42 research outputs found
On Extracting Mechanical Properties from Nanoindentation at Temperatures up to 1000C
Alloyed MCrAlY bond coats, where M is usually cobalt and/or nickel, are
essential parts of modern turbine blades, imparting environmental resistance
while mediating thermal expansivity differences. Nanoindentation allows the
determination of their properties without the complexities of traditional
mechanical tests, but was not previously possible near turbine operating
temperatures.
Here, we determine the hardness and modulus of CMSX-4 and an Amdry-386 bond
coat by nanoindentation up to 1000C. Both materials exhibit a
constant hardness until 400C followed by considerable softening,
which in CMSX-4 is attributed to the multiple slip systems operating underneath
a Berkovich indenter.
The creep behaviour has been investigated via the nanoindentation hold
segments. Above 700C, the observed creep exponents match the
temperature-dependence of literature values in CMSX-4. In Amdry-386,
nanoindentation produces creep exponents very close to literature data,
implying high-temperature nanoindentation may be powerful in characterising
these coatings and providing inputs for material, model and process
optimisations
Softening non-metallic crystals by inhomogeneous elasticity
High temperature structural materials must be resistant to cracking and oxidation. However, most oxidation resistant materials are brittle and a significant reduction in their yield stress is required if they are to be resistant to cracking. It is shown, using density functional theory, that if a crystal's unit cell elastically deforms in an inhomogeneous manner, the yield stress is greatly reduced, consistent with observations in layered compounds, such as TiâSiCâ, NbâCoâ, WâBâ
, TaâC and TaâCâ. The mechanism by which elastic inhomogeneity reduces the yield stress is explained and the effect demonstrated in a complex metallic alloy, even though the electronegativity differences within the unit cell are less than in the layered compounds. Substantial changes appear possible, suggesting this is a first step in developing a simple way of controlling plastic flow in non-metallic crystals, enabling materials with a greater oxidation resistance and hence a higher temperature capability to be used.The work was supported by the EPSRC/Rolls-Royce Strategic Partnership (EP/M005607/1)
Microcompression experiments on glasses â strain rate sensitive cracking behavior
Figure 11 â microcompression experiments on glasses showing stable crack growth (a) and reversible deformation (b)
It is well known that the mechanical properties of glasses are closely related to their atomic structure. The exact structure-property-relationship, however, is only poorly understood even for fundamental mechanisms like shear and densification. Nanomechanical test methods like micropillar compression and nano indentation can help fill this gap. In this study a sodium-boro-silicate glass is quenched from different temperatures to induce changes in the atomic structure. Micropillar compression was used to introduce plastic deformation into these glasses at room temperature under a uniaxial stress state. By changing the strain rate it is shown that deformation shifts from completely reversible deformation, to stable crack growth, and finally brittle failure. It is shown that by changing the glass structure, the strain rates corresponding to these deformation regimes are shifted. Finally, the occurrence of shear and densification is discussed. These findings are analysed against the background of the glass structure.
Please click Additional Files below to see the full abstract
Deformation of micrometer and mm-sized Fe2.4wt.%Si single- and bi-crystals with a high angle grain boundary at room temperature
Plasticity in body-centred cubic (BCC) metals, including dislocation
interactions at grain boundaries, is much less understood than in face-centred
cubic (FCC) metals. At low temperatures additional resistance to dislocation
motion due to the Peierls barrier becomes important, which increases the
complexity of plasticity. Iron-silicon steel is an interesting, model BCC
material since the evolution of the dislocation structure in
specifically-oriented grains and at particular grain boundaries have
far-reaching effects not only on the deformation behaviour but also on the
magnetic properties, which are important in its final application as electrical
steel. In this study, two different orientations of micropillars (1, 2, 4
microns in diameter) and macropillars (2500 microns) and their corresponding bi
crystals are analysed after compression experiments with respect to the effect
of size on strength and dislocation structures. Using different experimental
methods, such as slip trace analysis, plane tilt analysis and cross-sectional
EBSD, we show that direct slip transmission occurs, and different slip systems
are active in the bi-crystals compared to their single-crystal counterparts.
