensity increases as Y content increases. These results are explained by the structure tuning and oxygen deficiency with the introduction of Y

On the complexity of strongly connected components in directed hypergraphs

We study the complexity of some algorithmic problems on directed hypergraphs and their strongly connected components (SCCs). The main contribution is an almost linear time algorithm computing the terminal strongly connected components (i.e. SCCs which do not reach any components but themselves). "Almost linear" here means that the complexity of the algorithm is linear in the size of the hypergraph up to a factor alpha(n), where alpha is the inverse of Ackermann function, and n is the number of vertices. Our motivation to study this problem arises from a recent application of directed hypergraphs to computational tropical geometry. We also discuss the problem of computing all SCCs. We establish a superlinear lower bound on the size of the transitive reduction of the reachability relation in directed hypergraphs, showing that it is combinatorially more complex than in directed graphs. Besides, we prove a linear time reduction from the well-studied problem of finding all minimal sets among a given family to the problem of computing the SCCs. Only subquadratic time algorithms are known for the former problem. These results strongly suggest that the problem of computing the SCCs is harder in directed hypergraphs than in directed graphs.Comment: v1: 32 pages, 7 figures; v2: revised version, 34 pages, 7 figure

Structure–activity Relationships of Amyloid Beta-aggregation Inhibitors Based on Curcumin: Influence of Linker Length and Flexibility

Peer Reviewedhttp://deepblue.lib.umich.edu/bitstream/2027.42/66293/1/j.1747-0285.2007.00557.x.pd