Spatial distribution of oxygen-18 and deuterium in stream waters across the Japanese archipelago

The spatial distribution of oxygen and hydrogen isotopic composition (δ¹⁸O and δ²H) of stream waters across Japan was clarified with a data set by compiling sample data obtained from 1278 forest catchments during the summer of 2003. Both δ¹⁸O and δ²H values showed positive correlations with the mean annual air temperature and annual evapotranspiration, and negative correlations with latitude and elevation. Deuterium excess (d-excess) values in stream waters were higher on the Sea of Japan side, and lower on the Pacific Ocean side, of the Japanese archipelago. The d-excess in precipitation was generally higher in winter and lower in summer in Japan. The Sea of Japan side experiences a great deal of snowfall, and seasonal changes in monthly precipitation are rather small. In contrast, the Pacific Ocean side experiences a large amount of rainfall during summer with low levels of precipitation during the winter. Therefore, the lower d-excess in stream waters on the Pacific Ocean side reflects summer precipitation, and the higher values on the Sea of Japan side are affected by delayed recharge from snowmelt. The isoscapes of stream water connote not only spatially integrated but also temporally integrated isotope signals of precipitation and provide a framework for addressing applied hydrological, ecological, or meteorological research questions at regional scales, such as the effects of climate change

Reviews and Syntheses: Ocean acidification and its potential impacts on marine ecosystems

Ocean acidification, a complex phenomenon that lowers seawater pH, is the net outcome of several contributions. They include the dissolution of increasing atmospheric CO₂ that adds up with dissolved inorganic carbon (dissolved CO₂, H₂CO₃, HCO₃⁻, and CO₃²⁻) generated upon mineralization of primary producers (PP) and dissolved organic matter (DOM). The aquatic processes leading to inorganic carbon are substantially affected by increased DOM and nutrients via terrestrial runoff, acidic rainfall, increased PP and algal blooms, nitrification, denitrification, sulfate reduction, global warming (GW), and by atmospheric CO₂ itself through enhanced photosynthesis. They are consecutively associated with enhanced ocean acidification, hypoxia in acidified deeper seawater, pathogens, algal toxins, oxidative stress by reactive oxygen species, and thermal stress caused by longer stratification periods as an effect of GW. We discuss the mechanistic insights into the aforementioned processes and pH changes, with particular focus on processes taking place with different timescales (including the diurnal one) in surface and subsurface seawater. This review also discusses these collective influences to assess their potential detrimental effects to marine organisms, and of ecosystem processes and services. Our review of the effects operating in synergy with ocean acidification will provide a broad insight into the potential impact of acidification itself on biological processes. The foreseen danger to marine organisms by acidification is in fact expected to be amplified by several concurrent and interacting phenomena