Renewable biocatalyst for swine manure treatment and mitigation of odorous VOCs, ammonia and hydrogen sulfide emissions: Review

Comprehensive control of odors, hydrogen sulfide (H2S), ammonia (NH3), and greenhouse gas (GHG) emissions associated with swine production is a critical need. The objective of this paper is to review the use of soybean peroxidase (SBP) and peroxides as a manure additive to mitigate emissions of odorous volatile organic compounds (VOC), NH3, H2S, and GHGs. Soybean peroxidase plus peroxide (SBPP) was tested as a mitigation technology for swine manure emissions on three scales (lab, pilot and farm). Several laboratory scale experiments were completed to assess SBPP dosages and type of oxygen source mixed into swine manure and surface application. A pilot scale experiment was done with surface application of SBPP and multiple dosages to observe scale up effects. Finally, a farm scale trial was completed to assess the SBPP treatment to a swine manure surface under a fully slatted barn floor. The ‘gated‘ approach to testing SBPP from lab- to pilot- and finally the farm-scale was appropriate and allowed for controlled experiments with sufficient replication. This approach resulted in gradual decrease of the dose of SBP, decreasing the cost of treatment, increase of treatment longevity, inclusion of many key gases of concern to the experimental protocol, and finally testing the treatment on farm-scale. To date, the farm-scale results indicate that SBPP can be effective in mitigating many important odorous gas emissions without increasing GHGs. Specifically, a 2.28 kg m-2 SBP dose mixed with 4.2% CaO2 added by weight and added to manure surface resulted in significant reductions in gaseous emissions of NH3(21.7%), H2S (79.7%), n-butyric acid (37.2%), valeric acid (47.7%), isovaleric acid (39.3%), indole (31.2%), and skatole (43.5%). Emissions of DMDS/MT increased by 30.6%. Emissions of p-cresol were reduced by 14.4% but were not statistically significant. There were no significant changes to the GHG emissions of CH4, CO2 and N2O. The treatment cost (SBP+CaO2) was $1.45 per marketed pig of which the cost of SBP was only ~40%. Thus, further research is needed to optimize the dose and the cost of catalysts

Recovery of Agricultural Odors and Odorous Compounds from Polyvinyl Fluoride Film Bags

Accurate sampling methods are necessary when quantifying odor and volatile organic compound emissions at agricultural facilities. The commonly accepted methodology in the U.S. has been to collect odor samples in polyvinyl fluoride bags (PVF, brand name Tedlar®) and, subsequently, analyze with human panelists using dynamic triangular forced-choice olfactometry. The purpose of this research was to simultaneously quantify and compare recoveries of odor and odorous compounds from both commercial and homemade PVF sampling bags. A standard gas mixture consisting of p-cresol (40 μg m−3) and seven volatile fatty acids: acetic (2,311 μg m−3), propionic (15,800 μg m−3), isobutyric (1,686 μg m−3), butyric (1,049 μg m−3), isovaleric (1,236 μg m−3), valeric (643 μg m−3), and hexanoic (2,158 μg m−3) was placed in the PVF bags at times of 1 h, 1 d, 2 d, 3 d, and 7 d prior to compound and odor concentration analyses. Compound concentrations were quantified using sorbent tubes and gas chromatography/mass spectrometry. Odor concentration, intensity, and hedonic tone were measured using a panel of trained human subjects. Compound recoveries ranged from 2 to 40% after 1 h and 0 to 14% after 7 d. Between 1 h and 7 d, odor concentrations increased by 45% in commercial bags, and decreased by 39% in homemade bags. Minimal changes were observed in intensity and hedonic tone over the same time period. These results suggest that PVF bags can bias individual compound concentrations and odor as measured by dynamic triangular forced-choice olfactometry

Signatures of the disk-jet coupling in the Broad-line Radio Quasar 4C+74.26

Here we explore the disk-jet connection in the broad-line radio quasar 4C+74.26, utilizing the results of the multiwavelength monitoring of the source. The target is unique in that its radiative output at radio wavelengths is dominated by a moderately-beamed nuclear jet, at optical frequencies by the accretion disk, and in the hard X-ray range by the disk corona. Our analysis reveals a correlation (local and global significance of 96\% and 98\%, respectively) between the optical and radio bands, with the disk lagging behind the jet by $250 \pm 42$ days. We discuss the possible explanation for this, speculating that the observed disk and the jet flux changes are generated by magnetic fluctuations originating within the innermost parts of a truncated disk, and that the lag is related to a delayed radiative response of the disk when compared with the propagation timescale of magnetic perturbations along relativistic outflow. This scenario is supported by the re-analysis of the NuSTAR data, modelled in terms of a relativistic reflection from the disk illuminated by the coronal emission, which returns the inner disk radius $R_{\rm in}/R_{\rm ISCO} =35^{+40}_{-16}$. We discuss the global energetics in the system, arguing that while the accretion proceeds at the Eddington rate, with the accretion-related bolometric luminosity $L_{\rm bol} \sim 9 \times 10^{46}$ erg s$^{-1}$ $\sim 0.2 L_{\rm Edd}$, the jet total kinetic energy $L_\textrm{j} \sim 4 \times 10^{44}$ erg s$^{-1}$, inferred from the dynamical modelling of the giant radio lobes in the source, constitutes only a small fraction of the available accretion power.Comment: 9 pages and 6 figures, ApJ accepte

