Metastable Solid Solutions in the Gallium Antimonide-Germanium Pseudobinary System

Abstract unavailable

Metastable Electron Compound in Ag-Ge Alloys

Abstract unavailable

Prediction of explosive yield and other characteristics of liquid propellant rocket explosions Final report

Explosive hazards and yield predictions for liquid rocket propellant

Effects of publication bias on conservation planning

Conservation planning needs reliable information on spatial patterns of biodiversity. However, existing data sets are skewed: some habitats, taxa, and locations are under-represented. Here, we map geographic publication density at the sub-national scale of individual 'provinces'. We query the Web of Science catalogues SCI and SSCI for biodiversity-related publications including country and province names (for the period 1993-2016). We combine these data with other provincial-scale factors hypothesised to affect research (i.e. economic development, human presence, infrastructure and remoteness). We show that sites that appear to be understudied, compared with the biodiversity expected from their bioclimatic conditions, are likely to have been inaccessible to researchers for a diversity of reasons amongst which current or recent armed conflicts are notable. Finally, we create a priority list of provinces where geographic publication bias is of most concern, and discuss how our provincial-scale model can assist in adjusting for publication biases in conservation planning.Comment: 10 pages; 3 figures; 1 table;R code on https://github.com/raffael-hickisch; data at https://zenodo.org/record/998889; interactive at http://bit.ly/publication_density_ma

Distorted Copulas: Constructions and Tail Dependence

Given a copula C, we examine under which conditions on an order isomorphism ψ of [0, 1] the distortion C ψ: [0, 1]2 → [0, 1], C ψ(x, y) = ψ{C[ψ−1(x), ψ−1(y)]} is again a copula. In particular, when the copula C is totally positive of order 2, we give a sufficient condition on ψ that ensures that any distortion of C by means of ψ is again a copula. The presented results allow us to introduce in a more flexible way families of copulas exhibiting different behavior in the tails

Population Changes and Location-Specific Differences for Otolith-Derived Age and Growth of Recreationally Harvested Spotted Seatrout (Cynoscion nebulosus) From Alabama in 2007

Spotted seatrout (Cynoscion nebulosus), is a nonmigratory game fish common in the Gulf of Mexico that is important in estuarine ecosystems. Population dynamics of spotted seatrout were examined using otolith-based age-and-growth models derived from observed and back-calculated length-at-age values. These data were used to identify sex-based differences and annular variation. Recent growth was quantified, using marginal increment analysis for comparisons between sexes and the two major bays in Alabama (Mobile Bay and Mississippi Sound). Sex ratios were also compared for these locations. Our results show that females were larger than males and that fish collected in Mobile Bay were larger than those from Mississippi Sound. Combined data from both bays resulted in a sex ratio that approached 1 : 1; however, examination of each bay individually showed that the Mississippi Sound had a female-biased population and that Mobile Bay had a male-biased population. Differences in observed length-at-age measurements became evident between males and females by age 2 with females typically larger than males, whereas the maximum age for males was greater. The oldest females were age 5 and the oldest males were age 8. Compared to previous estimates of trout growth in Alabama, results showed an increase in the modal length of fish and increased growth rates. Results suggest faster growth of the fish in the current population and decreased harvest of larger fish compared to historic estimates. This may be indicative of ecosystem-wide changes in spotted seatrout populations and highlights the need to closely monitor this population

Selective Analysis of Redox Processes at the Electrode Interface with Time-Resolved Raman Spectroscopy

Electrochemistry and electrochemical reactions are increasingly important in the transition to a sustainable chemical industry. The electron transfer that drives such reactions takes place within nanometers of the electrode surface, and follow-up chemical reactions take place within the diffusion layer. Hence, understanding electrochemical reactions requires time-, potential-, and spatially resolved analysis. The confocal nature of Raman spectroscopy provides high spatial resolution, in addition to detailed information on molecular structure. The intrinsic weakness of nonresonant Raman scattering, however, is not sensitive enough for relatively minor changes to the solution resulting from reactions at the electrode interface. Indeed, the limit of detection is typically well above the concentrations used in electrochemical studies. Here, we show that surface-enhanced Raman scattering (SERS) and resonance Raman (rR) spectroscopy allow for spatially and time-resolved analysis of solution composition at (&lt;1-2 nm) and near (within 5 μm) the electrode surface, respectively, in a selective manner for species present at low (&lt;1 mM) concentrations. We show changes in concentration of species at the electrode surface, without the need for labels, specific adsorption, or resonance enhancement, using a SERS-active gold electrode prepared readily by electrochemical surface roughening. A combination of smooth and roughened gold electrodes is used to distinguish between surface and resonance enhancement using the well-known redox couples ferrocene and 2,2’-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS). We discuss the impact of specific adsorption on the spectral analysis with the ruthenium(II) polypyridyl complex, [Ru(bpy)3]2+. The dual function of the electrode (surface enhancement and electron transfer) in the analysis of solution processes is demonstrated with the reversible oxidation of TMA (4,N,N-trimethylaniline), where transient soluble species are identified in real time, with rapid spectral acquisition, making use of localized enhancement. We anticipate that this approach will find use in elucidating electro(catalytic) reactions at electrode interfaces.</p

Strain localization and percolation of stable structure in amorphous solids

Spontaneous strain localization occurs during mechanical tests of a model amorphous solid simulated using molecular dynamics. The degree of localization depends upon the extent of structural relaxation prior to mechanical testing. In the most rapidly quenched samples higher strain rates lead to increased localization, while the more gradually quenched samples exhibit the opposite strain rate dependence. This transition coincides with the k-core percolation of atoms with quasi-crystal-like short range order. The authors infer the existence of a related microstructural length scale.Comment: 4 pages, 4 figure

Identifying stellar streams in the 1st RAVE public data release

We searched for and detected stellar streams or moving groups in the solar neighbourhood, using the data provided by the 1st RAVE public data release. This analysis is based on distances to RAVE stars estimated from a color-magnitude relation that was calibrated on Hipparcos stars. Our final sample consists of 7015 stars selected to be within 500 pc of the Sun and to have distance errors better than 25%. Together with radial velocities from RAVE and proper motions from various data bases, there are estimates for all 6 phase-space coordinates of the stars in the sample. We characterize the orbits of these stars through suitable proxies for their angular momentum and eccentricity, and compare the observed distribution to the expectations from a smooth distribution. On this basis we identify at least four "phase space overdensities" of stars on very similar orbits in the Solar neighbourhood. We estimate the statistical significance of these overdensities by Monte Carlo simulations. Three of them have been identified previously: the Sirius and Hercules moving group and a stream found independently in 2006 by Arifyanto and Fuchs and Helmi et al. In addition, we have found a new stream candidate on a quite radial orbit, suggesting an origin external to the Milky Way's disk. Also, there is evidence for the Arcturus stream and the Hyades-Pleiades moving group in the sample. This analysis, using only a minute fraction of the final RAVE data set, shows the power of this experiment to probe the phase-space substructure of stars around the Sun.Comment: accepted for publication in Ap