A Hydronium Solvate Ionic Liquid: Facile Synthesis of Air-Stable Ionic Liquid with Strong Bronsted Acidity

This was Paper 3475 presented at the Honolulu, Hawaii, Meeting of the Society, October 2–7, 2016.A new kind of ionic liquid (IL) with strong Brønsted acidity, i.e., a hydronium (H₃O⁺) solvate ionic liquid, is reported. The IL can be described as [H₃O⁺·18C6]Tf₂N, where water exists as the H₃O⁺ ion solvated by 18-crown-6-ether (18C6), of which the counter anion is bis(trifluoromethylsulfonyl)amide (Tf₂N⁻; Tf = CF₃SO₂). The hydrophobic Tf₂N⁻ anion makes [H₃O⁺·18C6]Tf₂N, evaluated using the indicator method, is a new record for ILs and indicates strong aciditiy. The findings regarding this proton-condensed solvate IL are of fundamental interest, and will help in the design of media for new acid-base reactions

A Hydronium Solvate Ionic Liquid: Ligand Exchange Conduction Driven by Labile Solvation

We observed a new class of proton conduction in a hydronium (H₃O⁺) solvate ionic liquid (IL). The IL is described as [H₃O⁺·18C6]Tf₂N⁻; Tf = CF₃SO₂) anion. Self-diffusion coefficient measurements revealed that protons of H₃O⁺ (solute ion) move faster than 18C6 ligand (solvent), marking the first observation of ligand exchange conduction not only among solvate ILs but also among protic ILs without free neutral molecules. The presence of ligand exchange conduction without inducing external electric field indicates that solvation of H₃O⁺ by 18C6 is kinetically labile, i.e. ligand exchange is very fast for the reaction H₂O + 18C6 + HTf₂N ⇌ H₃O⁺·18C6]Tf₂N, while the equilibrium shifts to the right. The fundamental findings regarding the hydronium solvate IL will help in the design of proton conductors