5,870 research outputs found
Single-crystal growth and dependences on the hole concentration and magnetic field of the magnetic ground state in the edge-sharing CuO chain system CaYCuO
We have succeeded in growing large-size single-crystals of
CaYCuO with and measured the
magnetic susceptibility, specific heat and magnetization curve, in order to
study the magnetic ground state in the edge-sharing CuO chain as a function
of hole concentration and magnetic field. In , it has been
found that an antiferromagnetically ordered phase with the magnetic easy axis
along the b-axis is stabilized and that a spin-flop transition occurs by the
application of magnetic fields parallel to the b-axis. The antiferromagnetic
transition temperature decreases with increasing and disappears around 1.4. Alternatively, a spin-glass phase appears around . At where the hole concentration is 1/3 per Cu, it appears that a
spin-gap state is formed owing to the formation of spin-singlet pairs. No sign
of the coexistence of an antiferromagnetically ordered state and a spin-gap one
suggested in CaCuO has been found in
CaYCuO.Comment: 13 pages, 12 figures, 1 tabl
Multi-Triplet Magnons in SrCu(BO) Studied by Thermal Conductivity Measurements in Magnetic Fields
We have measured the thermal conductivity parallel to the a-axis of the
Zn-free and 1% Zn-substituted SrCuZn(BO) in magnetic fields
up to 14 T, in order to examine the thermal conductivity due to the
multi-triplet magnons. It has been found that the thermal conductivity peak
observed in the spin gap state is suppressed by the substitution of Zn for Cu
in high magnetic fields above 6 T, while it is not changed in low magnetic
fields below 6 T. The results suggest that the thermal conductivity peak in the
spin-gap state of SrCu(BO) is composed of not only thermal
conductivity due to phonons but also that due to the multi-triplet magnons in
high fields above 6 T.Comment: 7 pages, 2 figure
Diffusive transport in spin-1 chains at high temperatures
We present a numerical study on the spin and thermal conductivities of the
spin-1 Heisenberg chain in the high temperature limit, in particular of the
Drude weight contribution and frequency dependence. We use the Exact
Diagonalization and the recently developed microcanonical Lanczos method; it
allows us a finite size scaling analysis by the study of significantly larger
lattices. This work, pointing to a diffusive rather than ballistic behavior is
discussed with respect to other recent theoretical and experimental studies
High temperature thermal conductivity of 2-leg spin-1/2 ladders
Based on numerical simulations, a study of the high temperature, finite
frequency, thermal conductivity of spin-1/2 ladders is
presented. The exact diagonalization and a novel Lanczos technique are
employed.The conductivity spectra, analyzed as a function of rung coupling,
point to a non-diverging limit but to an unconventional low frequency
behavior. The results are discussed with perspective recent experiments
indicating a significant magnetic contribution to the energy transport in
quasi-one dimensional compounds.Comment: 4 pages, 4 figure
Synthesis and Characterization of Homoleptic and Heteroleptic Ruthenium Polypyridine Complexes
The homoleptic ruthenium(II) complex Ru(C13H10N2)3(PF6)2, and heteroleptic ruthenium(II) complexes Ru(C13H10N2)2(C10H8N2)(PF6)2, and Ru(C13H10N2)(C10H8N2)2(PF6)2 have been prepared by following the standard synthetic procedure. These complexes were then purified by repeated column chromatography. The identity and the integrity of the complexes were confirmed by elemental analysis and mass spectroscopy. The calculated and the experimental values for the elemental analysis were in good agreement. The calculated and the experimental molar masses obtained were also identical. Ultravioletvisible absorption and emission spectroscopic methods were used to investigate the properties of these complexes. The absorption spectra of all complexes consist of a series of absorption bands in the ultraviolet and visible region. All three complexes show a strong emission band in the visible region. The emission maxima for the heteroleptic complexes are slightly redshifted
Level statistics of XXZ spin chains with a random magnetic field
The level-spacing distribution of a spin 1/2 XXZ chain is numerically studied
under random magnetic field. We show explicitly how the level statistics
depends on the lattice size L, the anisotropy parameter , and the mean
amplitude of the random magnetic field h. In the energy spectrum, quantum
integrability competes with nonintegrability derived from the randomness, where
the XXZ interaction is modified by the parameter . When ,
the level-spacing distribution mostly shows Wigner-like behavior, while when
=0, Poisson-like behavior appears although the system is nonintegrable
due to randomness. Poisson-like behavior also appears for in the
large h limit. Furthermore, the level-spacing distribution depends on the
lattice size L, particularly when the random field is weak.Comment: 4 pages, 3 figures, to be published in Phys. Rev.
Evidence for Ballistic Thermal Conduction in the One-Dimensional S=1/2 Heisenberg Antiferromagnetic Spin System Sr2CuO3
We have measured the thermal conductivity of the one-dimensional (1D) S=1/2
Heisenberg antiferromagnetic spin system of Sr2Cu1-xPdxO3 single crystals
including nonmagnetic impurities of Pd2+. It has been found that the mean free
path of spinons along the 1D spin chain at low temperatures is very close to
the average length of finite spin chains between spin defects estimated from
the magnetic susceptibility measurements. This proves that the thermal
conduction due to spinons at low temperatures in Sr2CuO3 is ballistic as
theoretically expected [Zotos et al.: Phys. Rev. Lett. 55 (1997) 11029]
Slow, Steady-State Transport with "Loading" and Bulk Reactions: the Mixed Ionic Conductor LaCuO
We consider slow, steady transport for the normal state of the superconductor
LaCuO in a one-dimensional geometry, with surface fluxes
sufficiently general to permit oxygen to be driven into the sample (``loaded'')
either by electrochemical means or by high oxygen partial pressure. We include
the bulk reaction OO, where neutral atoms () go into ions
() and holes (). For slow, steady transport, the transport equations
simplify because the bulk reaction rate density and the bulk loading rates
then are uniform in space and time. All three fluxes must be
specified at each surface, which for a uniform current density corresponds
to five independent fluxes. These fluxes generate two types of static modes at
each surface and a bulk response with a voltage profile that varies
quadratically in space, characterized by and the total oxygen flux
(neutral plus ion) at each surface. One type of surface mode is associated with
electrical screening; the other type is associated both with diffusion and
drift, and with chemical reaction (the {\it diffusion-reaction mode}). The
diffusion-reaction mode is accompanied by changes in the chemical potentials
, and by reactions and fluxes, but it neither carries current (J=0) nor
loads the system chemically (). Generation of the diffusion-reaction
mode may explain the phenomenon of ``turbulence in the voltage'' often observed
near the electrodes of other mixed ionic electronic conductors (MIECs).Comment: 11 pages, 1 figur
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