On the High--Velocity Ejecta of the Type Ia Supernova 1994D

Synthetic spectra generated with the parameterized supernova synthetic-spectrum code SYNOW are compared to spectra of the Type Ia SN 1994D that were obtained before the time of maximum brightness. Evidence is found for the presence of two-component Fe II and Ca II features, forming in high velocity ($\ge 20,000$ \kms) and lower velocity ($\le 16,000$ \kms) matter. Possible interpretations of these spectral splits, and implications for using early--time spectra of SNe Ia to probe the metallicity of the progenitor white dwarf and the nature of the nuclear burning front in the outer layers of the explosion, are discussed.Comment: 15 pages, 3 figures, 3 tables, Astrophysical Journal, in pres

The Photophysical Properties Investigation of Hybrid Associates of Methylene Blue Molecules with Colloidal CdS Quantum Dots and CdS / Cd(OH)2 "Core-Shell" Systems

The spectral properties of associates of methylene blue molecules with colloidal CdS quantum dots and CdS / Cd(OH)2 «core-shell» systems were investigated. It is shown that according to env ironment methylene blue changes its photophysical properties during association. These properties are due to changes of MB structure as a result of oxidation-reduction reactions. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/3527

Subaru and Keck Observations of the Peculiar Type Ia Supernova 2006gz at Late Phases

Recently, a few peculiar Type Ia supernovae (SNe) that show exceptionally large peak luminosity have been discovered. Their luminosity requires more than 1 Msun of 56Ni ejected during the explosion, suggesting that they might have originated from super-Chandrasekhar mass white dwarfs. However, the nature of these objects is not yet well understood. In particular, no data have been taken at late phases, about one year after the explosion. We report on Subaru and Keck optical spectroscopic and photometric observations of the SN Ia 2006gz, which had been classified as being one of these "overluminous" SNe Ia. The late-time behavior is distinctly different from that of normal SNe Ia, reinforcing the argument that SN 2006gz belongs to a different subclass than normal SNe Ia. However, the peculiar features found at late times are not readily connected to a large amount of 56Ni; the SN is faint, and it lacks [Fe II] and [Fe III] emission. If the bulk of the radioactive energy escapes the SN ejecta as visual light, as is the case in normal SNe Ia, the mass of 56Ni does not exceed ~ 0.3 Msun. We discuss several possibilities to remedy the problem. With the limited observations, however, we are unable to conclusively identify which process is responsible. An interesting possibility is that the bulk of the emission might be shifted to longer wavelengths, unlike the case in other SNe Ia, which might be related to dense C-rich regions as indicated by the early-phase data. Alternatively, it might be the case that SN 2006gz, though peculiar, was actually not substantially overluminous at early times.Comment: 8 pages, 6 figures, 4 tables. Accepted for publication in The Astrophysical Journa

Physics of thick polymers

We present the results of analytic calculations and numerical simulations of the behaviour of a new class of chain molecules which we call thick polymers. The concept of the thickness of such a polymer, viewed as a tube, is encapsulated by a special three body interaction and impacts on the behaviour both locally and non-locally. When thick polymers undergo compaction due to an attractive self-interaction, we find a new type of phase transition between a compact phase and a swollen phase at zero temperature on increasing the thickness. In the vicinity of this transition, short tubes form space filling helices and sheets as observed in protein native state structures. Upon increasing the chain length, or the number of chains, we numerically find a crossover from secondary structure motifs to a quite distinct class of structures akin to the semi-crystalline phase of polymers or amyloid fibers in polypeptides.Comment: 41 pages, 20 figures. Accepted for publication in J. Pol. Sci.

