Study of Mushy-Zone Development in Dendritic Microstructures with Glass-Forming Eutectic Matrices Using Electrostatic Levitation

The coarsening of dendrites in two bulk metallic glass matrix composites was investigated using noncontact techniques in a high vacuum electrostatic levitator. Progressive degrees of coarsening were observed after isothermal holds of varying duration. Specific volume and surface tension during heating and cooling were measured. Hysteresis in specific volume was observed

Towards an understanding of tensile deformation in Ti-based bulk metallic glass matrix composites with BCC dendrites

The microstructure and tension ductility of a series of Ti-based bulk metallic glass matrix composite (BMGMC) is investigated by changing content of the β stabilizing element vanadium while holding the volume fraction of dendritic phase constant. The ability to change only one variable in these novel composites has previously been difficult, leading to uninvestigated areas regarding how composition affects properties. It is shown that the tension ductility can range from near zero percent to over ten percent simply by changing the amount of vanadium in the dendritic phase. This approach may prove useful for the future development of these alloys, which have largely been developed experimentally using trial and error

Compositionally graded metals: A new frontier of additive manufacturing

The current work provides an overview of the state-of-the-art in polymer and metal additive manufacturing and provides a progress report on the science and technology behind gradient metal alloys produced through laser deposition. The research discusses a road map for creating gradient metals using additive manufacturing, demonstrates basic science results obtainable through the methodology, shows examples of prototype gradient hardware, and suggests that Compositionally Graded Metals is an emerging field of metallurgy research

Developing Gradient Metal Alloys through Radial Deposition Additive Manufacturing

Interest in additive manufacturing (AM) has dramatically expanded in the last several years, owing to the paradigm shift that the process provides over conventional manufacturing. Although the vast majority of recent work in AM has focused on three-dimensional printing in polymers, AM techniques for fabricating metal alloys have been available for more than a decade. Here, laser deposition (LD) is used to fabricate multifunctional metal alloys that have a strategically graded composition to alter their mechanical and physical properties. Using the technique in combination with rotational deposition enables fabrication of compositional gradients radially from the center of a sample. A roadmap for developing gradient alloys is presented that uses multi-component phase diagrams as maps for composition selection so as to avoid unwanted phases. Practical applications for the new technology are demonstrated in low-coefficient of thermal expansion radially graded metal inserts for carbon-fiber spacecraft panels

Castable Bulk Metallic Glass Strain Wave Gears: Towards Decreasing the Cost of High-Performance Robotics

The use of bulk metallic glasses (BMGs) as the flexspline in strain wave gears (SWGs), also known as harmonic drives, is presented. SWGs are unique, ultra-precision gearboxes that function through the elastic flexing of a thin-walled cup, called a flexspline. The current research demonstrates that BMGs can be cast at extremely low cost relative to machining and can be implemented into SWGs as an alternative to steel. This approach may significantly reduce the cost of SWGs, enabling lower-cost robotics. The attractive properties of BMGs, such as hardness, elastic limit and yield strength, may also be suitable for extreme environment applications in spacecraft

Castable Bulk Metallic Glass Strain Wave Gears: Towards Decreasing the Cost of High-Performance Robotics

The use of bulk metallic glasses (BMGs) as the flexspline in strain wave gears (SWGs), also known as harmonic drives, is presented. SWGs are unique, ultra-precision gearboxes that function through the elastic flexing of a thin-walled cup, called a flexspline. The current research demonstrates that BMGs can be cast at extremely low cost relative to machining and can be implemented into SWGs as an alternative to steel. This approach may significantly reduce the cost of SWGs, enabling lower-cost robotics. The attractive properties of BMGs, such as hardness, elastic limit and yield strength, may also be suitable for extreme environment applications in spacecraft

A New, Biomimetic Collagen–Apatite Wound-Healing Composite with a Potential Regenerative and Anti-Hemorrhagic Effect in Dental Surgery

The aim of this work was to obtain and characterize composite biomaterials containing two components, namely carbonated hydroxyapatite, which was substituted with Mg2+ and Zn2+ ions, and natural polymer–collagen protein. The following two different types of collagen were used: lyophilized powder of telocollagen from bovine Achilles tendon and atelocollagen solution from bovine dermis. The obtained 3D materials were used as potential matrices for the targeted delivery of tranexamic acid for potential use in wound healing after tooth extractions. Tranexamic acid (TXA) was introduced into composites by two different methods. The physicochemical analyses of the obtained composites included Fourier-transform infrared spectroscopy (FT-IR), inductively coupled plasma–optical emission spectroscopy (ICP-OES), transmission electron microscopy (TEM), scanning electron microscopy (SEM), powder X-ray diffraction (PXRD), release kinetics tests, swelling test, and cytotoxicity assays. The studies showed that the proposed synthetic methods yielded biomaterials with favorable physicochemical properties, as well as the expected release profile of the drug and ions from the matrices

Selenium-Doped Hydroxyapatite Nanocrystals–Synthesis, Physicochemical Properties and Biological Significance

Hydroxyapatites (HAs), as materials with a similar structure to bone minerals, play a key role in biomaterials engineering. They have been applied as bone substitute materials and as coatings for metallic implants, which facilitates their osseointegration. One of the beneficial characteristics of HA, when used to create biocompatible materials with improved physicochemical or biological properties, is its capacity for ionic substitution. The aim of the study was to present the current state of knowledge about HAs containing selenate ions IV or VI. The enrichment of HAs with selenium aims to create a material with advantageous effects on bone tissue metabolism, as well as having anticancer and antibacterial activity. The work is devoted to both methods of obtaining Se-HA and an evaluation of its chemical structure and physicochemical properties. In addition, the biological activity of such materials in vitro and in vivo is discussed

Effect of cooling rate on the volume fraction of B2 phases in a CuZrAlCo metallic glass matrix composite

The material properties of bulk metallic glass matrix composites (BMGMCs) depend strongly on the morphology and elastic constants of the included crystalline phase. Transformation induced plasticity (TRIP) BMGMCs based on the Cu–Zr system are alternatives to traditional dendrite-reinforced BMGMCs. Samples of a representative alloy, Zr_(48)Cu_(47.5)Al_4Co_(0.5), are fabricated in various dimensions and characterized using DSC, SEM, and ultrasonic measurement of elastic constants. It is shown that the Cu–Zr system uniquely softens during crystallization, and the microstructure of the alloy depends strongly on the rate of cooling. We conclude by discussing how combinations of part design and alloy development could be used to utilize these alloys in applications

New Methods for Developing and Manufacturing Compliant Mechanisms Utilizing Bulk Metallic Glass

Compliant mechanisms rely on the elastic bending of thin members to generate motion. In the paper by Homer, et al., bulk metallic glasses (BMGs) are shown to have an optimal combination of mechanical properties and processing ability, making them ideal for complex, low-cost compliant mechanisms