Specific Heat of the Ca-Intercalated Graphite Superconductor CaC6_6

The superconducting state of Ca-intercalated graphite CaC6 has been investigated by specific heat measurements. The characteristic anomaly at the superconducting transition (Tc = 11.4 K) indicates clearly the bulk nature of the superconductivity. The temperature and magnetic field dependence of the electronic specific heat are consistent with a fully-gapped superconducting order parameter. The estimated electron-phonon coupling constant is lambda = 0.60 - 0.74 suggesting that the relatively high Tc of CaC6 can be explained within the weak-coupling BCS approach.Comment: 4 pages, 4 figs, submitted to Phys. Rev. Let

Inflationary and dark energy regimes in 2+1 dimensions

In this work we investigate the behavior of three-dimensional (3D) cosmological models. The simulation of inflationary and dark-energy-dominated eras are among the possible results in these 3D formulations; taking as starting point the results obtained by Cornish and Frankel. Motivated by those results, we investigate, first, the inflationary case where we consider a two-constituent cosmological fluid: the scalar field represents the hypothetical inflaton which is in gravitational interaction with a matter/radiation contribution. For the description of an old universe, it is possible to simulate its evolution starting with a matter dominated universe that faces a decelerated/accelerated transition due to the presence of the additional constituent (simulated by the scalar field or ruled by an exotic equation of state) that plays the role of dark energy. We obtain, through numerical analysis, the evolution in time of the scale factor, the acceleration, the energy densities, and the hydrostatic pressure of the constituents. The alternative scalar cosmology proposed by Cornish and Frankel is also under investigation in this work. In this case an inflationary model can be constructed when another non-polytropic equation of state (the van der Waals equation) is used to simulate the behavior of an early 3D universe.Comment: Latex file, plus 9 figures. To appear in General Relativity and Gravitatio

Effect of Pressure on Superconducting Ca-intercalated Graphite CaC6_6

The pressure effect on the superconducting transition temperature ($T_c$) of the newly-discovered Ca-intercalated graphite compound CaC$_6$ has been investigated up to $\sim$ 16 kbar. $T_c$ is found to increase under pressure with a large relative ratio $\Delta$$T_c$/$T_c$ of $\approx$ +0.4 %/kbar. Using first-principles calculations, we show that the large and positive effect of pressure on $T_c$ can be explained in the scope of electron-phonon theory due to the presence of a soft phonon branch associated to in-plane vibrations of Ca atoms. Implications of the present findings on the current debate about the superconducting mechanism in graphite intercalation compounds are discussed.Comment: 6 pages, 5 figs, final PRB versio

3D gravity and non-linear cosmology

By the inclusion of an additional term, non-linear in the scalar curvature $R$, it is tested if dark energy could rise as a geometrical effect in 3D gravitational formulations. We investigate a cosmological fluid obeying a non-polytropic equation of state (the van der Waals equation) that is used to construct the energy-momentum tensor of the sources, representing the hypothetical inflaton in gravitational interaction with a matter contribution. Following the evolution in time of the scale factor, its acceleration, and the energy densities of constituents it is possible to construct the description of an inflationary 3D universe, followed by a matter dominated era. For later times it is verified that, under certain conditions, the non-linear term in $R$ can generate the old 3D universe in accelerated expansion, where the ordinary matter is represented by the barotropic limit of the van der Waals constituent.Comment: 7 pages, to appear in Mod. Phys. Let

Cosmological model with non-minimally coupled fermionic field

A model for the Universe is proposed whose constituents are: (a) a dark energy field modeled by a fermionic field non-minimally coupled with the gravitational field, (b) a matter field which consists of pressureless baryonic and dark matter fields and (c) a field which represents the radiation and the neutrinos. The coupled system of Dirac's equations and Einstein field equations is solved numerically by considering a spatially flat homogeneous and isotropic Universe. It is shown that the proposed model can reproduce the expected red-shift behaviors of the deceleration parameter, of the density parameters of each constituent and of the luminosity distance. Furthermore, for small values of the red-shift the constant which couples the fermionic and gravitational fields has a remarkable influence on the density and deceleration parameters.Comment: Accepted for publication in Europhysics Letter