GC–MS and GC–NPD Determination of Formaldehyde Dimethylhydrazone in Water Using SPME

Formaldehyde dimethylhydrazone (FADMH) is one of the important transformation products of residual rocket fuel 1,1-dimethylhydrazine (1,1-DMH). Thus, recent studies show that FADMH toxicity is comparable to that of undecomposed 1,1-DMH. In this study, a new method for quantification of FADMH in water based on solid phase microextraction (SPME) in combination with gas chromatography (GC) with mass spectrometric (MS) and nitrogen-phosphorus detection (NPD) is presented. Effects of SPME fiber coating type, extraction and desorption temperatures, extraction time, and pH on analyte recovery were studied. The optimized method used 65 micron polydimethylsiloxane/divinylbenzene fiber coating for 1 min headspace extractions at 30 °C. Preferred pH and desorption temperature from the SPME fiber are >8.5 and 200 °C, respectively. Detection limits were estimated to be 1.5 and 0.5 μg L−1 for MS and NPD, respectively. The method was applied to laboratory-scale experiments to quantify FADMH. Results indicate applicability for in situ sampling and analysis and possible first-time detection of free FADMH in water

Soft Magnetic Properties and Electromagnetic Shielding Performance of Fe40Ni40B20 Microfibers

Fi(40)Ni(40)B(20) metallic glass is a key material among the many amorphous systems investigated thus far, owing to its high strength and appealing soft magnetic properties that make it suitable for use as transformer cores. In this study, Fi(40)Ni(40)B(20) microfibers are fabricated down to 5 mu m diameter. Three different melt-spinning wheel velocities: approximate to 51 m s(-1), approximate to 59 m s(-1), and approximate to 63 m s(-1) (MG1, MG2, MG3) are used. Their fully amorphous structure is confirmed using X-ray diffraction, and differential scanning calorimetry (DSC) traces reveal a larger relaxation profile for the higher-quenched microfiber. Vibrating sample magnetometer measurements showed a higher saturation magnetization of 136 emug(-1) for annealed metallic glass microfibers with a wheel velocity of 59.66 ms(-1). Cylindrical magnetic field shields are obtained by aligning and wrapping the fibers around a cast. The observed anisotropic static field shielding behavior is in accordance with the microfibers' anisotropic nature. Composite samples are also produced by embedding the microfibers in an epoxy matrix to investigate their electromagnetic properties at GHz frequencies. Inclusion of the microfibers increase the composite's attenuation constant by 20 to 25 times, making it an ideal candidate for applications in the communications frequency range

SIKE Round 2 Speed Record on ARM Cortex-M4

We present the first practical software implementation of Supersingular Isogeny Key Encapsulation (SIKE) round 2, targeting NIST’s 1, 2, and 5 security levels on 32-bit ARM Cortex-M4 microcontrollers. The proposed library introduces a new speed record of SIKE protocol on the target platform. We achieved this record by adopting several state-of-the-art engineering techniques as well as highly-optimized hand-crafted assembly implementation of finite field arithmetic. In particular, we carefully redesign the previous optimized implementations of filed arithmetic on 32-bit ARM Cortex-M4 platform and propose a set of novel techniques which are explicitly suitable for SIKE/SIDH primes. Moreover, the proposed arithmetic implementations are fully scalable to larger bit-length integers and can be adopted over different security levels. The benchmark result on STM32F4 Discovery board equipped with 32-bit ARM Cortex-M4 microcontrollers shows that the entire key encapsulation over p434 takes about 326 million clock cycles (i.e. 1.94 seconds @168MHz). In contrast to the previous optimized implementation of the isogeny-based key exchange on low-power 32-bit ARM Cortex-M4, our performance evaluation shows feasibility of using SIKE mechanism on the target platform. In comparison to the most of the post-quantum candidates, SIKE requires an excessive number of arithmetic operations, resulting in significantly slower timings. However, its small key size makes this scheme as a promising candidate on low-end microcontrollers in the quantum era by ensuring the lower energy consumption for key transmission than other schemes