9 research outputs found
Experimental study of the Ca2 1S+1S asymptote
The filtered laser excitation technique was applied for measuring transition
frequencies of the Ca B-X system from asymptotic levels of the
X ground state reaching . That level has an
outer classical turning point of about 20~\AA which is only 0.2 \rcm below the
molecular SS asymptote. Extensive analysis of the spectroscopic data,
involving Monte Carlo simulation, allowed for a purely experimental
determination of the long range parameters of the potential energy curve. The
possible values of the s-wave scattering length could be limited to be between
250 and 1000.Comment: 10 pages, 7 figure