487 research outputs found
Dynamics of diluted magnetic semiconductors from atomistic spin dynamics simulations: Mn doped GaAs as a case study
The dynamical behavior of the magnetism of diluted magnetic semiconductors
(DMS) has been investigated by means of atomistic spin dynamics simulations.
The conclusions drawn from the study are argued to be general for DMS systems
in the low concentration limit, although all simulations are done for 5%
Mn-doped GaAs with various concentrations of As antisite defects. The
magnetization curve, , and the Curie temperature have been
calculated, and are found to be in good correspondence to results from Monte
Carlo simulations and experiments. Furthermore, equilibrium and non-equilibrium
behavior of the magnetic pair correlation function have been extracted. The
dynamics of DMS systems reveals a substantial short ranged magnetic order even
at temperatures at or above the ordering temperature, with a non-vanishing pair
correlation function extending up to several atomic shells. For the high As
antisite concentrations the simulations show a short ranged anti-ferromagnetic
coupling, and a weakened long ranged ferromagnetic coupling. For sufficiently
large concentrations we do not observe any long ranged ferromagnetic
correlation. A typical dynamical response shows that starting from a random
orientation of moments, the spin-correlation develops very fast ( 1ps)
extending up to 15 atomic shells. Above 10 ps in the simulations, the
pair correlation is observed to extend over some 40 atomic shells. The
autocorrelation function has been calculated and compared with ferromagnets
like bcc Fe and spin-glass materials. We find no evidence in our simulations
for a spin-glass behaviour, for any concentration of As antisites. Instead the
magnetic response is better described as slow dynamics, at least when compared
to that of a regular ferromagnet like bcc Fe.Comment: 24 pages, 15 figure
Scaling Law and Aging Phenomena in the Random Energy Model
We study the effect of temperature shift on aging phenomena in the Random
Energy Model (REM). From calculation on the correlation function and simulation
on the Zero-Field-Cooled magnetization, we find that the REM satisfies a
scaling relation even if temperature is shifted. Furthermore, this scaling
property naturally leads to results obtained in experiment and the droplet
theory.Comment: 8 pages, 7 figures, to be submitted to J. Phys. Soc. Jp
Memory Effect, Rejuvenation and Chaos Effect in the Multi-layer Random Energy Model
We introduce magnetization to the Multi-layer Random Energy Model which has a
hierarchical structure, and perform Monte Carlo simulation to observe the
behavior of ac-susceptibility. We find that this model is able to reproduce
three prominent features of spin glasses, i.e., memory effect, rejuvenation and
chaos effect, which were found recently by various experiments on aging
phenomena with temperature variations.Comment: 10 pages, 14 figures, to be submitted to J. Phys. Soc. Jp
Numerical Study of Aging in the Generalized Random Energy Model
Magnetizations are introduced to the Generalized Random Energy Model (GREM)
and numerical simulations on ac susceptibility is made for direct comparison
with experiments in glassy materials. Prominent dynamical natures of spin
glasses, {\it i.e.}, {\em memory} effect and {\em reinitialization}, are
reproduced well in the GREM. The existence of many layers causing continuous
transitions is very important for the two natures. Results of experiments in
other glassy materials such as polymers, supercooled glycerol and orientational
glasses, which are contrast to those in spin glasses, are interpreted well by
the Single-layer Random Energy Model.Comment: 8 pages, 9 figures, to be submitted to J. Phys. Soc. Jp
Relaxation oscillations and negative strain rate sensitivity in the Portevin - Le Chatelier effect
A characteristic feature of the Portevin - Le Chatelier effect or the jerky
flow is the stick-slip nature of stress-strain curves which is believed to
result from the negative strain rate dependence of the flow stress. The latter
is assumed to result from the competition of a few relevant time scales
controlling the dynamics of jerky flow. We address the issue of time scales and
its connection to the negative strain rate sensitivity of the flow stress
within the framework of a model for the jerky flow which is known to reproduce
several experimentally observed features including the negative strain rate
sensitivity of the flow stress. We attempt to understand the above issues by
analyzing the geometry of the slow manifold underlying the relaxational
oscillations in the model. We show that the nature of the relaxational
oscillations is a result of the atypical bent geometry of the slow manifold.
The analysis of the slow manifold structure helps us to understand the time
scales operating in different regions of the slow manifold. Using this
information we are able to establish connection with the strain rate
sensitivity of the flow stress. The analysis also helps us to provide a proper
dynamical interpretation for the negative branch of the strain rate
sensitivity.Comment: 7 figures, To appear in Phys. Rev.
