618 research outputs found

    Anomalous oxygen isotope effect on the in-plane FIR conductivity of detwinned YBa2Cu316,18^{16,18}O6.9_{6.9}

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    We observe an anomalous oxygen isotope effect on the a-axis component of the far-infrared electronic response of detwinned YBa2Cu316,18^{16,18}O6.9_{6.9}. For 18^{18}O a pronounced low-energy electronic mode (LEM) appears around 240 cm1^{-1}. This a-axis LEM exhibits a clear aging effect, after one year it is shifted to 190 cm1^{-1}. For 16^{16}O we cannot resolve a corresponding a-axis LEM above 120 cm1^{-1}. We interpret the LEM in terms of a collective electronic mode that is pinned by `isotopic defects', i.e. by the residual 16^{16}O in the matrix of 18^{18}O.Comment: 10 pages, 2 figure

    Signatures of Electronic Correlations in Optical Properties of LaFeAsO1x_{1-x}Fx_x

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    Spectroscopic ellipsometry is used to determine the dielectric function of the superconducting LaFeAsO0.9_{0.9}F0.1_{0.1} (TcT_c = 27 K) and undoped LaFeAsO polycrystalline samples in the wide range 0.01-6.5 eV at temperatures 10 T\leq T \leq 350 K. The free charge carrier response in both samples is heavily damped with the effective carrier density as low as 0.040±\pm0.005 electrons per unit cell. The spectral weight transfer in the undoped LaFeAsO associated with opening of the pseudogap at about 0.65 eV is restricted at energies below 2 eV. The spectra of superconducting LaFeAsO0.9_{0.9}F0.1_{0.1} reveal a significant transfer of the spectral weight to a broad optical band above 4 eV with increasing temperature. Our data may imply that the electronic states near the Fermi surface are strongly renormalized due to electron-phonon and/or electron-electron interactions.Comment: 4 pages, 4 figures, units in Fig.2 adde

    The formation of medical workers subjectity in the patient care institution environment from a position of the eco-psychological approach

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    The process of the medical worker's subjectity development as the realization of the ability to be a subject of the optional activity in the shape of professional performance in the patient care institution environment is analyse

    Infrared studies of a La_(0.67)Ca_(0.33)MnO_3 single crystal: Optical magnetoconductivity in a half-metallic ferromagnet

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    The infrared reflectivity of a La_(0.67)Ca_(0.33)MnO_3 single crystal is studied over a broad range of temperatures (78–340 K), magnetic fields (0–16 T), and wave numbers (20–9000cm^(-1)). The optical conductivity gradually changes from a Drude-like behavior to a broad peak feature near 5000cm-1 in the ferromagnetic state below the Curie temperature T_C=307K. Various features of the optical conductivity bear striking resemblance to recent theoretical predictions based on the interplay between the double exchange interaction and the Jahn-Teller electron-phonon coupling. A large optical magnetoconductivity is observed near T_C

    In Vitro Maturation of a Humanized Shark VNAR Domain to Improve Its Biophysical Properties to Facilitate Clinical Development

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    Acknowledgments: The authors would like to acknowledge the funding support for this work from Scottish Enterprise [VNAR_001(2012)] and the Biotechnology and Biological Sciences Research Council (BB/K010905/1).Peer reviewedPublisher PD

    Infrared Studies of a La_{0.67}Ca_{0.33}MnO_3 Single Crystal: Optical Magnetoconductivity in a Half-Metallic Ferromagnet

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    The infrared reflectivity of a La0.67Ca0.33MnO3\rm La_{0.67}Ca_{0.33}MnO_3 single crystal is studied over a broad range of temperatures (78-340 K), magnetic fields (0-16 T), and wavenumbers (20-9000 cm1^{-1}). The optical conductivity gradually changes from a Drude-like behavior to a broad peak feature near 5000 cm1^{-1} in the ferromagnetic state below the Curie temperature TC=307KT_C=307 K. Various features of the optical conductivity bear striking resemblance to recent theoretical predictions based on the interplay between the double exchange interaction and the Jahn-Teller electron-phonon coupling. A large optical magnetoconductivity is observed near TCT_C.Comment: 4 pages, 4 figures, Latex, PostScript; The 7th Joint MMM-Intermag Conference,San Francisco, January 6-9, 1998; The Int. Conf. on Strongly Correlated Electron Systems, Paris, July 15-18,199

    Spin-controlled Mott-Hubbard bands in LaMnO_3 probed by optical ellipsometry

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    Spectral ellipsometry has been used to determine the dielectric function of an untwinned crystal of LaMnO_3 in the spectral range 0.5-5.6 eV at temperatures 50 K < T < 300 K. A pronounced redistribution of spectral weight is found at the Neel temperature T_N = 140 K. The anisotropy of the spectral weight transfer matches the magnetic ordering pattern. A superexchange model quantitatively describes spectral weight transfer induced by spin correlations. This analysis implies that the lowest-energy transitions around 2 eV are intersite d-d transitions, and that LaMnO_3 is a Mott-Hubbard insulator.Comment: 4 pages, 4 figure

    Low-energy Mott-Hubbard excitations in LaMnO_3 probed by optical ellipsometry

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    We present a comprehensive ellipsometric study of an untwinned, nearly stoichiometric LaMnO_3 crystal in the spectral range 1.2-6.0 eV at temperatures 20 K < T < 300 K. The complex dielectric response along the b and c axes of the Pbnm orthorhombic unit cell, \epsilon^b(\nu) and \epsilon^c(\nu), is highly anisotropic over the spectral range covered in the experiment. The difference between \epsilon^b(\nu) and \epsilon^c(\nu) increases with decreasing temperature, and the gradual evolution observed in the paramagnetic state is strongly enhanced by the onset of A-type antiferromagnetic long-range order at T_N = 139.6 K. In addition to the temperature changes in the lowest-energy gap excitation at 2 eV, there are opposite changes observed at higher energy at 4 - 5 eV, appearing on a broad-band background due to the strongly dipole-allowed O 2p -- Mn 3d transition around the charge-transfer energy 4.7 eV. Based on the observation of a pronounced spectral-weight transfer between low- and high-energy features upon magnetic ordering, they are assigned to high-spin and low-spin intersite d^4d^4 - d^3d^5 transitions by Mn electrons. The anisotropy of the lowest-energy optical band and the spectral weight shifts induced by antiferromagnetic spin correlations are quantitatively described by an effective spin-orbital superexchange model. An analysis of the multiplet structure of the intersite transitions by Mn e_g electrons allowed us to estimate the effective intra-atomic Coulomb interaction, the Hund exchange coupling, and the Jahn-Teller splitting energy between e_g orbitals in LaMnO_3. This study identifies the lowest-energy optical transition at 2 eV as an intersite d-d transition, whose energy is substantially reduced compared to that obtained from the bare intra-atomic Coulomb interaction.Comment: 10 pages, 14 figure

    Properties of coatings based on carbon and nitrogen-doped carbon obtained using a pulsed vacuum arc method

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    Diamond-like carbon coatings on hard-alloy substrates, including coatings doped with nitrogen about 1.0 μm thick have been obtained using a pulse vacuum-arc method. Three types of coatings have been investigated: a carbon diamond-like coating (C), a carbon coating doped with nitrogen (C : N), and a composite coating based on (C : N + C) layer

    VALUE ADDED TOMATO-SAUCE FORTIFIED WITH CHLORELLA PROTEIN ISOLATES

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    The research funding from the Ministry of Science and Higher Education of the Russian Federation is gratefully acknowledged
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