Listening with Curiosity – Tracking the Acoustic Response of Portable Laser Ablation

Nowadays, one of the methods of choice for minimal invasive sampling of solid matter is laser ablation (LA). Routine LA sampling is performed commonly in the laboratory and the amount of ablated mass can directly be monitored and analysed. By contrast laser-based sampling in the field, using a portable laser ablation system (pLA), still remains challenging concerning low-absorbing or NIR-transparent samples. The current hardware is limited in regards to photon energy and density resulting in unsteady ablation. But as the actual amount of collected mass is the major crux of on-site sampling, with this performance it is often unknown and estimates can only be made based on the experience from prior method development and the experience of the user. In the following work an easy-to-use method to monitor the amount of ablated material collected during laser-based sampling by measuring the acoustic response is presented. The pLA-system was coupled to inductively coupled plasma mass spectrometry (ICPMS) via a diffusion driven gas exchange device (GED) which allowed to monitor mass removal and acoustic response quasi-simultaneously. For the current instrumentation only actual mass removal leads to the formation of shockwaves (SW) and, thus, acoustic signals. These events can be used as indicator for executed LA events and counted on an individual basis. The intensity of acoustic signals has been shown to correlate with the LA mass, i.e., the amount of ablated material. This allows to perform re-adjustment of the laser focus during sampling for optimal ablation based on the intensity of the acoustic signal. Likewise, acoustic intensity together with counting allows the operator to make estimates about total mass sampled. Therefore, unsuccessful laser aerosol collection in the field shall become a thing of the past

Earthquakes in Switzerland and surrounding regions during 2010

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2010. During this period, 407 earthquakes and 85 quarry blasts were detected and located in the region under consideration. With a total of only 19 events with ML≥2.5, the seismic activity in the year 2010 was below the average over the previous 35years. The two most noteworthy earthquakes were the ML3.4 Barrhorn event near Sankt Niklaus (VS) and the ML 3.0 event of Feldkirch, both of which produced shaking of intensity I

Earthquakes in Switzerland and surrounding regions during 2011

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2011. During this period, 522 earthquakes and 92 quarry blasts were detected and located in the region under consideration. With a total of only 10 events with M L≥2.5, the seismic activity in the year 2011 was far below the average over the previous 36years. Most noteworthy were the earthquake sequence of Sierre (VS) in January, with two events of M L 3.3 and 3.2, the M L 3.3 earthquake at a depth of 31km below Bregenz, and the M L 3.1 event near Delémont. The two strongest events near Sierre produced shaking of intensity I

Earthquakes in Switzerland and surrounding regions during 2011

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2011. During this period, 522 earthquakes and 92 quarry blasts were detected and located in the region under consideration. With a total of only 10 events with M L≥2.5, the seismic activity in the year 2011 was far below the average over the previous 36years. Most noteworthy were the earthquake sequence of Sierre (VS) in January, with two events of M L 3.3 and 3.2, the M L 3.3 earthquake at a depth of 31km below Bregenz, and the M L 3.1 event near Delémont. The two strongest events near Sierre produced shaking of intensity I

Earthquakes in Switzerland and surrounding regions during 2005

Abstract.: This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2005. During this period, 611 earthquakes, 96 quarry blasts and two landslides were detected and located in the region under consideration. With 19 events with ML ≥ 2.5, the seismic activity in the year 2005 was below the average over the last 30 years. However, with the earthquake of Vallorcine (ML 4.9) located just across the border to France, between Martigny and Chamonix, and the two earthquakes of Rumisberg and Brugg (ML 4.1), located in the lower crust beneath the Jura Mountains of northern Switzerland, the year 2005 saw three events that produced shaking of intensity IV and V (EMS98). Of the 611 recorded earthquakes more than 110 events are aftershocks of the Vallorcine quake. Moreover, 51 events occurred within two days at the end of August during a period of very intense rainfalls. The epicenters of these events were concentrated in several clusters distributed over a wide area of central Switzerland, and their focal depths were shallow, so that they most likely constitute a case of precipitationinduced seismicit

Earthquakes in Switzerland and surrounding regions during 2012

This report of the Swiss Seismological Service summarizes the seismic activity in Switzerland and surrounding regions during 2012. During this period, 497 earthquakes and 88 quarry blasts were detected and located in the region under consideration. With a total of only 13 events with ML≥2.5, the seismic activity in the year 2012 was far below the average over the previous 37years. Most noteworthy were the earthquake sequence of Filisur (GR) in January with two events of ML 3.3 and 3.5, the ML 4.2 and ML 3.5 earthquakes at a depth of 32km below Zug in February and the ML 3.6 event near Vallorcine in October. The epicentral intensity of the ML 4.2 event close to Zug was IV, with a maximum intensity of V reached in a few areas, probably due to site amplification effect

