80 research outputs found
2-(2H-Benzotriazol-2-yl)-6-[(diethylamino)methyl]-4-methylphenol
In the title compound, C18H22N4O, the dihedral angle between the planes of the benzotriazol unit and the phenyl ring of the phenoxy group is 6.4 (2)°. There is an intramolecular O—H⋯N hydrogen bond between the phenol and benzotriazol groups
(E)-2-(2H-Benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl)phenol
In the title compound, C20H16N4O, the non-H atoms of the benzotriazole ring system and those of the methylphenol group are essentially coplanar, with an r.m.s. deviation of 0.004 (2) Å. The mean plane of these atoms forms a dihedral angle of 60.9 (2)° with the phenyl ring. There is an intramolecular O—H⋯N hydrogen bond between the phenol and benzotriazole groups
(E)-N-{2-[1-(Benzylimino)ethyl]phenyl}benzamide
In the title compound, C22H20N2O, the molecular conformation is supported by an intramolecular N—H⋯N hydrogen bond, resulting in an almost planar [mean deviation = 0.048 (2) Å] S(6) ring. The dihedral angles between the central benzene ring and the imine- and amide-substituted aromatic rings are 76.6 (2) and 11.7 (2)°, respectively
3,3′-Di-tert-butyl-2′-hydroxy-5,5′,6,6′-tetramethylbiphenyl-2-yl benzenesulfonate
In the title compound, C30H38O4S, the hydroxyl group bonded to one phenyl ring and an O atom of the benzenesulfonate group attached to the other phenyl ring of the biphenyl backbone of the structure are involved in an intramolecular O—H⋯O hydrogen bond. The dihedral angle between the planes of the two aromatic rings of the biphenyl unit is 70.4 (2)°
(E)-N-[2-(Benzyliminomethyl)phenyl]-2,6-diisopropylaniline
The molecular conformation of the title compound, C26H30N2, is reinforced by an intramolecular N—H⋯N hydrogen bond, resulting in an almost planar [mean deviation of 0.023 (2) Å] S(6) ring. The dihedral angles between the central benzene ring and the terminal unsubstituted and substituted aromatic rings are 64.45 (9) and 89.40 (8)°, respectively
Bis(μ-9-anthracenemethanolato)bis[dimethylaluminium(III)]
The title complex, [Al2(CH3)4(C15H11O)2], is dimeric bridged through the O atoms of the 9-anthracenemethanolate anions. Each Al atom is tetracoordinated by two bridging O atoms from two different 9-anthracenemethanolate ligands and by two C atoms from two methyl groups, forming a distorted tetrahedral environment. The average Al—O bond distance in the Al2O2 core is 1.845 Å
Bis[μ-2-(2H-benzotriazol-2-yl)-4-methylphenolato]bis[dimethylaluminium(III)]
The title complex, [Al2(CH3)4(C13H10N3O)2], is dimeric, bridged through the O atoms of the phenolate anions. The asymmetric unit contains one half of the molecule and there is a crystallographic inversion centre in this molecule. Each Al atom is pentacoordinated by one N atom and two bridging O atoms of two N,O-bidentate benzotriazolylphenolate ligands and by two C atoms from two methyl groups, forming a distorted trigonal–bipyramidal environment
Bis[2-(2H-benzotriazol-2-yl)-4-methyl-6-(phenyliminomethyl-κN)phenolato-κO]palladium(II)
In the title complex, [Pd(C20H15N4O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate imine–benzotriazole phenolate ligands, forming a square-planar environment. The asymmetric unit contains two half-molecules in both of which the PdII atom lies on a centre of symmetry. The average distances between the PdII atom and the coordinated O and N atoms are 1.9831 (12) and 2.012 (2) Å, respectively
Bis[2-(2H-benzotriazol-2-yl)-4-methylphenolato]palladium(II)
In the title complex, [Pd(C13H10N3O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate 2-(2H-benzotriazol-2-yl)-4-methylphenolate ligands, forming a square-planar environment. The asymmetric unit contains one half molecule in which the Pd atom lies on a centre of symmetry
- …