53 research outputs found
Physico-chemical characterization of mixed-ligand complexes of Mn(III) based on the acetylacetonate and maleic acid and its hydroxylamine derivative
Two new Mn(III) mixed-ligand complexes with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L] were prepared. Their structure was established by using elemental analysis, FTIR and UV/VIS spectroscopic methods, as well as magnetic measurement. Replacement of the acetylacetonate ligand by the corresponding acid ligand has been confirmed in Mn(III) acetylacetonate. Based on the obtained experimental data and literature indications, structural formulae to these compounds were assigned
Infrared and Raman spectra of LiV2O5 single crystals
The phonon dynamics of LiV2O5 single crystals is studied using infrared and
Raman spectroscopy techniques. The infrared-active phonon frequencies and
dielectric constants are obtained by oscillator fitting procedure of the
reflectivity data measured at room temperature. The Raman scattering spectra
are measured at room temperature and at T=10 K in all nonequivalent polarized
configurations. The assignment of the phonons is done by comparing the infrared
and Raman spectra of LiV2O5 and NaV2O5. The factor-group-analysis of the LiV2O5
crystal symmetry and of its constituent layers is performed to explain the
symmetry properties of the observed modes. We concluded that layer symmetry
dominates in the vibrational properties of this compound.Comment: 10 pages, 5 figure
Thermopower in the strongly overdoped region of single-layer Bi2Sr2CuO6+d superconductor
The evolution of the thermoelectric power S(T) with doping, p, of
single-layer Bi2Sr2CuO6+d ceramics in the strongly overdoped region is studied
in detail. Analysis in term of drag and diffusion contributions indicates a
departure of the diffusion from the T-linear metallic behavior. This effect is
increased in the strongly overdoped range (p~0.2-0.28) and should reflect the
proximity of some topological change.Comment: 4 pages, 4 figure
Charge-ordering and optical transitions of LiV2O5 and NaV2O5
We present the measurements of the polarized optical spectra of NaV2O5 and
LiV2O5. In an energy range from 0.5 to 5.5 eV we observe similar peaks in the E
parallel a spectra of LiV2O5 and NaV2O5, which suggests similar electronic
structure along the a axis in both materials. On the other hand, we find an
almost complete suppression of the peaks in sigma_b of LiV2O5 around 1 and 5
eV. We attribute this suppression to the charge localization originating from
the existence of double-chain charge-ordering patterin in LiV2O5.Comment: 7 pages, 3 figures final version, to appear in PR
One-dimensional dynamics of the d-electrons in -NaVO
We have studied the electronic properties of the ladder compound
-NaVO, adopting a joint experimental and theoretical
approach. The momentum-dependent loss function was measured using electron
energy-loss spectroscopy in transmission. The optical conductivity derived from
the loss function by a Kramers-Kronig analysis agrees well with our results
from LSDA+U band-structure calculations upon application of an
antiferromagnetic alignment of the V~3 spins along the legs and an
on-site Coulomb interaction U of between 2 and 3 eV. The decomposition of the
calculated optical conductivity into contributions from transitions between
selected energy regions of the DOS reveals the origin of the observed
anisotropy of the optical conductivity. In addition, we have investigated the
plasmon excitations related to transitions between the vanadium states within
an effective 16 site vanadium cluster model. Good agreement between the
theoretical and experimental loss function was obtained using the hopping
parameters derived from the tight binding fit to the band-structure and
moderate Coulomb interactions between the electrons within the ab plane.Comment: 23 pages, 8 figures; submitted to PR
Evidence for Two Superconducting Gaps in
We have measured the Raman spectra of polycrystalline MgB from 25 {\cm}
to 1200 {\cm}. When the temperature was decreased below the superconducting
transition temperature , we observed a superconductivity-induced
redistribution in the electronic Raman continuum. Two pair-breaking peaks
appear in the spectra, suggesting the presence of two superconducting gaps.
