Formation of rectifier with gold nanoclusters

Gold nanoclusters encapsulated with organic molecules are of great interest for its possible applications in the fields of molecular electronics, catalysis and medical science. Here we demonstrate that monolayer and bilayer films of thiol-capped gold nanoclusters can exhibit diode-like properties provided controlled spatial asymmetry exist between two tunnel junctions used to connect a thiol capped gold nanoclusters. Current-voltage characteristics of this rectifier were obtained from conducting probe atomic force microscopy measurements and also from conventional two probe resistance measurements. Systematic x-ray reflectivity and atomic force microscopy measurements were carried out to characterize the spatial asymmetry introduced by a monolayer of fatty acid salt gadolinium stearate used to deposit thiol-capped gold nanocluster molecules on hydrophilic SiO2-Si(001) substrate by Langmuir Blodgett technique. This information was used to explain prominent rectification observed in these nano-structured films.Comment: 13 pages, 3 figure

Formation rates of Dark Matter Haloes

We derive an estimate of the rate of formation of dark matter halos per unit volume as a function of the halo mass and redshift of formation. Analytical estimates of the number density of dark matter halos are useful in modeling several cosmological phenomena. We use the excursion set formalism for computing the formation rate of dark matter halos. We use an approach that allows us to differentiate between major and minor mergers, as this is a pertinent issue for semi-analytic models of galaxy formation. We compute the formation rate for the Press-Schechter and the Sheth-Tormen mass function. We show that the formation rate computed in this manner is positive at all scales. We comment on the Sasaki formalism where negative halo formation rates are obtained. Our estimates compare very well with N-Body simulations for a variety of models. We also discuss the halo survival probability and the formation redshift distributions using our method.Comment: 30 pages, 9 figure