Le Monde on the Algerian War under the Fourth Republic A study of the newspapers's coverage (1944-1958)

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Experimental Investigation of the Overall Residence Time of Pebbles in a Pebble Bed Reactor (PBR) using Radioactive Pebble

The granular flow of pebbles in a pebble bed reactor (PBR) under the influence of gravity is a dense granular flow with long-lasting frictional contacts. The basic governing physics is not fully understood and hence the dynamic core of a PBR and non-idealities associated with pebbles flow inside the reactor core are of non-trivial significance from the point of view of safety analyses, licensing, and thermal hydraulics. In the current study, overall and zonal pebbles residence time investigation is carried out by implementing noninvasive radioisotope-based flow visualization measurement techniques such as residence time distribution (RTD) and radioactive particle tracking (RPT). The characteristics of overall pebble residence time/transient number, zonal residence time, and the z-component of average zonal velocities at different initial seeding positions of a tracer particle have been summarized. It is found that the overall pebbles residence time/transient number increases (the z-component of average zonal velocities decreases) from the center towards the reactor wall. Also, pebbles\u27 zonal residence time results (the whole core is divided into three zones) which provide more insight and understanding about PBR core dynamics have been reported. The benchmark data provided could be used for assessment of commercial/in-house computational methodologies related to granular flow investigations

Biogenic silver nanoparticles of Moringa oleifera leaf extract: Characterization and photocatalytic application

The current study proposed a novel simple and environmentally friendly approach for producing silver nanoparticles (AgNPs) using an extract of Moringa oleifera leaves (MOL) and optimizing the different experimental factors required for the formation and stability of AgNPs. The formation of nanoparticles was confirmed by a color change from yellow to reddish-brown with a surface plasmon resonance band at 412 nm. The morphology, size, and elemental composition of AgNPs were investigated by zeta potential dynamic light scattering, field emission scanning electron microscopy, energy dispersive X-ray, X-ray diffraction, and transmission electron microscopy analysis, which showed crystalline and spherical AgNPs. The identification of functional groups was supported by Fourier-transform infrared spectroscopy. The photocatalytic activities of AgNPs were assessed in the degradation of organic Malachite green (MG) dye in the aqueous solution. Two kinetic adsorption models, the pseudo-first-order model and the pseudo-second-order model, and three isotherm models, the Langmuir, Freundlich, and Temkin, were used to mathematically characterize the MG degradation process. The pseudo-second-order kinetics and the Freundlich isotherm model were found to be in good agreement with the experimental data. As a result of their synergistic interaction with the MOL extract solution, the photocatalytic activity of AgNPs increases and they can successfully adapt to the photodegradation of organic dyes in industrial effluents

Discrete Element Method-Based Investigations of Granular Flow in a Pebble Bed Reactor

In a pebble bed reactor (PBR) core, nuclear fuel in the form of pebbles moves slowly under the influence of gravity. Due to the dynamic nature of the core, a thorough understanding about slow and dense granular flow of pebbles is required from both a reactor safety point of view and a performance evaluation point of view. In the current study, validation of discrete element method (DEM)-based simulation for the pebble flow in a PBR was carried out. Validation of DEM-based simulations necessitates validation of the employed numerical method of simulating packed structure. Hence, a parametric sensitivity study of packing interaction properties was initially conducted and also validation of the numerical method simulating packed structure at first. The parametric sensitivity analysis suggests that static friction characteristics play an important role from a packed/pebble bed structural characterization point of view. In addition, the simulated packed structure approach has shown a good agreement with the available benchmark data. Afterward, the effect of two different half-cone angles of 30 deg and 60 deg on pebble flow field in a PBR was studied by EDEMTM-based simulations. Results of streamlines, velocity radial profiles, and direct observation of discharge indicated a plug-type flow in the upper cylindrical region, whereas results indicated converging-type flow near the bottom conical region. EDEMTM results of granular flow were validated against experimental benchmark data and show a fair agreement in terms of Lagrangian trajectories and velocity profile. Therefore, this validated EDEMTM-based simulation can be used to obtain reliable results of pebble dynamics in a PBR and to enhance understanding of this phenomenon in a PBR. However, additional experimental investigations are recommended to be carried out for different sizes of test reactors, different bottom cone angles, and different sizes of pebbles to further assess DEM simulation results before using them for full-scale reactor simulations

