Recyclable Organic Bilayer Piezoresistive Cantilever for Torque Magnetometry at Cryogenic Temperatures

Flexible sensors made from organic bilayer films of molecular conductor on polymeric matrix have attracted many interest due to their simple fabrication with high potential for being scaled up, and for their high-performing multi-functionality at room temperatures. In particular, the piezoresistive property of the organic bilayer film is among one of the highest ever reported, allowing its utilization in various sensing applications. In this work, we present the study of the flexural piezoresistivity of an organic bilayer film based on $\beta-\rm (BEDT-TTF)_2I_3$ on polycarbonate matrix from room temperatures down to cryogenics temperatures. Non-trivial temperature dependent profile of the gauge factor is revealed, including enhancement of the gauge factor from $\sim 18$ at room temperatures to $\sim 48$ at 4.3 K. An organic bilayer cantilever magnetometer is developed and demonstrated to measure magnetic properties of a single crystalline organic superconductor $\kappa-\rm (BEDT-TTF)_2Cu(N(CN)_2)Br$ at temperatures down to $\sim 2.75$ K and magnetic fields up to 5 T. The high-performing bilayer devices can be fabricated in a very simple manner, and they are robust and recyclable

Second harmonic wave generation from Joule heating in layered organic conductors

The amplitude of a second harmonic wave (SHW) generated from Joule heating as a heat source in organic conductor β-(BEDT-TTF)2IBr2 is analyzed as a function of the magnetic field strength and its orientation with respect to the plane of the layers. Angular oscillations of the SHW amplitude are correlated with the angular changes of in-plane conductivity that arise from the periodic dependence of charge carriers velocity on the field orientation. It was found that the nonlinear effect of wave generation leads to a shift between the position of the peaks of the wave amplitude and in-plane conductivity. This allows an important information on the parameter values of organic conductors as well as wave velocity to be obtained. Magnetic field dependence shows that the wave is not strongly attenuated with increasing field and might give insights on the interactions between the electromagnetic, temperature and acoustic oscillations. We found that these observations are completely different compared to those of linear acoustic wave generation. It has been shown that the necessary conditions for observing the nonlinear acoustic wave generation are fulfilled in a wide range of fields and angles that allow the acoustic properties of organic conductors to be studied in detail

Giant Angular Nernst Effect in the Organic Metal <i>α</i>-(BEDT-TTF)₂KHg(SCN)₄

We have detected a large Nernst effect in the charge density wave state of the multiband organic metal α-(BEDT-TTF)2KHg(SCN)4. We find that apart from the phonon drag effect, the energy relaxation processes that govern the electron–phonon interactions and the momentum relaxation processes that determine the mobility of the q1D charge carriers have a significant role in observing the large Nernst signal in the CDW state in this organic metal. The emphasised momentum relaxation dynamics in the low field CDW state (CDW0) is a clear indicator of the presence of a significant carrier mobility that might be the main source for observation of the largest Nernst signal. The momentum relaxation is absent with increasing angle and magnetic field, i.e., in the high-field CDW state (CDWx) as evident from the much smaller Nernst effect amplitude in this state. In this case, only the phonon drag effect and electron–phonon interactions are contributing to the transverse thermoelectric signal. Our findings advance and change previous observations on the complex properties of this organic metal