Direct observation of substitutional Ga after ion implantation in Ge by means of extended x-ray absorption fine structure

We present an experimental lattice location study of Ga atoms in Ge after ion implantation at elevated temperature (250°C). Using extended x-rayabsorption fine structure (EXAFS) experiments and a dedicated sample preparation method, we have studied the lattice location of Ga atoms in Ge with a concentration ranging from 0.5 at. % down to 0.005 at. %. At Ga concentrations ≤0.05 at.%, all Ga dopants are substitutional directly after ion implantation, without the need for post-implantation thermal annealing. At higher Ga concentrations, a reduction in the EXAFS amplitude is observed, indicating that a fraction of the Ga atoms is located in a defective environment. The local strain induced by the Ga atoms in the Ge matrix is independent of the Ga concentration and extends only to the first nearest neighbor Ge shell, where a 1% contraction in bond length has been measured, in agreement with density functional theory calculations.We acknowledge the support from the Research Foundation Flanders, the epi-team from imec, the KU Leuven GOA 09/06 project, the IUAP program P6/42 and the Australian Research Council. S.C. acknowledges support from OCAS NV by an OCAS-endowed chair at Ghent University

Non-linear terms in 2D cosmology

In this work we investigate the behavior of two-dimensional (2D) cosmological models, starting with the Jackiw-Teitelboim (JT) theory of gravitation. A geometrical term, non-linear in the scalar curvature $R$, is added to the JT dynamics to test if it could play the role of dark energy in a 2D expanding universe. This formulation makes possible, first, the description of an early (inflationary) 2D universe, when the van der Waals (vdW) equation of state is used to construct the energy-momentum tensor of the gravitational sources. Second, it is found that for later times the non-linear term in $R$ can generate an old 2D universe in accelerated expansion, where an ordinary matter dominated era evolves into a decelerated/accelerated transition, giving to the dark energy effects a geometrical origin. The results emerge through numerical analysis, following the evolution in time of the scale factor, its acceleration, and the energy densities of constituents.Comment: tex file plus figures in two zipped files. To appear in Europhys. Let

Self-similar chain conformations in polymer gels

We use molecular dynamics simulations to study the swelling of randomly end-cross-linked polymer networks in good solvent conditions. We find that the equilibrium degree of swelling saturates at Q_eq = N_e**(3/5) for mean strand lengths N_s exceeding the melt entanglement length N_e. The internal structure of the network strands in the swollen state is characterized by a new exponent nu=0.72. Our findings are in contradiction to de Gennes' c*-theorem, which predicts Q_eq proportional N_s**(4/5) and nu=0.588. We present a simple Flory argument for a self-similar structure of mutually interpenetrating network strands, which yields nu=7/10 and otherwise recovers the classical Flory-Rehner theory. In particular, Q_eq = N_e**(3/5), if N_e is used as effective strand length.Comment: 4 pages, RevTex, 3 Figure

Confinement effects on glass forming liquids probed by DMA

Many molecular glass forming liquids show a shift of the glass transition T-g to lower temperatures when the liquid is confined into mesoporous host matrices. Two contrary explanations for this effect are given in literature: First, confinement induced acceleration of the dynamics of the molecules leads to an effective downshift of T-g increasing with decreasing pore size. Second, due to thermal mismatch between the liquid and the surrounding host matrix, negative pressure develops inside the pores with decreasing temperature, which also shifts T-g to lower temperatures. Here we present dynamic mechanical analysis measurements of the glass forming liquid salol in Vycor and Gelsil with pore sizes of d=2.6, 5.0 and 7.5 nm. The dynamic complex elastic susceptibility data can be consistently described with the assumption of two relaxation processes inside the pores: A surface induced slowed down relaxation due to interaction with rough pore interfaces and a second relaxation within the core of the pores. This core relaxation time is reduced with decreasing pore size d, leading to a downshift of T-g proportional to 1/d in perfect agreement with recent differential scanning calorimetry (DSC) measurements. Thermal expansion measurements of empty and salol filled mesoporous samples revealed that the contribution of negative pressure to the downshift of T-g is small (<30%) and the main effect is due to the suppression of dynamically correlated regions of size xi when the pore size xi approaches