1,020 research outputs found
Electron spin relaxation of N@C60 in CS2
We examine the temperature dependence of the relaxation times of the
molecules N@C60 and N@C70 (which comprise atomic nitrogen trapped within a
carbon cage) in liquid CS2 solution. The results are inconsistent with the
fluctuating zero field splitting (ZFS) mechanism, which is commonly invoked to
explain electron spin relaxation for S > 1/2 spins in liquid solution, and is
the mechanism postulated in the literature for these systems. Instead, we find
a clear Arrhenius temperature dependence for N@C60, indicating the spin
relaxation is driven primarily by an Orbach process. For the asymmetric N@C70
molecule, which has a permanent non-zero ZFS, we resolve an additional
relaxation mechanism caused by the rapid reorientation of its ZFS. We also
report the longest coherence time (T2) ever observed for a molecular electron
spin, being 0.25 ms at 170K.Comment: 6 pages, 6 figures V2: Updated to published versio
Topological Aspect of high- Superconductivity, Fractional Quantum Hall Effect and Berry Phase
We have analysed here the equivalence of RVB states with FQH states
in terms of the Berry Phase which is associated with the chiral anomaly in 3+1
dimensions. It is observed that the 3-dimensional spinons and holons are
characterised by the non-Abelian Berry phase and these reduce to 1/2 fractional
statistics when the motion is confined to the equatorial planes. The
topological mechanism of superconductivity is analogous to the topological
aspects of fractional quantum Hall effect with .Comment: 12 pages latex fil
The viscous slowing down of supercooled liquids as a temperature-controlled superArrhenius activated process: a description in terms of frustration-limited domains
We propose that the salient feature to be explained about the glass
transition of supercooled liquids is the temperature-controlled superArrhenius
activated nature of the viscous slowing down, more strikingly seen in
weakly-bonded, fragile systems. In the light of this observation, the relevance
of simple models of spherically interacting particles and that of models based
on free-volume congested dynamics are questioned. Finally, we discuss how the
main aspects of the phenomenology of supercooled liquids, including the
crossover from Arrhenius to superArrhenius activated behavior and the
heterogeneous character of the relaxation, can be described by an
approach based on frustration-limited domains.Comment: 13 pages, 4 figures, accepted in J. Phys.: Condensed Matter,
proceedings of the Trieste workshop on "Unifying Concepts in Glass Physics
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