Selective Laser Sintering and Freeze Extrusion Fabrication of Scaffolds for Bone Repair using 13-93 Bioactive Glass: A Comparison

13-93 glass is a third-generation bioactive material which accelerates the bone’s natural ability to heal by itself through bonding with surrounding tissues. It is an important requirement for synthetic scaffolds to maintain their bioactivity and mechanical strength with a porous internal architecture comparable to that of a human bone. Additive manufacturing technologies provide a better control over design and fabrication of porous structures than conventional methods. In this paper, we discuss and compare some of the common aspects in the scaffold fabrication using two such processes, viz. selective laser sintering (SLS) and freeze extrusion fabrication (FEF). Scaffolds fabricated using each process were structurally characterized and microstructure analysis was performed to study process differences. Compressive strength higher than that of human trabecular bone was achieved using SLS process and strength almost comparable to that of human cortical bone was achieved using FEF process

Energy-dependent Ps-He momentum-transfer cross section at low energies

Positronium (Ps)-He scattering presents one of the few opportunities for both theory and experiment to tackle the fundamental interactions of Ps with ordinary matter. Below the dissociation energy of 6.8 eV, experimental and theoretical work has struggled to find agreement on the strength of this interaction as measured by the momentum-transfer cross section (Ïm). Here, we present work utilizing the Doppler broadening technique with an age-momentum correlation apparatus. This work demonstrates a strong energy dependence for this cross section at energies below 1 eV and is consistent with previous experimental results

Memory Effects in Granular Material

We present a combined experimental and theoretical study of memory effects in vibration-induced compaction of granular materials. In particular, the response of the system to an abrupt change in shaking intensity is measured. At short times after the perturbation a granular analog of aging in glasses is observed. Using a simple two-state model, we are able to explain this short-time response. We also discuss the possibility for the system to obey an approximate pseudo-fluctuation-dissipation theorem relationship and relate our work to earlier experimental and theoretical studies of the problem.Comment: 5 pages, 4 figures, reference list change

Reversible Random Sequential Adsorption of Dimers on a Triangular Lattice

We report on simulations of reversible random sequential adsorption of dimers on three different lattices: a one-dimensional lattice, a two-dimensional triangular lattice, and a two-dimensional triangular lattice with the nearest neighbors excluded. In addition to the adsorption of particles at a rate K+, we allow particles to leave the surface at a rate K-. The results from the one-dimensional lattice model agree with previous results for the continuous parking lot model. In particular, the long-time behavior is dominated by collective events involving two particles. We were able to directly confirm the importance of two-particle events in the simple two-dimensional triangular lattice. For the two-dimensional triangular lattice with the nearest neighbors excluded, the observed dynamics are consistent with this picture. The two-dimensional simulations were motivated by measurements of Ca++ binding to Langmuir monolayers. The two cases were chosen to model the effects of changing pH in the experimental system.Comment: 9 pages, 10 figure

Slow relaxation due to optimization and restructuring: Solution on a hierarchical lattice

Motivated by the large strain shear of loose granular materials we introduced a model which consists of consecutive optimization and restructuring steps leading to a self organization of a density field. The extensive connections to other models of statistical phyics are discussed. We investigate our model on a hierarchical lattice which allows an exact asymptotic renormalization treatment. A surprisingly close analogy is observed between the simulation results on the regular and the hierarchical lattices. The dynamics is characterized by the breakdown of ergodicity, by unusual system size effects in the development of the average density as well as by the age distribution, the latter showing multifractal properties.Comment: 11 pages, 7 figures revtex, submitted to PRE see also: cond-mat/020920

Phenomenological glass model for vibratory granular compaction

A model for weakly excited granular media is derived by combining the free volume argument of Nowak et al. [Phys. Rev. E 57, 1971 (1998)] and the phenomenological model for supercooled liquids of Adam and Gibbs [J. Chem. Phys. 43, 139 (1965)]. This is made possible by relating the granular excitation parameter \Gamma, defined as the peak acceleration of the driving pulse scaled by gravity, to a temperature-like parameter \eta(\Gamma). The resulting master equation is formally identical to that of Bouchaud's trap model for glasses [J. Phys. I 2, 1705 (1992)]. Analytic and simulation results are shown to compare favourably with a range of known experimental behaviour. This includes the logarithmic densification and power spectrum of fluctuations under constant \eta, the annealing curve when \eta is varied cyclically in time, and memory effects observed for a discontinuous shift in \eta. Finally, we discuss the physical interpretation of the model parameters and suggest further experiments for this class of systems.Comment: 2 references added; some figure labels tweaked. To appear in PR

On the Glassy Behavior of Parking Lot Model

We present a theoretical discussion of the reversible parking problem, which appears to be one of the simplest systems exhibiting glassy behavior. The existence of slow relaxation, nontrivial fluctuations, and an annealing effect can all be understood by recognizing that two different time scales are present in the problem. One of these scales corresponds to the fast filling of existing voids, the other is associated with collective processes that overcome partial ergodicity breaking. The results of the theory are in a good agreement with simulation data; they provide a simple qualitative picture for understanding recent granular compaction experiments and other glassy systems.Comment: LaTeX, 19 pages; 6 PostScript figure

Compaction of Rods: Relaxation and Ordering in Vibrated, Anisotropic Granular Material

We report on experiments to measure the temporal and spatial evolution of packing arrangements of anisotropic, cylindrical granular material, using high-resolution capacitive monitoring. In these experiments, the particle configurations start from an initially disordered, low-packing-fraction state and under vertical vibrations evolve to a dense, highly ordered, nematic state in which the long particle axes align with the vertical tube walls. We find that the orientational ordering process is reflected in a characteristic, steep rise in the local packing fraction. At any given height inside the packing, the ordering is initiated at the container walls and proceeds inward. We explore the evolution of the local as well as the height-averaged packing fraction as a function of vibration parameters and compare our results to relaxation experiments conducted on spherically shaped granular materials.Comment: 9 pages incl. 7 figure

Glassy systems under time-dependent driving forces: application to slow granular rheology

We study the dynamics of a glassy model with infinite range interactions externally driven by an oscillatory force. We find a well-defined transition in the (Temperature-Amplitude-Frequency) phase diagram between (i) a `glassy' state characterized by the slow relaxation of one-time quantities, aging in two-time quantities and a modification of the equilibrium fluctuation-dissipation relation; and (ii) a `liquid' state with a finite relaxation time. In the glassy phase, the degrees of freedom governing the slow relaxation are thermalized to an effective temperature. Using Monte-Carlo simulations, we investigate the effect of trapping regions in phase space on the driven dynamics. We find that it alternates between periods of rapid motion and periods of trapping. These results confirm the strong analogies between the slow granular rheology and the dynamics of glasses. They also provide a theoretical underpinning to earlier attempts to present a thermodynamic description of moderately driven granular materials.Comment: Version accepted for publication - Physical Review