Formation of bi-aryls via a domino palladium catalysis

Synthesis of bi-aryls via a domino Pd-catalyzed reaction of 1-(2-bromophenyl)-2-methylpropan-1-ones/(2-bromophenyl)(cyclohexyl)methanones is presented. The mechanism of the reaction is believed to proceed through a five membered palladacycle that combines with a second molecule of halo-arene to yield the bi-aryls. This method is quite successful to deliver highly sterically crowded bi-aryls with dense functionalities on the aromatic rings

A domino palladium catalysis: Synthesis of 7-methyl-5 H -dibenzo[ a, c ][7] annulen-5-ones

A domino Pd-catalyzed reaction of 1-(2-bromophenyl)ethanones for the synthesis of novel 7-methyl-5H-dibenzo[a,c][7]annulen-5-ones, a carbon core structure present in colchicinoid natural products, is presented. The reaction is proposed to proceed via intermolecular homobiaryl coupling and intramolecular aldol condensatio

Palladium-catalyzed selective α-arylation of ortho -bromoacetophenones

Synthesis of 1-(2-bromophenyl)-2-phenylethanones via an intermolecular Pd-catalyzed α-arylation of 1-(2-bromophenyl)ethanones is presented. The method relies on selective C-H activation (α-arylation) of relatively more reactive external iodo-arenes as coupling partners without affecting the bromo-substituent. Moreover, the scope and generality of the method has been well studied by employing the reaction with iodo-arenes as coupling partners bearing electron-withdrawing, simple, and electron-donating groups on the aromatic ring

Jet stability, dynamics and energy transport

Relativistic jets carry energy and particles from compact to very large scales compared with their initial radius. This is possible due to their remarkable collimation despite their intrinsic unstable nature. In this contribution, I review the state-of-the-art of our knowledge on instabilities growing in those jets and several stabilising mechanisms that may give an answer to the question of the stability of jets. In particular, during the last years we have learned that the limit imposed by the speed of light sets a maximum amplitude to the instabilities, contrary to the case of classical jets. On top of this stabilising mechanism, the fast growth of unstable modes with small wavelengths prevents the total disruption and entrainment of jets. I also review several non-linear processes that can have an effect on the collimation of extragalactic and microquasar jets. Within those, I remark possible causes for the decollimation and decelleration of FRI jets, as opposed to the collimated FRII's. Finally, I give a summary of the main reasons why jets can propagate through such long distances.Comment: For the proceedings of High Energy Phenomena in Relativistic Outflows III (HEPRO III, IJMPD, accepted). 12 page

Further evidence for intra-night optical variability of radio-quiet quasars

Although well established for BL Lac objects and radio-loud quasars, the occurrence of intra-night optical variability (INOV) in radio-quiet quasars is still debated, primarily since only a handful of INOV events with good statistical significance, albeit small amplitude, have been reported so far. This has motivated us to continue intra-night optical monitoring of bona-fide radio-quiet quasars (RQQs). Here we present the results for a sample of 11 RQQs monitored by us on 19 nights. On 5 of these nights a given RQQ was monitored simultaneously from two well separated observatories. In all, two clear cases and two probable case of INOV were detected. From these data, we estimate an INOV duty cycle of $\sim$8% for RQQs which would increase to 19% if the `probable variable' cases are also included. Such comparatively small INOV duty cycles for RQQs, together with the small INOV amplitudes ($\sim$1%), are in accord with the previously deduced characteristics of this phenomenon.Comment: 15 Pages, 4 Tables, 24 Figures; Accepted in BAS

Karyotypic studies of freshwater prawn Machrobrachium rosenbergii

Chromosomal studies were conducted on Macrobrachium rosenbergii. On the basis of 50 metaphase plate counts, 38 metacentric, 14 sub metacentric and 66 telocentric chromosomes (2n = 118) were observed. The total length of the granomme was recorded to be 34.2 micron