Pseudo-single crystal electrochemistry on polycrystalline electrodes : visualizing activity at grains and grain boundaries on platinum for the Fe2+/Fe3+ redox reaction
The influence of electrode surface structure on electrochemical reaction rates and mechanisms is a major theme in electrochemical research, especially as electrodes with inherent structural heterogeneities are used ubiquitously. Yet, probing local electrochemistry and surface structure at complex surfaces is challenging. In this paper, high spatial resolution scanning electrochemical cell microscopy (SECCM) complemented with electron backscatter diffraction (EBSD) is demonstrated as a means of performing ‘pseudo-single-crystal’ electrochemical measurements at individual grains of a polycrystalline platinum electrode, while also allowing grain boundaries to be probed. Using the Fe2+/3+ couple as an illustrative case, a strong correlation is found between local surface structure and electrochemical activity. Variations in electrochemical activity for individual high index grains, visualized in a weakly adsorbing perchlorate medium, show that there is higher activity on grains with a significant (101) orientation contribution, compared to those with (001) and (111) contribution, consistent with findings on single-crystal electrodes. Interestingly, for Fe2+ oxidation in a sulfate medium a different pattern of activity emerges. Here, SECCM reveals only minor variations in activity between individual grains, again consistent with single-crystal studies, with a greatly enhanced activity at grain boundaries. This suggests that these sites may contribute significantly to the overall electrochemical behavior measured on the macroscale
Aging in KLiTa0: a domain growth interpretation
The aging behaviour of the a.c. susceptibility of randomly substituted
KLiTa0 crystals reveals marked differences with spin-glasses in
that cooling rate effects are very important. The response to temperature steps
(including temperature cycles) was carefully studied. A model based on
thermally activated domain growth accounts for all the experimental results,
provided one allows for a large distribution of pinning energies, in such a way
that `slow' and `fast' domains coexist. Interesting similarities with deeply
supercooled liquids are underlined.Comment: 4 pages. Preprint LPTENS/9820, submitted to Phys. Rev. Let
LATE-NC aggravates GVD-mediated necroptosis in Alzheimer's disease
It has become evident that Alzheimer's Disease (AD) is not only linked to its hallmark lesions-amyloid plaques and neurofibrillary tangles (NFTs)-but also to other co-occurring pathologies. This may lead to synergistic effects of the respective cellular and molecular players, resulting in neuronal death. One of these co-pathologies is the accumulation of phosphorylated transactive-response DNA binding protein 43 (pTDP-43) as neuronal cytoplasmic inclusions, currently considered to represent limbic-predominant age-related TDP-43 encephalopathy neuropathological changes (LATE-NC), in up to 70% of symptomatic AD cases. Granulovacuolar degeneration (GVD) is another AD co-pathology, which also contains TDP-43 and other AD-related proteins. Recently, we found that all proteins required for necroptosis execution, a previously defined programmed form of neuronal cell death, are present in GVD, such as the phosphorylated necroptosis executioner mixed-lineage kinase domain-like protein (pMLKL). Accordingly, this protein is a reliable marker for GVD lesions, similar to other known GVD proteins. Importantly, it is not yet known whether the presence of LATE-NC in symptomatic AD cases is associated with necroptosis pathway activation, presumably contributing to neuron loss by cell death execution. In this study, we investigated the impact of LATE-NC on the severity of necroptosis-associated GVD lesions, phosphorylated tau (pTau) pathology and neuronal density. First, we used 230 human post-mortem cases, including 82 controls without AD neuropathological changes (non-ADNC), 81 non-demented cases with ADNC, i.e.: pathologically-defined preclinical AD (p-preAD) and 67 demented cases with ADNC. We found that Braak NFT stage and LATE-NC stage were good predictors for GVD expansion and neuronal loss in the hippocampal CA1 region. Further, we compared the impact of TDP-43 accumulation on hippocampal expression of pMLKL-positive GVD, pTau as well as on neuronal density in a subset of nine non-ADNC controls, ten symptomatic AD cases with (ADTDP+) and eight without LATE-NC (ADTDP-). Here, we observed increased levels of pMLKL-positive, GVD-exhibiting neurons in ADTDP+ cases, compared to ADTDP- and controls, which was accompanied by augmented pTau pathology. Neuronal loss in the CA1 region was increased in ADTDP+ compared to ADTDP- cases. These data suggest that co-morbid LATE-NC in AD impacts not only pTau pathology but also GVD-mediated necroptosis pathway activation, which results in an accelerated neuronal demise. This further highlights the cumulative and synergistic effects of comorbid pathologies leading to neuronal loss in AD. Accordingly, protection against necroptotic neuronal death appears to be a promising therapeutic option for AD and LATE
Slow dynamics and aging in spin-glasses
Contribution presented by Eric Vincent in the Conference `Complex Behaviour
of Glassy Systems', Sitges, Barcelona, Spain, June, 1996. It contains a review
of the experimental results on Slow dynamics and aging in spin-glasses. It also
presents their comparison with recent theoretical developments in the
description of the out of equilibrium dynamics of disordered systems; namely,
the trap model and the mean-field theory.Comment: 35 pages, 12 figures, macro lmamult.sty (included
- …