87 research outputs found
Kinetically-controlled thin-film growth of layered - and NaCoO cobaltate
We report growth characteristics of epitaxial -NaCoO and
-NaCoO thin films on (001) sapphire substrates grown by
pulsed-laser deposition. Reduction of deposition rate could change structure of
NaCoO thin film from -phase with island growth mode to
-phase with layer-by-layer growth mode. The
-NaCoO thin film exhibits spiral surface growth with
multiterraced islands and highly crystallized texture compared to that of the
-NaCoO thin film. This heterogeneous epitaxial film growth
can give opportunity of strain effect of physical properties and growth
dynamics of NaCoO as well as subtle nature of structural change.Comment: accepted for publication in Applied Physics Letter
Graphyne: Hexagonal network of carbon with versatile Dirac cones
We study alpha, beta, and gamma graphyne, a class of graphene allotropes with
carbon triple bonds, using a first-principles density-functional method and
tight-binding calculation. We find that graphyne has versatile Dirac cones and
it is due to remarkable roles of the carbon triple bonds in electronic and
atomic structures. The carbon triple bonds modulate effective hopping matrix
elements and reverse their signs, resulting in Dirac cones with reversed
chirality in alpha graphyne, momentum shift of the Dirac point in beta
graphyne, and switch of the energy gap in gamma graphyne. Furthermore, the
triple bonds provide chemisorption sites of adatoms which can break sublattice
symmetry while preserving planar sp2-bonding networks. These features of
graphyne open new possibilities for electronic applications of carbon-based
two-dimensional materials and derived nanostructures.Comment: 5 pages, 5 figures, 1 tabl
Improving the mechanical properties of single-walled carbon nanotube sheets by intercalation of polymeric adhesives
Organic polymers, such as poly(vinyl alcohol), poly(vinyl pyrrolidone), and poly(styrene), were intercalated into single-walled carbon nanotube sheets by soaking the sheets in polymer solutions. Even for short soak times, significant polymer intercalation into existing free volume was observed. Tensile tests on intercalated sheets showed that the Young\u27s modulus, strength, and toughness increased by factors of 3, 9, and 28, respectively, indicating that the intercalated polymer enhances load transmission between nanotubes
Anomalous field-dependent specific heat in charge-ordered PrCaMnO and LaCaMnO
We report low temperature specific heat measurements of
PrCaMnO () and
LaCaMnO with and without applied magnetic field. An
excess specific heat, , of non-magnetic origin associated with
charge ordering is found for all the samples. A magnetic field sufficient to
induce the transition from the charge-ordered state to the ferromagnetic
metallic state does not completely remove the contribution. This
suggests that the charge ordering is not completely destroyed by a "melting"
magnetic field. In addition, the specific heat of the
PrCaMnO compounds exhibit a large contribution linear in
temperature () originating from magnetic and charge disorder.Comment: submitted to PRL 5 pages, 3 figures include
Structural and doping effects in the half-metallic double perovskite CrWO
he structural, transport, magnetic and optical properties of the double
perovskite CrWO with have been studied. By
varying the alkaline earth ion on the site, the influence of steric effects
on the Curie temperature and the saturation magnetization has been
determined. A maximum K was found for SrCrWO having an almost
undistorted perovskite structure with a tolerance factor . For
CaCrWO and BaCrWO structural changes result in a strong
reduction of . Our study strongly suggests that for the double perovskites
in general an optimum is achieved only for , that is, for an
undistorted perovskite structure. Electron doping in SrCrWO by a
partial substitution of Sr by La was found to reduce both
and the saturation magnetization . The reduction of could be
attributed both to band structure effects and the Cr/W antisites induced by
doping. Band structure calculations for SrCrWO predict an energy gap in
the spin-up band, but a finite density of states for the spin-down band. The
predictions of the band structure calculation are consistent with our optical
measurements. Our experimental results support the presence of a kinetic energy
driven mechanism in CrWO, where ferromagnetism is stabilized by a
hybridization of states of the nonmagnetic W-site positioned in between the
high spin Cr-sites.Comment: 14 pages, 10 figure
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