Furthermore, we have analyzed the measured spectra using a quasi
two-dimensional model in which two s-wave superconducting gaps open on two
sheets of Fermi surface. For the gap values we have obtained (2.7 meV) and (6.2 meV). Our results suggest
that a conventional phonon-mediated pairing mechanism occurs in the planar
boron bands and is responsible for the superconductivity of MgB.Comment: 3 figure
Optical studies of gap, hopping energies and the Anderson-Hubbard parameter in the zigzag-chain compound SrCuO2
We have investigated the electronic structure of the zigzag ladder (chain)
compound SrCuO2 combining polarized optical absorption, reflection,
photoreflectance and pseudo-dielectric function measurements with the model
calculations. These measurements yield an energy gap of 1.42 eV (1.77 eV) at
300 K along (perpendicular) to the Cu-O chains. We have found that the lowest
energy gap, the correlation gap, is temperature independent. The electronic
structure of this oxide is calculated using both the
local-spin-density-approximation with gradient correction method, and the
tight-binding theory for the correlated electrons. The calculated density of
electronic states for non-correlated and correlated electrons shows
quasi-one-dimensional character. The correlation gap values of 1.42 eV
(indirect transition) and 1.88 eV (direct transition) have been calculated with
the electron hopping parameters t = 0.30 eV (along a chain), t_yz = 0.12 eV
(between chains) and the Anderson-Hubbard repulsion on copper sites U= 2.0 eV.
We concluded that SrCuO_2 belongs to the correlated-gap insulators.Comment: 24 pages, 8 figures, to be published in Phys.Rev.
Temperature dependence of optical spectral weights in quarter-filled ladder systems
The temperature dependence of the integrated optical conductivity I(T)
reflects the changes of the kinetic energy as spin and charge correlations
develop. It provides a unique way to explore experimentally the kinetic
properties of strongly correlated systems. We calculated I(T) in the frame of a
t-J-V model at quarter-filling for ladder systems, like NaV_2O_5, and show that
the measured strong T dependence of I(T) for NaV_2O_5 can be explained by the
destruction of short range antiferromagnetic correlations. Thus I(T) provides
detailed information about super-exchange and magnetic energy scales.Comment: 4 pages, 5 figure
Electronic Properties of \alpha'-NaV_2O_5
We studied electronic excitations in NaV2O5 by Raman. Three main topics are
discussed. The first is related to a broad continuum of excitations found in
the 200-1500 cm-1 range and peaked around 680 cm-1. The resonant Raman profile
of this excitation, the polarization selection rules and the presence of its
overtone in resonance conditions allowed us to conclude that the origin of this
feature is magnetic. We proposed that it arises as a result of light coupling
to multi-spinon Raman excitations. Within this scenario we also argued for a
scenario explaining the puzzling temperature dependence of the magnetic
continuum in terms of an increasing role of next nearest neighbor frustration
and in the context of a strongly fluctuating low temperature phase. The second
topic is related to the observation of a folded S = 1 magnetic mode which
displayed very clear selection rules as a function of the magnetic field
orientation. We proposed that the coupling of the photon field to this
excitation takes place via the antisymmetric, Dzyaloshinskii-Moriya (DM),
interaction which, in a simple dimer model, can also explain the observed
selection rules: no splitting or shifts for magnetic fields parallel to the DM
vector and the observation of two (upward and downward) dispersing branches for
fields perpendicular to the DM vector. Thirdly, we discuss the nature of
several new resonances seen below T_c and focus on the possibilities that they
are either folded phonons or singlet bound states of two triplet excitations.
In particular we emphasized the existence of two modes at 66 and 105 cm-1, the
first one being degenerate with one of the spin gap modes.Comment: 29 pages, 19 figure
Low temperature ellipsometry of NaV2O5
The dielectric function of alpha'NaV2O5 was measured with electric field
along the a and b axes in the photon energy range 0.8-4.5 eV for temperatures
down to 4K. We observe a pronounced decrease of the intensity of the 1 eV peak
upon increasing temperature with an activation energy of about 25meV,
indicating that a finite fraction of the rungs becomes occupied with two
electrons while others are emptied as temperature increases. No appreciable
shifts of peaks were found s in the valence state of individual V atoms at the
phase transition is very small. A remarkable inflection of this temperature
dependence at the phase transition at 34 K indicates that charge ordering is
associated with the low temperature phase.Comment: Revisions in style and order of presentation. One new figure. In
press in Physical Review B. REVTeX, 4 pages with 4 postscript figure
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