Listening with Curiosity – Tracking the Acoustic Response of Portable Laser Ablation

Nowadays, one of the methods of choice for minimal invasive sampling of solid matter is laser ablation (LA). Routine LA sampling is performed commonly in the laboratory and the amount of ablated mass can directly be monitored and analysed. By contrast laser-based sampling in the field, using a portable laser ablation system (pLA), still remains challenging concerning low-absorbing or NIR-transparent samples. The current hardware is limited in regards to photon energy and density resulting in unsteady ablation. But as the actual amount of collected mass is the major crux of on-site sampling, with this performance it is often unknown and estimates can only be made based on the experience from prior method development and the experience of the user. In the following work an easy-to-use method to monitor the amount of ablated material collected during laser-based sampling by measuring the acoustic response is presented. The pLA-system was coupled to inductively coupled plasma mass spectrometry (ICPMS) via a diffusion driven gas exchange device (GED) which allowed to monitor mass removal and acoustic response quasi-simultaneously. For the current instrumentation only actual mass removal leads to the formation of shockwaves (SW) and, thus, acoustic signals. These events can be used as indicator for executed LA events and counted on an individual basis. The intensity of acoustic signals has been shown to correlate with the LA mass, i.e., the amount of ablated material. This allows to perform re-adjustment of the laser focus during sampling for optimal ablation based on the intensity of the acoustic signal. Likewise, acoustic intensity together with counting allows the operator to make estimates about total mass sampled. Therefore, unsuccessful laser aerosol collection in the field shall become a thing of the past.ISSN:0009-429

Tracking mass removal of portable laser ablation sampling by its acoustic response

If the sample cannot be brought to the lab for sampling, then the sampling needs to be done at the sample location. The portable laser ablation (pLA) system is one of the candidates to address this challenge, as it is a powerful tool for field deployable sampling of solids with the benefits of laser based analysis methods. However, sampling in the field is not always as convenient as in a defined laboratory setting and requires a neat prior method development. In the field, the evaluation of the sampling performance is not straightforward with current hardware. During mass removal by (p)LA, an acoustic pressure wave is formed for every individual LA event. In order to track these signals, a directional microphone was integrated into the handheld pLA-module. This allowed the monitoring of the acoustic signal close to the ablation site to count and quantify LA events from each individual pulse. In order to monitor mass removal and acoustic response quasi-simultaneously, the pLA sampling device was coupled to an ICPMS via a gas-exchange device (GED). Performance was investigated using various samples. Discrepancies were observed between samples with low and high ablation thresholds. For samples with low ablation thresholds, e.g. metals, the acoustic signal was mainly influenced by the laser fluence at the ablation site and not by the amount of mass removal. Comparatively, when ablating samples with high ablation thresholds, such as glasses and minerals, these variations were less pronounced, resulting in the observation of a linear relationship. Consequently, this allows the use of the acoustic energy as a measure of the amount of mass removal. In summary, results show that this approach enables a straightforward way to track all actual ablation events during on-site sampling and allows an instant evaluation of the ablation performance, thereby reducing unsuccessful sampling sessions.ISSN:0584-854

Synthesis and Characterization of Ion Pairs between Alkaline Metal Ions and Anionic Anti-Aromatic and Aromatic Hydrocarbons with π-Conjugated Central Seven- and Eight-Membered Rings

The synthesis, isolation and full characterization of ion pairs between alkaline metal ions (Li+, Na+, K+) and mono-anions and dianions obtained from 5H-dibenzo[a,d]cycloheptenyl (C15H11 = trop) is reported. According to Nuclear Magnetic Resonance (NMR) spectroscopy, single crystal X-ray analysis and Density Functional Theory (DFT) calculations, the trop‒ and trop2−• anions show anti-aromatic properties which are dependent on the counter cation M+ and solvent molecules serving as co-ligands. For comparison, the disodium and dipotassium salt of the dianion of dibenzo[a,e]cyclooctatetraene (C16H12 = dbcot) were prepared, which show classical aromatic character. A d8-Rh(I) complex of trop− was prepared and the structure shows a distortion of the C15H11 ligand into a conjugated 10π -benzo pentadienide unit—to which the Rh(I) center is coordinated—and an aromatic 6π electron benzo group which is non-coordinated. Electron transfer reactions between neutral and anionic trop and dbcot species show that the anti-aromatic compounds obtained from trop are significantly stronger reductantsISSN:1420-304