Phase-controlled, heterodyne laser-induced transient grating measurements of thermal transport properties in opaque material

The methodology for a heterodyned laser-induced transient thermal grating technique for non-contact, non-destructive measurements of thermal transport in opaque material is presented. Phase-controlled heterodyne detection allows us to isolate pure phase or amplitude transient grating signal contributions by varying the relative phase between reference and probe beams. The phase grating signal includes components associated with both transient reflectivity and surface displacement whereas the amplitude grating contribution is governed by transient reflectivity alone. By analyzing the latter with the two-dimensional thermal diffusion model, we extract the in-plane thermal diffusivity of the sample. Measurements on a 5 {\mu}m thick single crystal PbTe film yielded excellent agreement with the model over a range of grating periods from 1.6 to 2.8 {\mu}m. The measured thermal diffusivity of 1.3 \times 10-6 m2/s was found to be slightly lower than the bulk value.Comment: 19 pages, 6 figure

Statistical mechanics of semiflexible ribbon polymers

The statistical mechanics of a ribbon polymer made up of two semiflexible chains is studied using both analytical techniques and simulation. The system is found to have a crossover transition at some finite temperature, from a type of short range order to a fundamentally different sort of short range order. In the high temperature regime, the 2-point correlation functions of the object are identical to worm-like chains, while in the low temperature regime they are different due to a twist structure. The crossover happens when the persistence length of individual strands becomes comparable to the thickness of the ribbon. In the low temperature regime, the ribbon is observed to have a novel ``kink-rod'' structure with a mutual exclusion of twist and bend in contrast to smooth worm-like chain behaviour. This is due to its anisotropic rigidity and corresponds to an {\it infinitely} strong twist-bend coupling. The double-stranded polymer is also studied in a confined geometry. It is shown that when the polymer is restricted in a particular direction to a size less than the bare persistence length of the individual strands, it develops zigzag conformations which are indicated by an oscillatory tangent-tangent correlation function in the direction of confinement. Increasing the separation of the confining plates leads to a crossover to the free behaviour, which takes place at separations close to the bare persistence length. These results are expected to be relevant for experiments which involve complexation of two or more stiff or semiflexible polymers.Comment: 20 pages, 11 figures. PRE (in press

The early spectral evolution of SN 2004dt

Aims. We study the optical spectroscopic properties of Type Ia Supernova (SN Ia) 2004dt, focusing our attention on the early epochs. Methods. Observation triggered soon after the SN 2004dt discovery allowed us to obtain a spectrophotometric coverage from day -10 to almost one year (~353 days) after the B band maximum. Observations carried out on an almost daily basis allowed us a good sampling of the fast spectroscopic evolution of SN 2004dt in the early stages. To obtain this result, low-resolution, long-slit spectroscopy was obtained using a number of facilities. Results. This supernova, which in some absorption lines of its early spectra showed the highest degree of polarization ever measured in any SN Ia, has a complex velocity structure in the outer layers of its ejecta. Unburnt oxygen is present, moving at velocities as high as ~16,700 km/s, with some intermediate-mass elements (Mg, Si, Ca) moving equally fast. Modeling of the spectra based on standard density profiles of the ejecta fails to reproduce the observed features, whereas enhancing the density of outer layers significantly improves the fit. Our analysis indicates the presence of clumps of high-velocity, intermediate-mass elements in the outermost layers, which is also suggested by the spectropolarimetric data.Comment: 13 pages, 15 figures, accepted for pubblication in Astronomy and Astrophysic

A Review of Computational Methods in Materials Science: Examples from Shock-Wave and Polymer Physics

This review discusses several computational methods used on different length and time scales for the simulation of material behavior. First, the importance of physical modeling and its relation to computer simulation on multiscales is discussed. Then, computational methods used on different scales are shortly reviewed, before we focus on the molecular dynamics (MD) method. Here we survey in a tutorial-like fashion some key issues including several MD optimization techniques. Thereafter, computational examples for the capabilities of numerical simulations in materials research are discussed. We focus on recent results of shock wave simulations of a solid which are based on two different modeling approaches and we discuss their respective assets and drawbacks with a view to their application on multiscales. Then, the prospects of computer simulations on the molecular length scale using coarse-grained MD methods are covered by means of examples pertaining to complex topological polymer structures including star-polymers, biomacromolecules such as polyelectrolytes and polymers with intrinsic stiffness. This review ends by highlighting new emerging interdisciplinary applications of computational methods in the field of medical engineering where the application of concepts of polymer physics and of shock waves to biological systems holds a lot of promise for improving medical applications such as extracorporeal shock wave lithotripsy or tumor treatment