Green Synthesis of Silver Nanoparticles Using Aqueous <i>Citrus limon</i> Zest Extract: Characterization and Evaluation of Their Antioxidant and Antimicrobial Properties

The current work concentrated on the green synthesis of silver nanoparticles (AgNPs) through the use of aqueous Citruslimon zest extract, optimizing the different experimental factors required for the formation and stability of AgNPs. The preparation of nanoparticles was confirmed by the observation of the color change of the mixture of silver nitrate, after the addition of the plant extract, from yellow to a reddish-brown colloidal suspension and was established by detecting the surface plasmon resonance band at 535.5 nm, utilizing UV-Visible analysis. The optimum conditions were found to be 1 mM of silver nitrate concentration, a 1:9 ratio extract of the mixture, and a 4 h incubation period. Fourier transform infrared spectroscopy spectrum indicated that the phytochemicals compounds present in Citrus limon zest extract had a fundamental effect on the production of AgNPs as a bio-reducing agent. The morphology, size, and elemental composition of AgNPs were investigated by zeta potential (ZP), dynamic light scattering (DLS), SEM, EDX, X-ray diffraction (XRD), and transmission electron microscopy (TEM) analysis, which showed crystalline spherical silver nanoparticles. In addition, the antimicrobial and antioxidant properties of this bioactive silver nanoparticle were also investigated. The AgNPs showed excellent antibacterial activity against one Gram-negative pathogens bacteria, Escherichia coli, and one Gram-positive bacteria, Staphylococcus aureus, as well as antifungal activity against Candida albicans. The obtained results indicate that the antioxidant activity of this nanoparticle is significant. This bioactive silver nanoparticle can be used in biomedical and pharmacological fields

Green Synthesis and Characterization of Silver Nanoparticles Using <i>Flaxseed</i> Extract and Evaluation of Their Antibacterial and Antioxidant Activities

Bioactive plant chemicals are considered to be rich and useful for creating nanomaterials. The current work investigated the biosynthesis of silver nanoparticles (AgNPs) using ethanolic flaxseed extract as an efficient reducing factor. The production of AgNPs was verified by color-shifting observation of the mixture of silver nitrate (AgNO3) from yellow to a reddish suspension after the addition of the extract and by evaluating it by UV–visible inspection. Additionally, FTIR spectrum was used to support the identification of functional groups. The morphology and structure of AgNPs were assessed using scanning electron microscopy (SEM), and X-ray diffraction (XRD) examinations, which revealed spherical AgNPs with a diameter of 46.98 ± 12.45 nm and a crystalline structure. The zeta potential (ZP) and dynamic light scattering (DLS) measurements of AgNPs revealed values of −44.5 mV and 231.8 nm, respectively, suggesting appropriate physical stability. The antibacterial activity of AgNPs was investigated against Escherichia coli, Klebsiella pneumoniae, Staphylococcus aureus, and Streptococcus pyogenes, while the antioxidant effect was investigated using the DPPH technique. These obtained AgNPs could potentially be used as efficient antibacterial and antioxidant nanomaterials

Green Synthesis and Characterization of Silver Nanoparticles Using Flaxseed Extract and Evaluation of Their Antibacterial and Antioxidant Activities

Bioactive plant chemicals are considered to be rich and useful for creating nanomaterials. The current work investigated the biosynthesis of silver nanoparticles (AgNPs) using ethanolic flaxseed extract as an efficient reducing factor. The production of AgNPs was verified by color-shifting observation of the mixture of silver nitrate (AgNO3) from yellow to a reddish suspension after the addition of the extract and by evaluating it by UV&ndash;visible inspection. Additionally, FTIR spectrum was used to support the identification of functional groups. The morphology and structure of AgNPs were assessed using scanning electron microscopy (SEM), and X-ray diffraction (XRD) examinations, which revealed spherical AgNPs with a diameter of 46.98 &plusmn; 12.45 nm and a crystalline structure. The zeta potential (ZP) and dynamic light scattering (DLS) measurements of AgNPs revealed values of &minus;44.5 mV and 231.8 nm, respectively, suggesting appropriate physical stability. The antibacterial activity of AgNPs was investigated against Escherichia coli, Klebsiella pneumoniae, Staphylococcus aureus, and Streptococcus pyogenes, while the antioxidant effect was investigated using the DPPH technique. These obtained AgNPs could potentially be used as efficient antibacterial and antioxidant nanomaterials