11 research outputs found

    Mathematical Description of Changes of Dried Apple Characteristics during Their Rehydration

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    The mathematical description of changes of dried apples characteristics (mass gain, volume increase, dry matter loss, rehydration indices, and colour) during their rehydration was performed. The effect of conditions of both processes on model parameters were also considered. Apple slices (3 and 10 mm) and cubes (10 mm) were dried in natural convection (drying air velocity 0.01 m/s), forced convection (0.5 and 2 m/s), and fluidisation (6 m/s). Drying air temperatures (Td) were equal to 50, 60, and 70 °C. The rehydration process was carried out in distilled water at the temperatures (Tr) of 20, 45, 70, and 95 °C. Mass gain, volume increase, and dry matter loss were modelled using the following empirical models: Peleg, Pilosof–Boquet–Batholomai, Singh and Kulshrestha, Lewis (Newton), Henderson–Pabis, Page, and modified Page. Colour changes were described through applying the first-order model. Artificial neural networks (feedforward multilayer perceptron) were applied to make the rehydration indices and colour variations (ΔE) dependent on characteristic dimension, Td, drying air velocity, and Tr. The Page and the modified Page models can be considered to be the most appropriate in order to characterise the mass gain (RMSE = 0.0143–0.0619) and the volume increase (RMSE = 0.0142–0.1130), whereas the Peleg, Pilosof–Bouquet–Batholomai, and Singh and Kulshrestha models were found to be the most appropriate to characterise dry matter loss (RMSE = 0.0116–0.0454). The ANNs described rehydration indices and ΔE satisfactorily (RMSE = 0.0567–0.0802). Both considered process conditions influenced (although in different degree) the changes of the considered dried apple characteristics during their rehydration

    Mathematical Description of Changes of Dried Apple Characteristics during Their Rehydration

    No full text
    The mathematical description of changes of dried apples characteristics (mass gain, volume increase, dry matter loss, rehydration indices, and colour) during their rehydration was performed. The effect of conditions of both processes on model parameters were also considered. Apple slices (3 and 10 mm) and cubes (10 mm) were dried in natural convection (drying air velocity 0.01 m/s), forced convection (0.5 and 2 m/s), and fluidisation (6 m/s). Drying air temperatures (Td) were equal to 50, 60, and 70 °C. The rehydration process was carried out in distilled water at the temperatures (Tr) of 20, 45, 70, and 95 °C. Mass gain, volume increase, and dry matter loss were modelled using the following empirical models: Peleg, Pilosof–Boquet–Batholomai, Singh and Kulshrestha, Lewis (Newton), Henderson–Pabis, Page, and modified Page. Colour changes were described through applying the first-order model. Artificial neural networks (feedforward multilayer perceptron) were applied to make the rehydration indices and colour variations (ΔE) dependent on characteristic dimension, Td, drying air velocity, and Tr. The Page and the modified Page models can be considered to be the most appropriate in order to characterise the mass gain (RMSE = 0.0143–0.0619) and the volume increase (RMSE = 0.0142–0.1130), whereas the Peleg, Pilosof–Bouquet–Batholomai, and Singh and Kulshrestha models were found to be the most appropriate to characterise dry matter loss (RMSE = 0.0116–0.0454). The ANNs described rehydration indices and ΔE satisfactorily (RMSE = 0.0567–0.0802). Both considered process conditions influenced (although in different degree) the changes of the considered dried apple characteristics during their rehydration

    Dual Anticoagulant/Antiplatelet Activity of Polyphenolic Grape Seeds Extract

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    Because of the side-effects of commonly used anti-platelet and anticoagulant drugs, investigations into plant substances with similar activities are very common. Based on our own studies in recent years, we estimate that it is possible to use natural compounds to both inhibit coagulation pathway enzymes and to reduce blood platelets’ activation. As such, in our current study we wanted to verify the anti-platelet and anticoagulant properties of grape seed extract (GSE) using in vitro models. During our analysis, the following parameters were analyzed: Coagulation times, thromboelastometry assays (coagulation time, clot formation time and maximum clot firmness), aggregation of platelets and phosphorylation of vasodilator-stimulated phosphoprotein (VASP). Adenosine diphosphate (ADP)-induced aggregation was lower in GSE 7.5 µg/mL as well as in GSE 15.0 µg/mL. A similar dependence was observed in VASP assays for GSE 7.5 µg/mL and GSE 15 µg/mL. The effect on plasma coagulation tests was distinct only with GSE 15 µg/mL. All of the thromboelastometry variables were statistically significant with 15.0 µg/mL GSE concentration. Our results show, for the first time, the multi-potential effect of grape seed extract on coagulation systems, and clearly suggest that grape seed extract could be considered a promising nutraceutical in the prevention of cardiovascular thrombotic events caused by different mechanisms

    Improving functional properties of protective coatings obtained by electrophoretic deposition on steel interconnects for solid oxide cells by tuning particle size distribution

