28 research outputs found
Combined optical and electrical modeling of polymer:fullerene bulk heterojunction solar cells
Optical characterization of inhomogeneous thin films containing transition layers using the combined method of spectroscopic ellipsometry and spectroscopic reflectometry based on multiple-beam interference model
Novel, Fourier Filtering Method That Reuses Interference-Patterned Spectra to Extend the Calibration Set for Thickness Determination
Eliminating the Interference Pattern in Near-Infrared Spectra Used for Identification of Thin Plastic Foils
Combined optical and electrical modeling of polymer:fullerene bulk heterojunction solar cells
Optical interference effects are important for the total absorption as well as the profile of the exciton generation rate in polymer:fullerene bulk heterojunction solar cells. For solar cells with an active layer of poly[2-methoxy-5-(3',7'-dimethyloctyloxy)-1,4-phenylenevinylene] as electron donor and [6,6]-phenyl C61 butyric acid methyl ester as electron acceptor, the total exciton generation rate can be directly extracted from the saturated photocurrent. It is demonstrated that for solar cells with an active layer thickness smaller than 250 nm, a constant exciton generation profile, based on this extracted total rate, gives identical electrical characteristics as compared to exciton generation profiles from an optical model. For thicker cells interference effects have to be taken into account, since a uniform generation profile leads to an overestimation of recombination losses and space-charge formation.