1 research outputs found
On hydrogen bond correlations at high pressures
In situ high pressure neutron diffraction measured lengths of O H and H O
pairs in hydrogen bonds in substances are shown to follow the correlation
between them established from 0.1 MPa data on different chemical compounds. In
particular, the conclusion by Nelmes et al that their high pressure data on ice
VIII differ from it is not supported. For compounds in which the O H stretching
frequencies red shift under pressure, it is shown that wherever structural data
is available, they follow the stretching frequency versus H O (or O O) distance
correlation. For compounds displaying blue shifts with pressure an analogy
appears to exist with improper hydrogen bonds.Comment: 12 pages,4 figure