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    This paper analyses the effect of particle size distribution in the suspension on the quality of the resulting coating in the electrophoretic deposition of a protective coating on a steel interconnect for solid oxide cells (SOCs). Mn1.5Co1.5O4 commercial powder was subjected to grinding for 2, 4 and 18 h, and admixing it with the finest fraction was used to form thin layers on Crofer 22APU steel. The functional properties of the coatings, such as density and area-specific resistance (ASR) were evaluated over the respective temperature ranges. The resistivity of the coatings was measured in 60 and 1000 h tests. It was shown that the increase of the fine powder fractions yields a higher density layer, which contributes to slowing down the growth rate of the oxide scale and therefore can decrease ASR by 65%. The lowest resistivity was performed by the samples fabricated with the admixed powder. Post-test analysis by FIB/SEM/EDS did not reveal diffusion of chromium through the fabricated layers (after the 1000 h test), which is a key indicator of the reliability of the formed protective barrier

    Influence of the Contamination of Fuel with Fly Ash Originating from Biomass Gasification on the Performance of the Anode-Supported SOFC

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    The integration of solid oxide fuel cells (SOFCs) with biomass gasification reactors raises the possibility of solid particle contamination of the gaseous fuel entering the cell. Technical specifications from SOFC manufacturers, among other sources, claim that SOFCs do not tolerate the presence of solid particles in fuel. However, there is very limited literature on the experimental investigation of feeding SOFCs with particulate matter aerosols. In this study, a standard 5 × 5 cm anode-supported SOFC was fueled by two types of aerosols, namely, (1) inert powder of grain sizes and concentration equivalent to gasifier fly ash and (2) a real downdraft gasifier fly ash, both suspended in a gaseous fuel mixture. For reference, cells were also investigated with a dust-free fuel gas of the same composition. A straightforward negative influence of the inert powder aerosol could not be confirmed in experiments with a duration of 6 days. That said, the introduction of carbonaceous fly ash aerosol caused slow but irreversible damage to the SOFC. The degradation mechanisms were studied, and the presence of carbon-containing particles was found to clog the pores of the SOFC anode. The maximum measured power density of the SOFC equaled 855 mW/cm2 (850 °C, reference fuel). Feeding inert aerosol fuel caused no rapid changes in power density. A moderate drop in performance was observed throughout the experiment. The contamination of fuel with fly ash resulted in an initial performance gain and a ca. 25% performance drop longer term (43 h of contamination). Post-mortem analysis revealed contamination on the walls of the gas channels, with some visible alumina or fly ash spots in the anode area

    Glass–Zirconia Composites as Seals for Solid Oxide Cells: Preparation, Properties, and Stability over Repeated Thermal Cycles

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    This study focuses on the preparation and characterization of composite gaskets designed for the sealing of the solid oxide cell stacks operating below 700 °C. The seals were fabricated with the addition of various amounts (10–90 wt.%) of 3 mol.% yttria partially stabilized zirconia to a BaO-Al2O3-CaO-SiO2 glass matrix. The sample gaskets in the form of thin frames were shaped by tape casting. The quality of the junctions between the composites and Crofer 22APU steel commonly used as an SOC interconnect was evaluated after thermal treatment of heating to 710 °C, then cooling to the working temperature of around 620 °C and then leaving them for 10h in an air atmosphere, before cooling to room temperature. The samples were also studied after 3, 5, and 10 thermal cycles to determine the changes in microstructure and to evaluate the porosity and possible crystallization of the glass phase. The compression of the seals was calculated on the basis of differences in thickness before and after thermal treatment. The influence of zirconia additions on the mechanical properties of the seals was studied. The experimental results confirmed that glass–ceramic composites are promising materials for gaskets in SOC stacks. The most beneficial properties were obtained for a composite containing 40 wt.% of YSZ

    Predictors of Neurological Outcome Following Infant Cardiac Surgery Without Deep Hypothermic Circulatory Arrest

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    The aim of this study is to describe the clinical characteristics, perioperative course and neuroimaging abnormalities of infants with congenital heart disease (CHD) undergoing heart surgery without deep hypothermic circulatory arrest (DHCA) and identify variables associated with neurological outcome. Infants with CHD undergoing open-heart surgery without DHCA between 2009 and 2017 were identified from a cardiac surgery database. Full-term infants \u3c 10 weeks of age at the time of surgery who had both a pre- and postoperative brain magnetic resonance imaging exam (MRI) were included. Clinical characteristics and perioperative variables were collected from the electronic medical record. Brain Injury Scores (BIS) were assigned to pre- and postoperative brain MRIs. Variables were examined for association with neurological outcome at 12 months of age or greater. Forty-two infants were enrolled in the study, of whom 69% (n = 29) had a neurological assessment ≥ to 12 months of age. Adverse neurological outcome was associated with longer intensive care unit (ICU) stay (P = 0.003), lengthier mechanical ventilation (P = 0.031), modified Blalock-Taussig (MBT) shunt procedure (P = 0.005) and postoperative seizures (P = 0.005). Total BIS scores did not predict outcome but postoperative infarction and/or intraparenchymal hemorrhage (IPH) was associated with worse outcome by multivariable analysis (P = 0.018). Infants with CHD undergoing open-heart surgery without DHCA are at increased risk of worse neurological outcome when their ICU stay is prolonged, mechanical ventilation is extended, MBT shunt is performed or when postoperative seizures are present. Cerebral infarctions and IPH on postoperative MRI are also associated with worse outcome
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