However, in spite of direct transmission and a very high transmission factor,
dislocation pile-up at the grain boundary is also observed at early stages of
deformation. Moreover, an effect of size scaling with the pillar size in single
crystals and the grain size in bi-crystals is found, which is consistent with
investigations elsewhere in FCC metals
Origins of limited non-basal plasticity in {\mu}-phase at room temperature
We unveil a new non-basal slip mechanism in the {\mu}-phase at room
temperature using nanomechanical testing, transmission electron microscopy and
atomistic simulations. The (1-105) planar faults with a displacement vector of
0.07[-5502] can be formed by dislocation glide. They do not disrupt the
Frank-Kasper packing and therefore enable the accommodation of plastic strain
at low temperatures without requiring atomic diffusion. The intersections
between the (1-105) planar faults and basal slip result in stress concentration
and crack nucleation during loading
Room temperature deformation mechanisms of the C14 Laves Phase in the MgâAlâCa system
In order to improve the creep resistance of magnesium alloys and thereby increase their operating temperature, hard intermetallic phases can be incorporated in the microstructure. In particular the addition of Al or Ca to Mg results in the formation of a skeleton-like intermetallic structure at the grain boundaries. This structure consists predominately of Laves phases, which reduces the minimum creep rate by a few orders of magnitude. In bulk, these Laves phases are extremely brittle at low temperatures, limiting our understanding of the underlying mechanisms of plasticity. Additionally, the small size of the microstructural features in technical alloys make bulk-scale tests unsuitable for studying these phases. Using nanomechanical testing (nanoindentation and microcompression) in individual grains, cracking can be suppressed and plastic deformation can be observed [1]. Micropillars were milled using FIB in individual grains of a polycrystalline specimen, and orientations determined by EBSD to activate and interrogate slip systems. These data have then been combined with slip line analysis around indents. Such an approach reveals the presence of pyramidal, prismatic and basal slip at ambient conditions, with pyramidal 1st order being the predominant slip plane. Critical resolved shear stresses for these slip systems have been calculated, and TEM analysis of the deformation microstructure performed. This work therefore exemplifies how nanomechanical testing in conjunction with electron microscopy can extend the current knowledge of plasticity in macroscopically brittle crystals.
[1] S. Korte, W.J. Clegg, Studying Plasticity in Hard and Soft NbâCo Intermetallics, Advanced Engineering Materials, 14, No. 11 (2012), 991-99
Investigation of the electroplastic effect using nanoindentation
A promising approach to deform metallic-intermetallic composite materials is the application of electric current pulses during the deformation process to achieve a lower yield strength and enhanced elongation to fracture. This is known as the electroplastic effect. In this work, a novel setup to study the electroplastic effect during nanoindentation on individual phases and well-defined interfaces was developed. Using a eutectic Al-Al2Cu alloy as a model material, electroplastic nanoindentation results were directly compared with macroscopic electroplastic compression tests. The results of the micro- and macroscopic investigations reveal current induced displacement shifts and stress drops, respectively, with the first displacement shift/stress drop being higher than the subsequent ones. A higher current intensity, higher loading rate and larger pulsing interval all cause increased displacement shifts. This observation, in conjunction with the fact that the first displacement shift is highest, strongly indicates that de-pinning of dislocations from obstacles dominates the mechanical response, rather than solely thermal effects
Using impactânanoindentation to test glasses at high strain rates and room temperature
In many daily applications glasses are indispensable, and novel applications demanding improved strength and crack resistance are appearing continuously. Up to now, the fundamental mechanical processes in glasses subjected to high strain rates at room temperature are largely unknown and thus guidelines for one of the major failure conditions of glass components are non-existent. Here, we elucidate this important regime for the first time using glasses ranging from a dense metallic glass to open fused silica by impact as well as quasi-static nano-indentation. We show that towards high strain rates, shear deformation becomes the dominant mechanism in all glasses accompanied by Non-Newtonian behavior evident in a drop of viscosity with increasing rate covering eight orders of magnitude. All glasses converge to the same limit stress determined by the theoretical hardness, thus giving the first experimental and quantitative evidence that Non-Newtonian shear flow occurs at the theoretical strength at room temperature
Plasticity of topologically close-packed phases in the Fe-Ta(-Al) system
Understanding the structure-property relationships of materials plays a significant role in the development of materials for technical applications. Due to the many possible combinations of two or more elements, intermetallic phases can be very interesting for these developments. High strength up to high temperatures makes intermetallics promising materials for high-temperature applications. However, their complex structure, resulting in a pronounced brittleness, has so far limited their applicability. We focus on the understanding of plastic deformation in topologically close-packed (TCP) phases, which form one of the largest groups of intermetallics. To do this, we use nanomechanical tests that allow us to study plasticity even in the most brittle materials. Here, we consider the Fe-Ta(-Al) system that contains two closely related TCP phases, a C14 Laves phase and a ”-phase. The building block-like structure of these phases enables a systematic investigation as well as a transfer of the findings to other complex crystals. The mechanical properties of the two TCP phases in the Fe-Ta(-Al) system, investigated by state-of-the-art micromechanical testing, are introduced in this work. The influence of the crystal structure and chemical composition on the mechanical properties and the deformation mechanisms of the TCP phases are discussed